Sulfate fluoride explained

The sulfate fluorides are double salts that contain both sulfate and fluoride anions. They are in the class of mixed anion compounds. Some of these minerals are deposited in fumaroles.

Fluoride sulfates were first discovered by Jean Charles de Marignac in 1859.[1] [2]

Some elements such as cobalt or uranium can form complexes that contain fluoride and sulfate groups, and would be referred to as fluoro and sulfato metallates.

List

Minerals

nameformularatiosystemspace groupunit cell Åvolumedensityopticalreferences
Chukhrovite-(Ca)Ca4.5Al2(SO4)F13·12H2O1:13IsometricFd3a = 16.749 Z=84698.62.23isotropic n = 1.432[3]
Chukhrovite-(Ce)Ca3(Y,Ce)(AlF6)2(SO4)F · 10H2O1:13IsometricFd3[4]
Chukhrovite-(Y)Ca3(Ce,Y)(AlF6)2(SO4)F · 10H2O1:13IsometricFd3[5]
Chukhrovite-(Nd)Ca3(Nd,Y)Al2(SO4)F13·12H2O1:13IsometricFd3a = 16.759 Z=84,707.02.42isotropic nα = 1.443[6]
MeniayloviteCa4[(SO<sub>4</sub>)(SiF<sub>6</sub>)(AlF<sub>6</sub>)]F · 12H2O1:13IsometricFd3a = 16.722 Z=84,675.89Isotropic n = 1.43
PseudograndreefitePb6(SO4)F101:10OrthorhombicF2 2 2a = 8.51 b = 19.57 c = 8.49 Z=41,413.93Biaxial (+) nα = 1.864 nβ = 1.865 nγ = 1.8732V: measured: 30°, calculated: 40°

Max birefringence: δ = 0.009

[7]
CreediteCa3SO4Al2F8(OH)2 · 2H2O1:8MonoclinicB2/ba = 13.936, b = 8.606, c = 9.985 β = 94.39° Z=41,194.022.713Biaxial (-) nα = 1.461 nβ = 1.478 nγ = 1.485Max birefringence: δ = 0.024[8]
ThermessaiteK2AlF3(SO4)1:3OrthorhombicPbcna = 10.81 b = 8.336 c = 6.822614.752.77
GrandreefitePb2(SO4)F21:2monoclinicA2/aa = 8.667 b = 4.4419 c = 14.242 β = 107.418 Z=4523.157.15Biaxial (+) nα = 1.872 nβ = 1.873 nγ = 1.8972V: Measured: 23°

Max Birefringence: δ = 0.025

[9]
ArangasiteAl2F(PO4)(SO4) · 9H2O1:1monoclinicP2/aa = 7.073 b = 9.634 c = 10.827 β = 100.40 Z = 2725.72.01Biaxial (+) ?nα = 1.493(5) nγ = 1.485(5)Max birefringence: δ = 0.008[10] [11]
KhademiteAl(SO4)F · 5H2O1:1orthorhombica = 11.17 b = 13.05 c = 10.881,585.961.925Biaxial (-) nα = 1.440 nβ = 1.460 nγ = 1.4872V: measured: 68° calculated: 84°

Max birefringence δ = 0.047

colourless

[12]
KogarkoiteNa3(SO4)F1:1Monoclinic?P21a = 18.07 b = 6.94 c = 11.44 β = 107.72° Z=121,366.582.676Biaxial (+) nα = 1.439 nβ = 1.439 nγ = 1.442Max Birefringence: δ = 0.003[13]
kononoviteNaMg(SO4)F1:1monoclinicC2/ca = 6.662 b = 8.584 c = 7.035 β = 114.06 Z=4367.42.91biaxial (+), nα = 1.488 nβ = 1.491 nγ = 1.496 2Vmeas = 75°Max birefringence: δ = 0.008[14]
LannoniteMg2Ca4Al4(SO4)8F8 · 24H2O8:8TetragonalI4/ma = 6.860 c = 28.0531,320.162.22Uniaxial (+) nω = 1.460 nε = 1.478Max Birefringence:δ = 0.018[15]
SulphohaliteNa6(SO4)2FCl2:1IsometricFmmIsotropic[16]
UklonskoviteNaMgSO4F•2H2O1:1monoclinica = 7.2 Å, b = 7.21 Å, c = 5.73 β = 113.23°273.34Biaxial (+) nα = 1.476 nγ = 1.500

Max Birefringence δ = 0.024

[17]
VlodavetsiteAlCa2(SO4)2F2Cl · 4H2O2:2TetragonalI4/ma = 6.870, c = 13.342 Z=2629.70Uniaxial (+) nω = 1.509 nε = 1.526

Max birefringence: δ = 0.017

[18]
SchaireriteNa21(SO4)7ClF67:6trigonal3_2/ma = 12.17 c = 19.292,474.252.67Uniaxial (+) nω = 1.440 nε = 1.445

Max birefringence: δ = 0.005

[19]
GaleiteNa15(SO4)5F4Cl5:4Trigonala = 12.17 c = 13.941,788.03Uniaxial (+) nω = 1.447 nε = 1.449

Max Birefringence: δ = 0.002

[20]
FluorellestaditeCa10(SiO4)3(SO4)3F23:2hexagonala = 9.53 c = 6.91543.493.03Uniaxial (-) nω = 1.655 nε = 1.650

Max birefringence:δ = 0.005

[21]
StraßmanniteAl(UO2)(SO4)2F·16H2O2:1monoclinicC2/ca = 11.0187 b = 8.3284 c = 26.673 β = 97.426°2427.22.20pale yellowish greenBiaxial (-) nα = 1.477(2) nβ = 1.485(2) nγ = 1.489(2)

