Rhodochrosite Explained

Rhodochrosite
Category:Carbonate minerals
Formula:MnCO3
Imasymbol:Rds[1]
Molweight:114.95 g/mol
Strunz:5.AB.05
System:Trigonal
Class:Hexagonal scalenohedral (m)
H-M symbol: (2/m)
Symmetry:Rc
Unit Cell:a = 4.777, c = 15.67 [Å]; Z = 6
Color:Pink, rose, rose-red, red, cherry-red, yellow, yellowish grey, grey, cinnamon-brown, white, may be banded; colourless to pale rose in transmitted light.
Habit:Rhombohedral and scalenohedral crystals; also commonly bladed, columnar, stalactitic, botryoidal, granular or massive
Twinning:On as contact and lamellar
Cleavage:On perfect; parting on
Fracture:Uneven, conchoidal
Tenacity:Brittle
Mohs:3.5–4
Lustre:Vitreous to pearly
Refractive:nω = 1.814–1.816
nε = 1.596–1.598
Opticalprop:Uniaxial (−)
Birefringence:δ = 0.218
Pleochroism:weak
Fluorescence:None
Streak:White
Gravity:3.7
Diaphaneity:Transparent to translucent
References:[2] [3] [4]

Rhodochrosite is a manganese carbonate mineral with chemical composition MnCO3. In its pure form (rare), it is typically a rose-red colour,[5] but it can also be shades of pink to pale brown. It streaks white,[6] and its Mohs hardness varies between 3.5 and 4.5. Its specific gravity is between 3.45 and 3.6.[7] The crystal system of rhodochrosite is trigonal, with a structure and cleavage in the carbonate rhombohedral system. The carbonate ions are arranged in a triangular planar configuration, and the manganese ions (Mn2+) are surrounded by six oxygen ions in an octahedral arrangement. The MnO6 octahedra and CO3 triangles are linked together to form a three-dimensional structure. Crystal twinning is often present. It can be confused with the manganese silicate rhodonite, but is distinctly softer.[8] Rhodochrosite is formed by the oxidation of manganese ore, and is found in South Africa, China, and the Americas.[6] It is one of the national symbols of Argentina.

Rhodochrosite forms a complete solid solution series with iron carbonate (siderite). Calcium (as well as magnesium and zinc, to a limited extent) frequently substitutes for manganese in the structure, leading to lighter shades of red and pink, depending on the degree of substitution. This is the reason for the pink color of rhodochrosite.

Occurrence and discovery

Rhodochrosite occurs as a hydrothermal vein mineral along with other manganese minerals in low temperature ore deposits as in the silver mines of Romania where it was first found. Banded rhodochrosite is mined in Capillitas, Argentina.

It was first described in 1813 in reference to a sample from Cavnic, Maramureş, present-day Romania. The name is derived from the combination of Greek words ροδόν (rodon, meaning rose) and χρωσις (chrosis, meaning coloring).[2]

Use

Rhodochrosite is mainly used as an ore of manganese, which is a key component of low-cost stainless steel formulations and certain aluminium alloys.[9] Quality banded specimens are often used for decorative stones and jewellery. Due to its softness and perfect cleavage it is rarely found faceted in jewellery.[10]

Manganese carbonate is extremely destructive to the amalgamation process historically used in the concentration of silver ores, and were often discarded on the mine dump.

Culture

Rhodochrosite is Argentina's "national gemstone".[11] [12] Colorado officially named rhodochrosite as its state mineral in 2002.[13]

It is sometimes called "Rosa del Inca", "Inca Rose" or Rosinca.[14]

See also

References

Notes and References

  1. Warr. L.N.. 2021. IMA–CNMNC approved mineral symbols. Mineralogical Magazine. 85. 3. 291–320. 10.1180/mgm.2021.43. 2021MinM...85..291W. 235729616. free.
  2. Book: Anthony, John W.. Bideaux, Richard A.. Bladh, Kenneth W. . Nichols, Monte C. . Handbook of Mineralogy. Mineralogical Society of America. Chantilly, VA, US. Rhodochrosite. 0962209740 . V (Borates, Carbonates, Sulfates). 2003.
  3. http://www.mindat.org/min-3406.html Rhodochrosite
  4. http://webmineral.com/data/Rhodochrosite.shtml Rhodochrosite
  5. Book: Rock-forming Minerals: Non-Silicates . 150–152 . 5B . Deer, William Alexander . Geological Society of London . 1998. 9781897799901 .
  6. Book: Understanding Minerals & Crystals . 180 . Cairncross, Bruce . Penguin Random House South Africa . 2015. 9781775843344 .
  7. Book: Manganese: General Information . 3 . Ridgway, Robert Henderson . U.S. Department of the Interior, Bureau of Mines . 1933.
  8. https://www.mindat.org/min-3407.html Rhodonite
  9. Book: Emsley, John. Nature's Building Blocks: An A-Z Guide to the Elements. Oxford University Press. 2001. Oxford, UK. 978-0-19-850340-8. Manganese. 251.
  10. Book: Matlins, Antoinette Leonard . Colored gemstones : the Antoinette Matlins buying guide : how to select, buy, care for & enjoy sapphires, emeralds, rubies, and other colored gems with confidence and knowledge . GemStone Press . Woodstock, Vt. . 2005 . 978-0-943763-45-3 . 60374175 . 143.
  11. Web site: Piedra nacional: la Rodocrosita. Embassy of the Argentine Republic in the Colombian Republic. 7 October 2013. es.
  12. News: La piedra argentina. Moreno, María. Página/12. 9 November 2002. 7 October 2013. es.
  13. Web site: Colorado State Archives; Symbols & Emblems . 2 February 2012.
  14. Web site: Central Michigan University. Rhodochrosite. Dietrich, R. V.. 16 July 2005. 15 August 2007.