Pierre Braunstein Explained

Pierre Braunstein (born 4 October 1947) is a French chemist. He was director of the Laboratoire de Chimie de Coordination (Coordination Chemistry Laboratory, CNRS-Université de Strasbourg) of Strasbourg (France) and is a member of the French Academy of Science.

Biography

He graduated from the École nationale supérieure de chimie de Mulhouse (with rank #1) in 1969 and then obtained his doctorate (Dr.Ing.) (under the supervision of J. Dehand) in inorganic chemistry from the Université Louis Pasteur (ULP) in Strasbourg in 1971. He spent the academic year 1971/72 as a post-doctoral fellow at University College London, with Professors Sir Ronald S. Nyholm and Robin J.H. Clark. After defending his state doctorate thesis at the ULP in 1974, he was awarded an Alexander-von-Humboldt fellowship to spend the academic year (1974/75) at the Technical University of Munich (TUM) with Professor Ernst Otto Fischer (Nobel Prize laureate).

He spent his entire career at the CNRS where he became an exceptional class Research Director. He has been Director of Research Emeritus since September 2014 and is also a professor "conventionné" at the University of Strasbourg.[1] [2] [3]

Notes and References

  1. « Pierre Braunstein », Angew. Chem. Intern. Ed., vol. 49, no 10, 2010, p. 1718, Coord. Chem. Rev., 2017, 350, p. 1-2, Coord. Chem. Rev., 2017, 350, p. 1-2
  2. Web site: Professor Pierre Braunstein.
  3. P. Braunstein, « Clusters moléculaires: matériaux, architectures, finalités », Nouv. J. Chim., 1986, 10, p. 365-368.
  4. P. Braunstein, « Metal-metal and metal-ligand interactions in heterometallic complexes », New J. Chem., 1994, 18, p. 51-60
  5. E. Sappa, A. Tiripicchio, P. Braunstein « Alkyne-substituted homo- and heterometallic carbonyl clusters of the iron, cobalt, and nickel triads », Chem. Rev., 1983, 83, p. 203-239
  6. E. Sappa, A. Tiripicchio, P. Braunstein, « Selective metal-ligand Interactions in heterometallic transition metal clusters », Coord. Chem. Rev, 1985, 65, p. 219-284
  7. P. Braunstein, J. Rosé « Gold in mimetallic molecular clusters. Their synthesis, bonding, chemical and catalytic reactivities », Gold Bull., 1985,18, p. 17-30
  8. S. Sculfort, P. Braunstein « Intramolecular d10 - d10 interactions in heterometallic clusters of the transition metals », Chem. Soc. Rev., 2011, 40, p. 2741-2760
  9. P. Braunstein, F. Naud « Hemilability of hybrid ligands and the coordination chemistry of oxazoline-based system », Angew. Chem. Int. Ed., 2001, 40, p. 680-699
  10. P. Braunstein, N. M. Boag « Alkyl, silyl, and phosphane ligands - classical ligands in nonclassical bonding modes », Angew. Chem. Int. Ed, 2001, 40, p. 2427-2433
  11. C. Fliedel, A. Ghisolfi, P. Braunstein, « Functional short-bite ligands: synthesis, coordination chemistry, and applications of N-functionalized bis(diaryl/dialkylphosphino) amine-type Ligands », Chem. Rev., 2016, 116, p. 9237-9304
  12. T. Simler, P. Braunstein, A. A. Danopoulos « Chromium(II) pincer complexes with dearomatized PNP and PNC ligands: A comparative study of their catalytic ethylene oligomerization activity », Organometallics, 2016, 35, p. 4044-4049 (front cover)
  13. S. Hameury, P. de Frémont, P. Braunstein « Metal complexes with oxygen-functionalized NHC ligands: synthesis and applications », Chem. Soc. Rev., 2017, 46, p. 632-733
  14. V. Charra, P. de Frémont, P. Braunstein « Multidentate N-heterocyclic carbene complexes of the 3d metals: synthesis, structure, reactivity and catalysis », Coord. Chem. Rev., 2017, 341, p. 53-176
  15. X. Ren, C. Gourlaouen, M. Wesolek, P. Braunstein « Tritopic NHC precursors: unusual nickel reactivity and ethylene insertion into a Csp3-H bond », Angew. Chem. Int. Ed., 2017, 56, p. 12557−12560
  16. P. Ai, K. Yu. Monakhov, J. van Leusen, P. Kögerler, C. Gourlaouen, M. Tromp, R. Welter, A. A. Danopoulos, P. Braunstein « Linear Cu2Pd, CuPd2 and Ag2Pd metal chains supported by rigid N,N’-diphosphanyl NHC ligands and metallophilic Interactions », Chem. Eur. J., 2018, 24,, p. 8787−8796 (front cover)
  17. X. Ren, M. Wesolek, P. Braunstein « Nickel(II) complexes with tritopic Nimine CNHCNamine pincer ligands », Chem. Eur. J., 2018, 24, p. 14794−1480