2V: measured: 70° calculated: 70.2°

Max birefringence: δ = 0.012

[22]
Svyazhinite(Mg,Mn2+,Ca)(Al,Fe3+)(SO4)2F · 14H2O2:1triclinica = 6.21 b = 13.3 c = 6.25 α = 90.15°, β = 93.56°, γ = 82.08°510.29Biaxial (-) nα = 1.423 nβ = 1.439 nγ = 1.444

2V: calculated: 56°

Max birefringence: δ = 0.021

[23]
WilcoxiteMgAl(SO4)2F · 17H2O2:1triclinicPa = 6.644, b = 6.749, c = 14.892 α = 79.664°, β = 80.113°, γ = 62.487579.61.58Biaxial (-) nα = 1.424 nβ = 1.436 nγ = 1.438

2V: measured: 48°, calculated: 44°

Max birefringence: δ = 0.014

[24]
KrasheninnikoviteKNa2CaMg(SO4)3F3:1hexagonalP63/mcma = 16.6682 c = 6.9007 Z = 61660.362.68Uniaxial (-) nω = 1.500 nε = 1.492Max birefringence: δ = 0.008[25]
ShuvaloviteK2(Ca2Na)(SO4)3F3:1orthorhombicPnmaa = 13.2383 b = 10.3023 c = 8.9909 Z = 41226.222.64biaxial (−), nα = 1.493 nβ = 1.498 nγ = 1.498 2Vmeasured ≤ 20[26]
Thermessaite-(NH4)(NH4)2AlSO4F31:3orthorhombicPbcna = 11.3005 b = 8.6125 c = 6.8501 Z = 4666.69[27]

