Scanning flow cell explained

Scanning Flow Cell (SFC) is an electrochemical technique, based on the principle of channel electrode. The electrolyte is continuously flowing over a substrate that is introduced externally on translation stage. In contrast to the reference and counter electrode that are integrated in the main channel or placed in side compartments connected with a salt bridge.

SFC utilizes V-formed geometry with a small opening on the bottom (in range of 0.2-1mm diameter) used to establish the contact with sample. The convective flow is sustained also in non-contact mode of operation that allows easy exchange of the working electrode.[1]

Application

The SFC is employed for combinatorial and high-throughput electrochemical studies. Due to its non-homogenous flow profile distribution, it is currently used for comparative kinetic studies. SFC is predominantly used for coupling of electrochemical measurements with post analytical techniques like UV-Vis, ICP-MS, ICP-OES etc. This makes possible a direct correlation of electrochemical and spectrometric signal. This methodology was successfully applied for corrosion studies.[2] [3]

Notes and References

  1. Web site: Scanning Flow Cell . 2023-09-23 . www.mpie.de . en.
  2. Topalov, A.A. . and Katsounaros, I. . Michael, A. . Cherevko, S. . Meier, J.C. . Klemm, S.O. . Mayrhofer, K.J.J. . Dissolution of Platinum: Limits for the Deployment of Electrochemical Energy Conversion?. Angewandte Chemie International Edition. 1521-3773. 10.1002/anie.201207256. 2012. AngChem. 12613–12615. 51. 50 . 23124819 . 3556695.
  3. Coupling of a high throughput microelectrochemical cell with online multielemental trace analysis by ICP-MS. Electrochemistry Communications. 13. 1533–1535. 2011. 1388-2481. 10.1016/j.elecom.2011.10.017. Klemm, S.O. . Topalov, A.A. . Laska, C.A. . Mayrhofer, K.J.J. . 12. eComm.