  18. A. A. Danopoulos, A. Massard, G. Frison, P. Braunstein « Iron and cobalt metallotropism in remote-substituted NHC ligands, metallation to abnormal NHC complexes or NHC ing opening », Angew. Chem. Int. Ed, 2018, 57, p. 14550−14554
  19. A. A. Danopoulos, T. Simler, P. Braunstein « N-Heterocyclic carbene complexes of copper, nickel and cobalt. », Chem. Rev., 2019, 119, p. 3730-3961
  20. P. Braunstein, « Bonding and organic and inorganic reactivity of metal-coordinated phosphinoenolates and related functional phosphine-derived anions », Chem. Rev., 2006, 106, p. 134-159
  21. P. Braunstein, D. Matt, D. Nobel « Reactions of carbon dioxide with C-C bond formation catalyzed by transition metal complexes », Chem. Rev., 1988, 88, p. 747-764
  22. P. Braunstein, D. Nobel « Transition metal mediated reactions of organic isocyanates », Chem. Rev., 1989, 89, p. 1927-1945
  23. P. Braunstein, M. Knorr « Reactivity of the metal-silicon bond in organometallic chemistry », J. Organomet. Chem., 1996, 500, p. 21-38
  24. P. Braunstein, M. Knorr, Ch. Stern « Bimetallic silicon chemistry: new opportunities in coordination and organometallic chemistry ". Coord.Chem. Rev. (Special Issue dedicated to the Inorganic Chemistry in France), 1998, 178-180, p. 903-965
  25. P. Braunstein, O. Siri, J.-P. Taquet, M.-M. Rohmer, M. Bénard, R. Welter « A 6π + 6π potentially antiaromatic zwitterion preferred to a quinoidal structure: Its reactivity towards organic and Inorganic reagents. », J. Am. Chem. Soc., 2003, 125, p. 12246-12256
  26. O. Siri, P. Braunstein, M.-M. Rohmer, M. Bénard, R. Welter « Novel « potentially antiaromatic », acidichromic quinonediimines with tunable delocalization of their 6π electron subunits », J. Am. Chem. Soc., 2003, 125, p. 13793-13803
  27. L. Routaboul, I. Tanabe, J. Colon Santana, M. Yuan, A. Ghisolfi, W. Serrano Garcia, P. A. Dowben, B. Doudin, P. Braunstein « Changes in molecular film metallicity with minor modifications of the constitutive quinonoid zwitterions », RSC Adv., 2017, 7, p. 21906-21917
  28. X. Zhang, P. S. Costa, J. Hooper, D. P. Miller, A. T. N’Diaye, S. Beniwal, X. Jiang, Y. Yin, P. Rosa, L. Routaboul, M. Gonidec, L. Poggini, P. Braunstein, B. Doudin, X. Xu, A. Enders, E. Zurek, P. A. Dowben « Locking and unlocking the molecular spin crossover transition », Adv. Mater., 2017, 29, p. 1702257
  29. P. Braunstein, X. Morise « Dehydrogenative coupling of hydrostannanes catalyzed by transition-metal complexes », Chem. Rev., 2000, 100, p. 3541-3552
  30. P. Braunstein, « Functional ligands and complexes for new structures, homogeneous catalysts and nanomaterials », J. Organomet. Chem., 2004, 689, p. 3953-3967 (special volume for the 40th anniversary of JOMC)
  31. F. Speiser, P. Braunstein, L. Saussine « Catalytic ethylene dimerization and oligomerization : recent developments with nickel complexes containing P,N-chelating ligands », Acc. Chem. Res., 2005, 38, p. 784-793
  32. A. Boudier, P.-A. R. Breuil, L. Magna, H. Olivier-Bourbigou, P. Braunstein « Ethylene oligomerization using iron complexes: beyond the discovery of bis(imino)pyridine ligands », Chem. Commun., 2014, 50, p. 1398-1407 (Feature article).
  33. P. Braunstein, J. Rosé « Heterometallic clusters in catalysis», in « metal clusters », in Chemistry, P. Braunstein, L. A. Oro and P. R. Raithby (Eds.); Wiley-VCH, Weinheim (Germany), 1999, vol. 2, p. 616-677
  34. P. Buchwalter, J. Rosé, P. Braunstein « Multimetallic catalysis based on heterometallic complexes and clusters », Chem. Rev., 2015, 115, p. 28-126
  35. Web site: List of Members. www.leopoldina.org. en. 2019-03-01.
  36. Web site: Academy of Europe: Braunstein Pierre. www.ae-info.org. 2019-03-01.
  37. Web site: European Academy of Sciences - List of Members. www.eurasc.org. 2019-03-01. https://web.archive.org/web/20101012014328/http://www.eurasc.org/members/members.asp?Cognome=b. 2010-10-12. dead.
  38. Fredy Speiser, Pierre Braunstein et Lucien Saussine, « Catalytic ethylene eimerization and oligomerization: Recent developments with nickel complexes containing P,N-chelating ligands », Acc.Chem. Res., vol. 38, no 10, 2005, p. 784–93 (PMID 16231874, DOI 10.1021/ar050040d)