Artificial

nameformulaMWratiosystemspace groupunit cellvolumedensityopticalCASreferences
LiMgFSO41:1triclinicPa = 5.1623 b = 5.388 c = 7.073 α = 106.68 β=107.40 and γ=97.50° Z=2[28]
NaMgSO4F1:1monoclinicC2/cZ=4109.8022.84
Na2AlSO4F31:1monoclinicP2/ca=6.3562 b=6.2899 c=7.1146 β=115.687° Z=2256.332.928[29]
Li4NH4Al(SO4)2F42:4monoclinicC2/ca=13.6561 b=4.9761 c=13.9919 β=92.135° Z=4950.22.383
Na4TiF4(SO4)22:4[30]
β-K3[SO<sub>4</sub>]F1:1tetragonalI4/mcma= 7.2961 c= 10.854[31]
α-K3[SO<sub>4</sub>]F1:1cubicPmma≈5.43 ≥585 °C
KMgSO4F178.471:1orthorhombicPna21a=12.973 b=6.4585 c=10.635 Z=8891.12.661colourless[32] [33]
Li6K3Al(SO4)4F44:4triclinicPa=5.0304 b=9.5690 c=9.7078 α=70.968° β=75.531° γ=75.183° Z=1420.082.554
sodium calcium sulfapatiteNa6Ca4(SO4)6F26:2
K3Ca2(SO4)3F3:1orthorhombicPn21aa=13.467 b=10.521 c=9.167 Z=41299.9[34]
[N<sub>2</sub>C<sub>10</sub>H<sub>12</sub>] TiF4SO4378.16?1:4triclinicPa=8.691 b=9.208 c=9.288 α=68.56 β=84.30 γ=81.59 Z=2              683.61.837colourless
[N<sub>2</sub>C<sub>10</sub>H<sub>12</sub>]TiF2(SO4)2436.22?2:2triclinicPa=4.5768 b=8.9162 c=10.1236 α=112.888 β=95.196 γ=98.706 Z=1              371.111.952colourless
Rb2TiF2(SO4)2 · 2H2O1:1[35]
Cs2TiF2(SO4)2 · 3H2O1:1
[N<sub>2</sub>C<sub>6</sub>H<sub>16</sub>]V(SO4)2F378.272:1monoclinicP21/ca=10.262 b =17.761 c=7.0518 β=93.93 Z=4                 1282.31.959green
Na2VF3SO41:3
Na3CrF2(SO4)22:2
LiMnSO4F1:1monoclinica=13.2406 b=6.4082 c=10.0229 β=120.499732.76[36]
[N<sub>2</sub>C<sub>6</sub>H<sub>16</sub>]2+Mn2F2(SO4)22:2
Li2MnF3(SO4)1:3pink-brown[37]
(NH4)2MnF3(SO4)1:3pink-brown
Na2MnF3(SO4)1:3pink-brown
Dipotassium trifluorosulfato manganate(III)K2MnF3(SO4)1:3pink-brown
FeFSO4170.911:1monoclinicC2/ca = 7.3037 b = 7.0753 c = 7.3117 β = 119.758°328.0173.461[38]
K2FeF3SO41:3
Li3FeF2(SO4)2·H2O2:2
[N<sub>2</sub>C<sub>6</sub>H<sub>16</sub>]Fe(SO4)2F383.182:1monoclinicP21/ca=10.2220 b=17.6599 c=7.0437 β=93.894 Z=41268.592.006brown
LiFeFSO4177.851:1triclinicPa = 5.1751 b = 5.4915 c = 7.2211 α = 106.506° β = 107.178° γ=97.865°182.443.237grass green
sodium ferrous sulfate fluorideNaFeFSO4193.911:1monoclinicP21/ca = 6.6739 b = 8.6989 c = 7.1869 β = 113.525°382.5673.366
sodium ferrous sulfate fluoride dihydrateNaFeFSO4·2H2O1:1monoclinicP21/ma=5.75959 b=7.38273 c=7.25047 β=113.3225283.109white[39]
trisodium ferric disulfate difluorideNa3Fe(SO4)2F22:2orthorhombicPncaa = 6.6419 b = 8.8115 c = 14.0023[40]
NaCoFSO41:1monoclinicC2/ca=6.6687 b=8.6251 c=7.1444 β=114.323374.46[41]
NaCoFSO4·2H2O1:1monoclinicP21/ma=5.73364 b=7.31498 c=7.18640 β=113.5028276.40pink
NH4CoFSO4·2H2O1:1[42]
KCoFSO4·2H2O1:1
NaNiFSO4·2H2O1:1monoclinicP21/ma=5.70118 b=7.27603 c=7.15634 β=113.8883271.429green
LiZnSO4F1:1orthorhombicPnma7.40357 b=6.32995 c=7.42016347.740[43]
KZnSO4F219.531:1orthorhombicPna21a=13.0602 b=6.4913 c=10.7106 Z=8908.023.212transparent <190 nm
K2Zn3(SO4)(HSO4)2F41:4orthorhombicCmc21a=17.725 b=7.6650 c=9.7505 Z=41324.73.212colourless[44]
Li4RbAl(SO4)2F42:4monoclinicC2/ca=13.6503 b=4.984 c=14.0081 β=91.509° Z=4948.822.858[45]
Y(SO4)F203.971:1orthorhombicPnmaa=8.3128, b=6.9255, c=6.3905 Z=4367.903.682[46]
YSO4F·H2O1:1monoclinicP21/na=4.9707 b=7.306 c=11.493 β =96.95°birefringence 0.0357 at 546 nm[47]
Y2Cu(OH)3(SO4)2F·H2O521.522:1monoclinicP21/na=11.6889, b=6.8660, c=12.5280, β=97.092° Z=4997.83.472blue
KYSO4F21:2monoclinicP21/ma=6.4402 b=5.7784 c=6.992 β=113.684° Z=2238.303.652band gap 7.79 eV; birefringence 0.015 @ 546.1 nm[48]
RbYSO4F21:2monoclinicP21/ma=6.5347 b=5.8212 c=7.1383 β=114.332° Z=2247.424.140band gap 7.82 eV; birefringence 0.02 @ 546.1 nm
Zr2O2F2SO4 · 6H2O1:2[49]
α-K3ZrF5SO4 · H2O1:5
K2ZrF4SO41:4
K2ZrF2(SO4)2 · 2.5H2O2:2
K3Zr2F9SO4 · 2H2O1:9
(NH4)3Zr2F9SO4 · 2H2O1:9
(NH4)2ZrF4SO41:4
(NH4)2ZrF2(SO4)2 · 2.5H2O2:2
Rb2ZrF4SO41:4
Rb2ZrF2(SO4)2 · 3H2O2:2
Rb3Zr2F9SO4 ·2H2O1:9
RbZr2O2F(SO4)2 · 5H2O2:1
Cs2ZrF4SO41:4
Cs2ZrF2(SO4)2 · 2H2O2:2
Cs8Zr4F2(SO4)11 · 16H2O11:2
CsZr2O2F(SO4)2 · 6H2O2:1
Zr2O2F2SO4 · 5H2O1:2
triindium trifluoride sulfate ditellurite hydrateIn3(SO4)(TeO3)2F3(H2O)866.741:3orthorhombicP212121a=8.3115 b=9.4341 c=14.80681161.04.959band gap 4.10 eV; white[50]
4,4'-bipyridine distannous difluoride disulfate(C10H10N2)0.5[SnF(SO<sub>4</sub>)]2:2triclinicPa=4.726 b=7.935 c=11.203 α = 81.05° β = 87.59° γ=73.70° Z=2398.32.608colourless[51]
