Diana's Tree (Latin: Arbor Diana or Dianae), also known as the Philosopher's Tree (Arbor Philosophorum), was considered a precursor to the philosopher's stone and resembled coral in regards to its structure.[1] It is a dendritic amalgam of crystallized silver, obtained from mercury in a solution of silver nitrate; so-called by the alchemists, among whom "Diana" stood for silver.[2] The arborescence of this amalgam, which even included fruit-like forms on its branches, led pre-modern chemical philosophers to theorize the existence of life in the kingdom of minerals.[3]
Alchemy was a series of practices that combined philosophical, magical, and chemical experimentation. One goal of European alchemists was to create what was known as the Philosopher’s Stone, a substance that when heated and combined with a non precious metal like copper or iron (known as the “base”) would turn into gold. Although now considered a pseudoscience, the practice of alchemy has contributed experimental techniques to the chemistry world such as the process of distillation and sublimation.[4] The Tree of Diana was thought to be a precursor to the Philosopher's Stone: experiments involving the Tree aimed to turn non precious metals into precious metals like gold or silver, similar to the Stone.
In pre-modern chemistry, the various methods for procuring Diana's Tree were exceedingly time-consuming; for example, the following process, originally described by Nicolas Lemery, required forty days to see results:
Giambattista della Porta in the 16th century described it this way:
The quickest method, as described by German natural philosopher Wilhelm Homberg (1652–1715), took about a quarter of an hour, and is described as follows:
The form of this metallic tree may be varied as desired. The stronger the user makes the first described water, the thicker the tree will be with branches, and sooner formed. Homberg also described how numerous other kinds of trees may be produced by crystallization and "digestion".
17th century American alchemist George Starkey, who wrote under the pen name "Eirenaeus Philalethes", had a recipe for "sophick mercury" that produced a branch-like structure consisting of an alloy of gold and mercury. His process involved the repeated distillation of the mercury, which he then heated while adding gold to produce the structure. In one version, a small seed of gold is mixed with mercury to create the "Philosopher’s Tree"; at the time Starkey was writing, the creation of gold from gold itself was viewed as being obviously possible. In 2018, Starkey's methods, including the above "Philosopher's Tree" were reconstructed by historian of science Lawrence Principe.[5]
In 2016, a copy of Starkey's recipe for making the Tree of Diana was discovered in a manuscript by Isaac Newton; however, there is no evidence that Newton attempted the process.[6] Newton kept his experiments on alchemy a secret, as the practice was illegal in England at the time. In addition, much of Newton's work regarding alchemy was lost in a fire supposedly started by his dog.[7]
There is also Saturn's Tree, which was a deposit of crystallized lead, massed together in the form of a "tree". It is produced by a shaving of zinc in a solution of the lead(II) acetate. In alchemy, Saturn was associated with lead.[2]
Experiments with the Tree of Diana have inspired modern chemists to replicate its creation, using the process to analyze reactions between metals and other substances. A 1967 experiment at the University of Seattle studied the reaction between solid copper and aqueous silver nitrate. In it, silver ions reacted with the copper metal to form a crystal structure, and this reaction continued until the concentration of silver ions was exhausted.[8]