Reika Yokochi Explained

Reika Yokochi (横地玲果, born November 9, 1975 in Saga, Kyushu Prefecture, Japan; died on February 17, 2024 in Chicago, USA) was a Japanese geochemist who worked on the origin and geological behavior of volatile elements. She held the position of Research Professor in the Department of the Geophysical Sciences at the University of Chicago.[1] Yokochi led a laboratory specializing in the purification and analysis of noble gases for dating and tracing water circulation within Earth's crust.[1] [2]

Education and early career

Yokochi completed her doctoral studies in earth sciences at National Polytechnic Institute of Lorraine (French: L'Institut National Polytechnique de Lorraine) in 2005, supervised by Bernard Marty. Her PhD thesis focused on understanding the origin of volatile elements in Earth. She identified noble gases of solar origin in Earth's deep mantle. She also worked out the contribution of 244Pu-decay (t1/2=81 Myr) to fissiogenic 136Xe* in the deep Earth, suggesting a protracted loss of volatiles from Earth's mantle.[3] Between 2005 and 2008, she was a postdoctoral researcher with Neil C. Sturchio at the University of Illinois Chicago, after which she joined the University of Chicago as researcher in 2008.[1]

Research activities

Yokochi's research focuses on noble gas geochemistry. She uses noble gases radionuclides, notably Krypton-81 (81Kr; t1/2=230,000 yr),[4] to study the age and circulation of groundwater in major aquifers worldwide, including the Nubian Sandstone Aquifer,[5] [6] Floridan Aquifer,[7] and the geothermal waters of Yellowstone.[8] Krypton-81 is produced by cosmic rays in the atmosphere and then dissolves into rainwater, eventually seeping into groundwater. The overall abundance of krypton in the atmosphere is only about 1.10 parts per million by volume (ppmv), and within this, the fraction of 81Kr is extremely small, about 5 × 10−13. Yokochi crafted a device capable of efficiently extracting krypton from vast quantities of groundwater, thus facilitating the accurate quantification of 81Kr using Atom Trap Trace Analysis (ATTA). [9]

In a study of the Nubian Sandstone Aquifer in Israel's Negev Desert, Yokochi and colleagues utilized radiokrypton (81Kr) to date groundwater, discovering two major water recharge events.[10] The first, about 38,000 years ago, originated from the Mediterranean, and the second, around 361,000 years ago, from the tropical Atlantic. These events, coinciding with periods of low orbital eccentricity, reveal the sensitivity of moisture transport to orbital forcing. The study highlights groundwater's potential as a record of ancient precipitation and long-term subsurface water storage.

Application of 81Kr to the Floridan Aquifer revealed freshwater recharge from the Last Glacial Period. Additionally, it detected fossil seawater predating the Last Glacial Maximum, indicating slow seawater movement and a limited but significant exchange of solutes with the ocean, contributing to the aquifer's dolomitization.

Yokochi also conducted experiments aimed at understanding how volatile elements are trapped in ices under conditions relevant to the formation of comets and icy moons.[11] [12] The results of those experiments showed that ice surfaces have heterogeneous adsorption energies, influenced by initial ice-deposition temperatures and thermal annealing. Adsorption sites with higher energy play a significant role at low pressures and higher temperatures, conditions relevant to the protosolar nebula. The experiments also showed that gas trapping occurs primarily through the burial of gas adsorbed on newly formed ice surfaces. Yokochi's experiments indicate that the formation temperature of comet 67P/Churyumov-Gerasimenko, as suggested by the observed Ar/H2O ratio, was around 40 K.

Yokochi contributed to the analysis of gases in samples returned from the Ryugu asteroid by JAXA's Hayabusa2 mission.[13] [14]

Awards and recognition

Yokochi received the Young Scientist Award from the Geochemistry Research Association of Japan in 2012; the same year, she was also named a NASA Planetary Science Early Career Fellow.[15]

Personal life

Reika Yokochi was married to Nicolas Dauphas, a fellow planetary scientist; the couple has two children. She died on February 17, 2024 from EGFR-driven lung cancer, a disease that disproportionately affects nonsmoking women of East asian ancestry.[16] Air pollution by particles less than 2.5 microns in diameter seems to be a factor contributing to the onset of EGFR-driven lung cancer.[17]