diantimony dipotassium hexafluoride sulfateK2SO4·(SbF3)2531.761:6monoclinicP21/ca=9.1962 b=5.6523 c=19.2354 β =103.209 Z=4973.403.629colourless[52]
diantimony dirubidium hexafluoride sulfateRb2SO4·(SbF3)2624.501:6monoclinicP21a=9.405 b=5.7210 c=9.879 β = 103.850 Z=2516.14.018colourless
tetraantimony hexarubidium dodecafluoride trisulfateRb6Sb4F12(SO4)31515.9893:12trigonalP3a=16.9490 c=7.5405 Z=21875.944.026white53168-89-1[53] [54]
hexaammonium dodecafluorotrisulfatotetraantimonate(III)[NH<sub>4</sub>]6Sb4F12(SO4)33:12trigonalP3a=17.07 c=7.515 Z=318962.92[55]
hexarubidium dodecafluorotrisulfatotetraantimonate(III)Rb6Sb4F12(SO4)33:12
Li4CsAl(SO4)2F42:4monoclinicC2/ca=13.574 b=5.0427 c=14.258 β=91.961° Z=4975.73.103
tetraantimony hexacaesium dodecafluoride trisulfateCs6Sb4F12(SO4)31800.6013:12triclinicPa=7.9044 b=10.5139 c=17.3534 al=90.350 β = 90.151 ga=104.797 Z=41394.34.289white53200-54-7[56]
antimony caesium difluoride sulfateCsSbF2SO4388.721:2orthorhombicPna21a=9.9759 b=11.6616 c=5.2968515.204.19clear, non-linear SH[57]
LiLa2F3(SO4)22:3monoclinicI2/aa = 8.283, b = 6.947, c = 14.209 β = 95.30° Z=4[58]
CeF2(SO4)1:2orthorhombicPca21a=8.3668 b=6.3600 c=8.3862birefringence 0.361@ 546 nm; SHG 8×KDP[59]
NdFSO4·H2O277.321:1monoclinicP21/na = 4.9948 b = 7.3684 c = 11.6366 β = 96.672° Z=4425.374.330pink[60]
NaPr2F3(SO4)22:3monoclinicI2/aa = 8.223, b = 6.9212, c = 14.199, β = 95.88° Z=4light green[61]
LiEr2F3(SO4)22:3orthorhombicPbcna = 14.791, b = 6.336, c = 8.137
hexa(triethylenetriammonium) tetrasamarium tetradecasulfate difluoride[C<sub>4</sub>H<sub>16</sub>N<sub>3</sub>]6[Sm<sub>4</sub>F<sub>2</sub>(SO<sub>4</sub>)<sub>14</sub>]2621.4314:2triclinicPa = 11.1988 b = 11.4073 c = 16.2666 α = 89.901°, β = 82.406°, γ = 67.757° Z=11903.92.286colourless
TbFSO4·H2O292.001:1monoclinicP21/na = 5.0014 b = 7.377 c = 11.651 β = 96.692° Z=4426.94.543colourless
gadolinium fluoride sulfateGdF[SO<sub>4</sub>]1:1orthorhombicPnmaa=8.436 b=7.0176 c=6.4338 Z=4[62]
γ-K2HfF2(SO4)2 · 2H2O2:2
K2HfF2(SO4)2 · 2.5H2O2:2
Na6Pb4(SO4)6F26:2[63]
ThSO4F2.H2O1:2monoclinicP21na = 6.9065 b = 6.9256 c = 10.589 β = 96.755° Z = 4502.98colourless[64]
potassium catena-di—fluoro-difluorotetraoxo-di—sulphato-diuranate(VI) hydrateK2UF2O2(SO4)·H2O1:2monoclinicP21/ca = 9.263 b = 8.672 c = 11.019 β= 101.60° Z = 4867.13.83greenish yellow[65] [66]
(NH4)2[UO<sub>2</sub>F<sub>2</sub>(SO<sub>4</sub>)]triclinicPa=9.73 b=10.28 c=11.37 α = 107.4°, β = 111.9°, γ =106.9 Z=2greenish yellow
(NH4)6[(UO<sub>2</sub>)<sub>2</sub>F<sub>4</sub>(SO<sub>4</sub>)<sub>3</sub>]triclinicP1a=9.35 b=9.85 c=11.25 α = 109.2°, β = 113.1°, γ =102.5 Z=1greenish yellow
Cs2[(UO<sub>2</sub>)<sub>2</sub>F<sub>4</sub>(SO<sub>4</sub>)]greenish yellow
(NH4)[UO<sub>2</sub>F(SO<sub>4</sub>)]triclinicP1a=8.99 b=7.12 c=7.42 α = 114.5°, β = 117.4°, γ =103.2 Z=11.92greenish yellow
RbUO2SO4ForthorhombicPca21a=25.353 b=6.735 c=11.496 Z=12[67] [68]
[N<sub>2</sub>C<sub>6</sub>H<sub>16</sub>][UO<sub>2</sub>F<sub>2</sub>(SO<sub>4</sub>)]520.291:2triclinicPa=6.9105 b=9.6605 =10.1033 α=72.6594(14) β=87.068 γ=77.9568 Z=2629.622.744yellow[69]
[N<sub>2</sub>C<sub>6</sub>H<sub>16</sub>][UO<sub>2</sub>F(SO<sub>4</sub>)]2884.372:2orthorhombicPmmna=6.9503 b=17.2147 c=7.0867 Z=2847.903.464yellow
[N<sub>2</sub>C<sub>3</sub>H<sub>12</sub>][UO<sub>2</sub>F(SO<sub>4</sub>)]2·H2O862.322:2orthorhombicPnmaa=13.5775 b=14.6180 c=8.1168 Z=41610.993.555yellow
[N<sub>2</sub>C<sub>5</sub>H<sub>14</sub>][UO<sub>2</sub>F(H<sub>2</sub>O)(SO<sub>4</sub>)]2907.382:2monoclinicP121/n1a=8.4354 b=15.5581 c=14.8442 β =96.666 Z=41935.03.115yellow
[N<sub>2</sub>C<sub>6</sub>H<sub>18</sub>]2[UO<sub>2</sub>F(SO<sub>4</sub>)]4·H2O1792.804:4triclinicPa=10.8832 b=10.9386 c=16.5325 α=75.6604 β=73.6101 γ=89.7726 Z=21824.733.263yellow
[N<sub>2</sub>C<sub>3</sub>H<sub>12</sub>][UO<sub>2</sub>F(SO<sub>4</sub>)]2·H2O864.342:2monoclinicP121/n1a=6.7745 b=8.1589 c=14.3661 β =94.556 Z=2791.543.626yellow
diammonium hydrazinium triuranium(IV) tetrafluoride hexasulfateU4+3F4(SO4)6·2NH4·H3N-NH31436.66:4monoclinicC2/ca=15.2309 b=8.77998 c=18.8590 β=105.5030 Z=42432.694.392green[70]

Notes and References

  1. Avdontceva . Margarita S. . Zolotarev . Andrey A. . Krivovichev . Sergey V. . Order–disorder phase transition in the antiperovskite-type structure of synthetic kogarkoite, Na3SO4F . Journal of Solid State Chemistry . November 2015 . 231 . 42–46 . 10.1016/j.jssc.2015.07.033. 2015JSSCh.231...42A .
  2. Book: de Marignac . Jean Charles . Recherches sur les formes cristallines et la composition chimique de divers sels . 1859. Annales des mines. 15 . 221.
  3. Web site: Chukhrovite-(Ca): Mineral information, data and localities.. 2020-06-03. www.mindat.org.
  4. Web site: Chukhrovite-(Ce): Mineral information, data and localities.. 2020-06-03. www.mindat.org.
  5. Web site: Chukhrovite-(Y): Mineral information, data and localities.. 2020-06-03. www.mindat.org.
  6. Web site: Chukhrovite-(Nd): Mineral information, data and localities.. 2020-06-03. www.mindat.org.
  7. Web site: Pseudograndreefite: Mineral information, data and localities.. 2020-06-03. www.mindat.org.
  8. Web site: Creedite: Mineral information, data and localities.. 2020-06-03. www.mindat.org.
  9. Web site: Grandreefite: Mineral information, data and localities.. 2020-06-03. www.mindat.org.
  10. Yakubovich. O. V.. Steele. I. M.. Chernyshev. V. V.. Zayakina. N. V.. Gamyanin. G. N.. Karimova. O. V.. August 2014. The crystal structure of arangasite, Al 2 F(PO 4)(SO 4)·9H 2 O determined using low-temperature synchrotron data. Mineralogical Magazine. en. 78. 4. 889–903. 10.1180/minmag.2014.078.4.09. 2014MinM...78..889Y. 94078023. 0026-461X.
  11. Web site: Arangasite: Mineral information, data and localities.. 2020-06-16. www.mindat.org.
  12. Web site: Khademite: Mineral information, data and localities.. 2020-06-16. www.mindat.org.
  13. Web site: Kogarkoite: Mineral information, data and localities.. 2020-06-03. www.mindat.org.
  14. Pekov. Igor V.. Krzhizhanovskaya. Maria G.. Yapaskurt. Vasiliy O.. Belakovskiy. Dmitry I.. Chukanov. Nikita V.. Lykova. Inna S.. Sidorov. Evgeny G.. 2015-07-27. Kononovite, NaMg(SO4)F, a new mineral from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. European Journal of Mineralogy. en. 27. 4. 575–580. 10.1127/ejm/2015/0027-2457. 2015EJMin..27..575P. 0935-1221.
  15. Web site: Lannonite: Mineral information, data and localities.. 2020-06-03. www.mindat.org.
  16. Web site: Sulphohalite: Mineral information, data and localities.. 2020-06-03. www.mindat.org.
  17. Web site: Uklonskovite: Mineral information, data and localities.. 2020-06-03. www.mindat.org.
  18. Web site: Vlodavetsite: Mineral information, data and localities.. 2020-06-03. www.mindat.org.
  19. Web site: Schairerite: Mineral information, data and localities.. 2020-06-03. www.mindat.org.
  20. Web site: Galeite: Mineral information, data and localities.. 2020-06-03. www.mindat.org.
  21. Web site: Fluorellestadite: Mineral information, data and localities.. 2020-06-16. www.mindat.org.
  22. Web site: Straßmannite: Mineral information, data and localities.. 2020-06-16. www.mindat.org.
  23. Web site: Svyazhinite: Mineral information, data and localities.. 2020-06-16. www.mindat.org.
  24. Web site: Wilcoxite: Mineral information, data and localities.. 2020-06-03. www.mindat.org.
  25. Pekov. I. V.. Zelenski. M. E.. Zubkova. N. V.. Ksenofontov. D. A.. Kabalov. Y. K.. Chukanov. N. V.. Yapaskurt. V. O.. Zadov. A. E.. Pushcharovsky. D. Y.. 2012-10-01. Krasheninnikovite, KNa2CaMg(SO4)3F, a new mineral from the Tolbachik volcano, Kamchatka, Russia. American Mineralogist. en. 97. 10. 1788–1795. 10.2138/am.2012.4104. 2012AmMin..97.1788P. 98050549. 0003-004X.
  26. Pekov. Igor V.. Zubkova. Natalia V.. Britvin. Sergey N.. Chukanov. Nikita V.. Yapaskurt. Vasiliy O.. Sidorov. Evgeny G.. Pushcharovsky. Dmitry Y.. 2016-03-23. Shuvalovite, K2(Ca2Na)(SO4)3F, a new mineral from the Tolbachik volcano, Kamchatka, Russia. European Journal of Mineralogy. en. 28. 1. 53–62. 10.1127/ejm/2015/0027-2471. 2016EJMin..28...53P. 0935-1221.
  27. Garavelli . Anna . Pinto . Daniela . Mitolo . Donatella . Kolitsch . Uwe . October 2021 . Thermessaite-(NH 4), (NH 4) 2 AlF 3 (SO 4), a new fumarole mineral from La Fossa crater at Vulcano, Aeolian Islands, Italy . Mineralogical Magazine . en . 85 . 5 . 665–672 . 10.1180/mgm.2021.69 . 0026-461X.