Notes and References

  1. Web site: Reika Yokochi . 2023-12-25 . . 2023-07-14 . https://web.archive.org/web/20230714064042/https://geosci.uchicago.edu/people/reika-yokochi/ . live .
  2. Web site: Reika Yokochi . 2023-12-25 . Google Scholar.
  3. L' azote, le néon et le xénon dans le manteau : sources, processus et hétérogénéités . . 2005-01-01 . PhD thesis . Reika . Yokochi . fr . 2023-12-25 . 2021-02-07 . https://web.archive.org/web/20210207114208/http://www.theses.fr/2005INPL045N . live .
  4. Lu . Z.-T. . Schlosser . P. . Smethie . W.M. . Sturchio . N.C. . Fischer . T.P. . Kennedy . B.M. . Purtschert . R. . Severinghaus . J.P. . Solomon . D.K. . Tanhua . T. . Yokochi . R. . 2014 . Tracer applications of noble gas radionuclides in the geosciences . Earth-Science Reviews . 138 . 196–214 . 1305.4608 . 2014ESRv..138..196L . 10.1016/j.earscirev.2013.09.002.
  5. Web site: Spizzirri . John . Lerner . Louise . 2019-07-29 . Krypton reveals ancient water beneath the Israeli desert . 2023-12-25 . . en . 2023-07-02 . https://web.archive.org/web/20230702233751/https://news.uchicago.edu/story/krypton-reveals-ancient-water-beneath-israeli-desert . live .
  6. Web site: Strongin . Ronni . 2019-07-30 . Krypton Reveals Ancient Water Beneath the Negev . 2023-12-25 . Americans for Ben-Gurion University . en-US.
  7. Web site: Mitchem . Savannah . 2021-09-30 . Scientists use nuclear physics to probe Floridan Aquifer threatened by climate change . 2023-12-25 . . en . 2023-02-09 . https://web.archive.org/web/20230209115551/https://www.anl.gov/article/scientists-use-nuclear-physics-to-probe-floridan-aquifer-threatened-by-climate-change . live .
  8. Yokochi . R. . Sturchio . N. C. . Purtschert . R. . Jiang . W. . Lu . Z. -T. . Mueller . P. . Yang . G. -M. . Kennedy . B. M. . Kharaka . Y. . 2013-02-15 . Noble gas radionuclides in Yellowstone geothermal gas emissions: A reconnaissance . Chemical Geology . Frontiers in Gas Geochemistry . 339 . 43–51 . 10.1016/j.chemgeo.2012.09.037 . 2013ChGeo.339...43Y . 0009-2541.
  9. Yokochi . Reika . Heraty . Linnea J. . Sturchio . Neil C. . Method for Purification of Krypton from Environmental Samples for Analysis of Radiokrypton Isotopes . Analytical Chemistry . 2008 . 80 . 22 . 8688–8693 . 10.1021/ac801804x . 18947236 .
  10. Yokochi . R. . Ram . R. . Zappala . J.C. . Jiang . W. . Adar . E. . Bernier . R. . Burg . A. . Dayan . U. . Lu . Z.T. . Mueller . P. . Purtschert . R. . 2019 . Radiokrypton unveils dual moisture sources of a deep desert aquifer . Proceedings of the National Academy of Sciences . 116 . 33 . 16222–16227. 10.1073/pnas.1904260116 . free . 31358637 . 6697870 . 2019PNAS..11616222Y .
  11. Yokochi . Reika . Marboeuf . Ulysse . Quirico . Eric . Schmitt . Bernard . Pressure dependent trace gas trapping in amorphous water ice at 77K: Implications for determining conditions of comet formation . Icarus . 218 . 2 . 760–770 . 2012 . 0019-1035 . 10.1016/j.icarus.2012.02.003. 2012Icar..218..760Y .
  12. Yokochi . Reika . Adsorption-driven Gas Trapping in Cometary Ice Analogs . The Astrophysical Journal . 940 . 2 . 153 . 2022 . 10.3847/1538-4357/ac9621 . American Astronomical Society. free . 2022ApJ...940..153Y .
  13. Web site: Lerner . Louise . 2022-06-09 . Scientists release first analysis of rocks plucked from speeding asteroid . 2023-12-25 . . en . 2023-07-02 . https://web.archive.org/web/20230702232404/https://news.uchicago.edu/story/scientists-release-first-analysis-rocks-plucked-speeding-asteroid . live .
  14. Okazaki . Ryuji . Marty . Bernard . Busemann . Henner . Hashizume . Ko . Gilmour . Jamie D. . Meshik . Alex . Yada . Toru . Kitajima . Fumio . Broadley . Michael W. . Byrne . David . Füri . Evelyn . Riebe . My E. I. . Krietsch . Daniela . Maden . Colin . Ishida . Akizumi . 2023-02-24 . Noble gases and nitrogen in samples of asteroid Ryugu record its volatile sources and recent surface evolution . Science . en . 379 . 6634 . eabo0431 . 10.1126/science.abo0431 . 36264828 . 2023Sci...379.0431O . 253045328 . 0036-8075 . 2023-12-25 . 2023-05-21 . https://web.archive.org/web/20230521060642/https://www.science.org/doi/10.1126/science.abo0431 . live .
  15. Web site: Reika Yokochi . 2023-12-25 . . 2022-04-18 . https://web.archive.org/web/20220418023348/http://yokochi.uchicago.edu/ . live .
  16. Lung cancer in never-smoker Asian females is driven by oncogenic mutations, most often involving EGFR . 2015 . 4467161 . Ha . S. Y. . Choi . S. J. . Cho . J. H. . Choi . H. J. . Lee . J. . Jung . K. . Irwin . D. . Liu . X. . Lira . M. E. . Mao . M. . Kim . H. K. . Choi . Y. S. . Shim . Y. M. . Park . W. Y. . Choi . Y. L. . Kim . J. . Oncotarget . 6 . 7 . 5465–5474 . 10.18632/oncotarget.2925 . 25760072 .
  17. Web site: Just 3 Years of Air Pollution Can Increase Lung Cancer Risk, Study Warns . ScienceAlert . 10 April 2023 . 2024-03-01.

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