  28. Sebastian. Litty. Gopalakrishnan. Jagannatha. Piffard. Yves. 2002-01-24. Synthesis, crystal structure and lithium ion conductivity of LiMgFSO4. Journal of Materials Chemistry. 12. 2. 374–377. 10.1039/b108289m.
  29. Wu . Zhencheng . Li . Huimin . Zhang . Zhiyuan . Su . Xin . Shi . Hongsheng . Huang . Yi-Neng . 2024-01-22 . Design of Deep-Ultraviolet Zero-Order Waveplate Materials by Rational Assembly of [AlO 2 F 4 ] and [SO 4 ] Groups ]. Inorganic Chemistry . en . 63 . 3 . 1674–1681 . 10.1021/acs.inorgchem.3c03904 . 0020-1669.
  30. Marshall. Kayleigh L.. Wang. Qianlong. Sullivan. Hannah S. I.. Weller. Mark T.. 2016. Synthesis and structural characterisation of transition metal fluoride sulfates. Dalton Transactions. en. 45. 21. 8854–8861. 10.1039/C6DT00582A. 27151299. 1477-9226.
  31. Skakle. Janet M. S.. Fletcher. James G.. West. Anthony R.. 1996. Polymorphism, structures and phase transformation of K3[SO4]F]. Journal of the Chemical Society, Dalton Transactions. en. 12. 2497–2501. 10.1039/dt9960002497. 0300-9246.
  32. Poddar. Anuradha. Gedam. S.C.. Dhoble. S.J.. November 2013. Photoluminescence study of KMgSO4F:X (X=Cu+ or Dy3+ or Eu3+) halosulfate phosphor. Journal of Luminescence. en. 143. 579–582. 10.1016/j.jlumin.2013.06.010. 2013JLum..143..579P.
  33. Zhou. Yang. Liu. Xiaomeng. Lin. Zheshuai. Li. Yanqiang. Ding. Qingran. Liu. Youchao. Chen. Yangxin. Zhao. Sangen. Hong. Maochun. Luo. Junhua. 2021-12-20. Pushing KTiOPO 4 -like Nonlinear Optical Sulfates into the Deep-Ultraviolet Spectral Region. Inorganic Chemistry. en. 60. 24. 18950–18956. 10.1021/acs.inorgchem.1c02764. 34881864. 245093289. 0020-1669.
  34. Triviño Vázquez. F.. July 1985. A new compound: K3Ca2 (SO4)3F, identified in coatings of heat recover cyclones. Cement and Concrete Research. en. 15. 4. 581–584. 10.1016/0008-8846(85)90055-9.
  35. Boroznovskaya. N. N.. Godneva. M. M.. Motov. D. L.. Klimkin. V. M.. April 2007. Synthesis and luminescent properties of alkali-metal and ammonium fluorosulfatozirconates and fluorosulfatohafnates. Inorganic Materials. en. 43. 4. 425–429. 10.1134/S0020168507040176. 97061342. 0020-1685.
  36. Tripathi. Rajesh. Popov. Guerman. Ellis. Brian L.. Huq. Ashfia. Nazar. L. F.. 2012. Lithium metal fluorosulfate polymorphs as positive electrodes for Li-ion batteries: synthetic strategies and effect of cation ordering. Energy & Environmental Science. en. 5. 3. 6238. 10.1039/c2ee03222h. 1754-5692.
  37. Bhattacharjee. M.N.. Chaudhuri. M.K.. January 1984. Alkali-metal trifluoromonosulphatomanganates (III) A2[MnF3(SO4)] (A = NH4, Li, Na or K). Polyhedron. en. 3. 5. 599–602. 10.1016/S0277-5387(00)88094-8.
  38. Tripathi. Rajesh. Ramesh. T. N.. Ellis. Brian L.. Nazar. Linda F.. 2010-11-08. Scalable Synthesis of Tavorite LiFeSO4F and NaFeSO4F Cathode Materials. Angewandte Chemie International Edition. en. 49. 46. 8738–8742. 10.1002/anie.201003743. 20941717.
  39. Ati. M.. Dupont. L.. Recham. N.. Chotard. J.N.. Walker. W.T.. Davoisne. C.. Barpanda. P.. Sarou-Kanian. V.. Armand. M.. Tarascon. J.M.. 2010-07-13. Synthesis, Structural, and Transport Properties of Novel Bihydrated Fluorosulphates NaMSO 4 F·2H 2 O (M = Fe, Co, and Ni). Chemistry of Materials. en. 22. 13. 4062–4068. 10.1021/cm1010482. 0897-4756.
  40. Long. Zhao. Wei. Liu. Shuang. Liu. lixin. Cao. Ge. Su. Rongjie. Gao. November 2015. The first anhydrous metal fluorosulfate Na3Fe(SO4)2F2 with layered structure prepared via the interesting "tailor" role of fluorine ions based on Na3Fe(SO4)2. Inorganica Chimica Acta. en. 438. 191–195. 10.1016/j.ica.2015.09.020.
  41. Melot. B. C.. Rousse. G.. Chotard. J.-N.. Kemei. M. C.. Rodríguez-Carvajal. J.. Tarascon. J.-M.. 2012-03-12. Magnetic structure and properties of NaFeSO 4 F and NaCoSO 4 F. Physical Review B. en. 85. 9. 094415. 10.1103/PhysRevB.85.094415. 2012PhRvB..85i4415M. 1098-0121.
  42. Bhattacharjee. Manabendra N.. Chaudhuri. Mihir K.. Devi. Meenakshi. Yhome. Khriesavilie. 1987. Direct synthesis of alkali trifluorocobaltate(II) monohydrates, A[CoF 3 ]·H 2 O (A = NH 4, Na, or K). First synthesis and structural assessment of mixed-ligand fluoro complexes of cobalt(II), [Co(NH 3) 4 F 2 ] and A[CoF(SO 4)(H 2 O) 2 ](A = NH 4, Na, or K)]. J. Chem. Soc., Dalton Trans.. en. 5. 1055–1057. 10.1039/DT9870001055. 0300-9246.
  43. Barpanda. Prabeer. Chotard. Jean-Noël. Delacourt. Charles. Reynaud. Marine. Filinchuk. Yaroslav. Armand. Michel. Deschamps. Michael. Tarascon. Jean-Marie. 2011-03-07. LiZnSO4F Made in an Ionic Liquid: A Ceramic Electrolyte Composite for Solid-State Lithium Batteries. Angewandte Chemie International Edition. en. 50. 11. 2526–2531. 10.1002/anie.201006331. 21370330.
  44. Zhou. Yang. Zhang. Xingyu. Xiong. Zheyao. Long. Xifa. Li. Yanqiang. Chen. Yangxin. Chen. Xin. Zhao. Sangen. Lin. Zheshuai. Luo. Junhua. 2021-08-23. Non-π-Conjugated Deep-Ultraviolet Nonlinear Optical Crystal K 2 Zn 3 (SO 4)(HSO 4) 2 F 4. The Journal of Physical Chemistry Letters. 12. 34. en. 8280–8284. 10.1021/acs.jpclett.1c01533. 34425677. 237280608. 1948-7185.
  45. Jiang . Bao . Yan . Yuchen . Liu . Xinglong . Zhang . Boxuan . Chen . Zhaohui . 2023-05-01 . Li<sub>4</sub>AAl(SO<sub>4</sub>)<sub>2</sub>F<sub>4</sub> (A = Cs, Rb): two deep-UV fluoroaluminosulfates with special motif [AlS&lt;sub&gt;2&lt;/sub&gt;O&lt;sub&gt;8&lt;/sub&gt;F&lt;sub&gt;4&lt;/sub&gt;] ]. SCIENTIA SINICA Chimica . en . 10.1360/SSC-2023-0072 . 1674-7224.
  46. Wang. Xiqu. Liu. Lumei. Ross. Kent. Jacobson. Allan J.. January 2000. Synthesis and crystal structures of yttrium sulfates Y(OH)(SO4), Y(SO4)F, YNi(OH)3(SO4)-II and Y2Cu(OH)3(SO4)2F·H2O. Solid State Sciences. en. 2. 1. 109–118. 10.1016/S1293-2558(00)00107-2.
  47. Jiao . Dong-Xue . Zhang . Hui-Li . Li . Xiao-Fei . He . Chao . Li . Jin-Hua . Wei . Qi . Yang . Guo-Yu . 2023-10-12 . YSO 4 F·H 2 O: A Deep-Ultraviolet Birefringent Rare-Earth Sulfate Fluoride with Enhanced Birefringence Induced by Fluorinated Y-Centered Polyhedra . Inorganic Chemistry . 62 . 42 . 17333–17340 . en . 10.1021/acs.inorgchem.3c02632 . 37823856 . 263907626 . 0020-1669.
  48. Wu . Zhencheng . Li . Huimin . Hou . Xueling . Yang . Zhihua . Shi . Hongsheng . 2024-02-27 . AYSO 4 F 2 (A = K, Rb): [YO 4 F 4 ] Polyhedra Enhancement of Birefringence in Non-π-Conjugated Sulfate Systems ]. Inorganic Chemistry . 63 . 10 . 4783–4789 . en . 10.1021/acs.inorgchem.4c00221 . 0020-1669.
  49. Godneva. M. M.. Motov. D. L.. Kuznetsov. V. Ya. 2002. Phase formation in the ZrO2 – H2SO4 – LiF(HF) – H2O system. Zhurnal Neorganicheskoj Khimii. ru. 47. 2. 312–318. 0044-457X.
  50. Gong. Ya-Ping. Ma. Yun-Xiang. Ying. Shao-Ming. Mao. Jiang-Gao. Kong. Fang. 2019-08-19. Two Indium Sulfate Tellurites: Centrosymmetric In 2 (SO 4)(TeO 3)(OH) 2 (H 2 O) and Non-centrosymmetric In 3 (SO 4)(TeO 3) 2 F 3 (H 2 O). Inorganic Chemistry. en. 58. 16. 11155–11163. 10.1021/acs.inorgchem.9b01730. 31365247. 199054944. 0020-1669.
  51. Detkov. D. G.. Gorbunova. Yu. E.. Kazarinova. A. S.. Mikhailov. Yu. N.. Kokunov. Yu. V.. 2003. Polymeric Tin(II) Complexes with Dibasic Nitrogen-Containing Organic Cations. Synthesis and Crystal Structure of (C10H10N2)0.5[SnF(SO4]. Russian Journal of Coordination Chemistry. 29. 7. 451–454. 10.1023/A:1024721310366. 92085359.
  52. Wang. Qian. Wang. Lei. Zhao. Xiaoyu. Huang. Ling. Gao. Daojiang. Bi. Jian. Wang. Xin. Zou. Guohong. 2019. Centrosymmetric K 2 SO 4 ·(SbF 3) 2 and noncentrosymmetric Rb 2 SO 4 ·(SbF 3) 2 resulting from cooperative effects of lone pair and cation size. Inorganic Chemistry Frontiers. en. 6. 11. 3125–3132. 10.1039/C9QI01036J. 203556418. 2052-1553.
  53. Dong . Xuehua . Long . Ying . Zhao . Xiaoyu . Huang . Ling . Zeng . Hongmei . Lin . Zhien . Wang . Xin . Zou . Guohong . A6Sb4F12(SO4)3 (A = Rb, Cs): Two Novel Antimony Fluoride Sulfates with Unique Crown-like Clusters . Inorganic Chemistry . 22 May 2020 . 59 . 12 . 8345–8352 . 10.1021/acs.inorgchem.0c00756. 32441103 . 218831866 .
  54. Web site: Landolt-Börnstein Substance / Property Index. lb.chemie.uni-hamburg.de. 2020-05-25.
  55. Waśkowska. A.. Lis. T.. 1988-08-15. Structure of hexaammonium dodecafluorotrisulfatotetraantimonate(III) at 300 K. Acta Crystallographica Section C: Crystal Structure Communications. 44. 8. 1342–1345. 10.1107/S0108270188003774.
  56. Web site: Landolt-Börnstein Online Search. lb.chemie.uni-hamburg.de. 2020-05-25.
  57. Dong. Xuehua. Huang. Ling. Hu. Cuifang. Zeng. Hongmei. Lin. Zhien. Wang. Xin. Ok. Kang Min. Zou. Guohong. 2019-05-13. CsSbF 2 SO 4 : An Excellent Ultraviolet Nonlinear Optical Sulfate with a KTiOPO 4 (KTP)-type Structure. Angewandte Chemie International Edition. en. 58. 20. 6528–6534. 10.1002/anie.201900637. 30805990. 73468465. 1433-7851.
  58. Wickleder. Mathias S.. 1999. LiLa2F3(SO4)2 und LiEr2F3(SO4)2: Fluoridsulfate der Selten-Erd-Elemente mit Lithium. Zeitschrift für anorganische und allgemeine Chemie. de. 625. 2. 302–308. 10.1002/(SICI)1521-3749(199902)625:2<302::AID-ZAAC302>3.0.CO;2-Y. 1521-3749.
  59. Wu . Chao . Wu . Tianhui . Jiang . Xingxing . Wang . Zujian . Sha . Hongyuan . Lin . Lin . Lin . Zheshuai . Huang . Zhipeng . Long . Xifa . Humphrey . Mark G. . Zhang . Chi . 2021-03-24 . Large Second-Harmonic Response and Giant Birefringence of CeF 2 (SO 4) Induced by Highly Polarizable Polyhedra . Journal of the American Chemical Society . en . 143 . 11 . 4138–4142 . 10.1021/jacs.1c00416 . 33625206 . 232039261 . 0002-7863. 1885/251607 . free .
  60. Zhou. Wanli. Xu. Yan. Han. Lijie. Zhu. Dunru. 2010. Solvothermal syntheses, crystal structures and luminescence properties of three new lanthanide sulfate fluorides. Dalton Transactions. en. 39. 15. 3681–6. 10.1039/b926131a. 20354621. 1477-9226.
  61. Wickleder. Mathias S.. 2000. Synthese und Kristallstruktur von NaPr2F3(SO4)2. Zeitschrift für anorganische und allgemeine Chemie. en. 626. 8. 1723–1724. 10.1002/1521-3749(200008)626:8<1723::AID-ZAAC1723>3.0.CO;2-1. 1521-3749.
  62. Wickleder. Mathias S.. 1999. Halogenidsulfate des Gadoliniums: Synthese und Kristallstruktur von GdClSO4 und GdFSO4. Zeitschrift für anorganische und allgemeine Chemie. de. 625. 5. 725–728. 10.1002/(SICI)1521-3749(199905)625:5<725::AID-ZAAC725>3.0.CO;2-T. 1521-3749.
  63. Book: Ptáček, Petr. Apatites and their Synthetic Analogues: Synthesis, Structure, Properties and Applications. 2016-04-13. BoD – Books on Demand. 978-953-51-2265-4. 227. en.
  64. Zhao. Yanyan. Wang. Chunxiang. Su. Jing. Wang. Yaxing. Wang. Yanlong. Wang. Shuao. Diwu. Juan. Liu. Zhihong. October 2015. Insights into the new Th (IV) sulfate fluoride complex: Synthesis, crystal structures, and temperature dependent spectroscopic properties. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. en. 149. 295–303. 10.1016/j.saa.2015.04.037. 25965512.
  65. Alcock. N. W.. Roberts. M. M.. Chakravorti. M. C.. 1980-03-01. Structure of potassium catena -di-μ-fluoro-difluorotetraoxo-di-μ-sulphato-diuranate(VI) hydrate. Acta Crystallographica Section B: Structural Crystallography and Crystal Chemistry. 36. 3. 687–690. 10.1107/S0567740880004141. 0567-7408.
  66. Chakravorti. M.C.. Bharadwaj. P.K.. January 1979. Fluoro complexes of hexavalent uranium—VII. Journal of Inorganic and Nuclear Chemistry. en. 41. 8. 1149–1152. 10.1016/0022-1902(79)80474-1.
  67. Lussier. Aaron J.. Lopez. Rachel A.K.. Burns. Peter C.. January 2016. A Revised and Expanded Structure Hierarchy of Natural and Synthetic Hexavalent Uranium Compounds. The Canadian Mineralogist. en. 54. 1. 177–283. 10.3749/canmin.1500078. 2016CaMin..54..177L . 0008-4476.
  68. Mikhailov. Yu. N.. Gorbunova. Yu. E.. Mit'kovskaya. E. V.. Serezhkina. L. B.. Serezhkin. V. N.. 2002. Crystal Structure of Rb[UO2(SO4)F]. Radiochemistry. 44. 4. 315–318. 10.1023/A:1020652306275. 92322197.
  69. Doran. Michael B.. Cockbain. Ben E.. O'Hare. Dermot. 2005. Structural variation in organically templated uranium sulfate fluorides. Dalton Transactions. en. 10. 1774–80. 10.1039/b504457j. 15877147. 1477-9226.
  70. Olchowka. Jakub. Volkringer. Christophe. Henry. Natacha. Loiseau. Thierry. March 2014. Crystal structures of tetravalent uranium fluorides obtained in the presence of hydrazine from uranyl source. Journal of Fluorine Chemistry. en. 159. 1–7. 10.1016/j.jfluchem.2013.12.003.

This article is licensed under the GNU Free Documentation License. It uses material from the Wikipedia article "Sulfate fluoride".

Except where otherwise indicated, Everything.Explained.Today is © Copyright 2009-2024, A B Cryer, All Rights Reserved. Cookie policy.