    Scientific research

    His research focuses on the inorganic and organometallic chemistry of the transition metals and the main group elements, where he has (co-)authored of more than 580 scientific publications and review articles. They cover impressively diverse areas ranging from the study of metal-metal-bonded complexes, (hetero)nuclear complexes and atomic aggregates,[3] [4] multisite activation of organic substrates,[5] [6] heterometallic clusters with metallophilic interactions between metal ions with complete electronic shells,[7] [8] functional and hemilable ligands (with donor atoms N, P, O, S, N-heterocyclic carbenes,...)[9] [10] [11] [12] [13] [14] [15] [16] [17] [18] [19] phosphinoenolate complexes,[20] the activation of CO2 and organic isocyanates and their catalytic recovery,[21] [22] silylated ligands in a heterobimetallic environment,[23] [24] the study of original quinonoid zwitterions with delocalized organic π systems, which promote electronic communication between metal centres,[25] [26] and allow the modification of the electronic properties of the surfaces on which they are deposited.[27] [28] The applications of his work range from various homogeneous catalysis reactions,[29] [30] including the dehydrogenating coupling of stannanes, H-transfer reactions and ethylene oligomerization,[31] [32] to the first use of bimetallic nanoparticles derived from molecular clusters in heterogeneous catalysis.[33] [34]

    He has given more than 480 plenary lectures and invited guests to international conferences and institutions and has received numerous awards and honours from France, Germany, China, Italy, Japan, Portugal, Singapore, Spain, the Netherlands and the United Kingdom. He holds or has held many editorial positions and is regularly called upon to participate in the evaluation of major foreign research programs.

    Pierre Braunstein has mentored countless young scientists including ca. 70 PhD students and an equal number of post-doctoral researchers.

    He is a member of the French Academy of Sciences and the German Academy of Sciences Leopoldina,[35] a corresponding member of the Zaragoza Academy of Sciences (Spain) and the Lisbon Academy of Sciences (Portugal). He is also a member of the Academia Europaea[36] and the European Academy of Sciences.[37] Since 2015, he is head of the Chemical Sciences Division of the European Academy of Sciences.

    Distinctions

    Prizes

    • Prize of the Division of Physical and Mineral Chemistry of the French Chemical Society 1975
    • Aumale Prize of the French Institute on the proposal of the French Academy of Sciences, 1983
    • Alexander-von-Humboldt Forschungspreis, 1988
    • Silver medal of the CNRS, 1989
    • Max-Planck Forschungspreis (jointly with H. Vahrenkamp, Germany), 1991
    • Raymond Beer Grand Prize of the French Chemical Society 1995
    • 1st winner of the Paul Sabatier - Miguel Catalán Franco-Spanish Prize between the French Chemical Society and the Royal Spanish Chemical Society, 1998
    • Grignard - Georg Wittig Prize between the French Chemical Society and the Gesellschaft Deutscher Chemiker, 1999
    • Otto-Warburg Prize (Germany) 2002
    • Visiting Professor at the Academia Sinica Taipei, Taipei (Taiwan), 2002
    • Grand Prize of the French Institute of Petroleum (IFPEN) of the French Academy of Sciences, 2004
    • Descartes-Huygens Prize (Dutch Academy of Sciences), 2008
    • International Prize of the Japanese Society of Coordination Chemistry, 2013
    • Prize of the International Foundation for Organic Chemistry (Kyoto, Japan), 2013
    • Pierre Süe Grand Prize of the French Chemical Sociéty, 2013
    • Sacconi Medal (Italian Chemical Society), 2013
    • 1st Awardee of the Portugal-France Chemistry Bilateral Lectureship Award between the Sociedade Portuguesa de Química and the French Chemical Society, 2019
    • China-France Chemistry Bilateral Lectureship Award between the Chinese Chemical Society and the French Chemical Society, 2020
    • European Prize for Organometallic Chemistry of the European Chemical Society (EuChemS), Division of Organometallic Chemistry, 2021

    Honours

    • Visiting Professor at the Faculty of Chemistry, University of Konstanz (Germany), 1984
    • 1st Great Manchester Inorganic Chemistry Conference - UMIST - Manchester (United Kingdom), 1985
    • Weissberger Williams Lecture - Kodak Research Laboratories - Rochester (United States), 1986
    • John van Geuns Lecture, Amsterdam (Netherlands), 1993
    • Fellow of the Japanese Society for the Promotion of Science - Tokyo, Japan, 1997
    • Chini Memorial Lecture (Italian Chemical Society), 2003
    • Nyholm Lecture and Medal (Royal Society of Chemistry), 2003
    • Molecular Science Forum Lecture Professorship, Chinese Academy of Sciences, Beijing, China, 2006
    • Distinguished Visiting Scientist, Institute of Materials and Engineering. A*STAR, Singapore, 2013-2017
    • Named "Technische Universität Munich (TUM) Ambassador" (1st promotion), 2013
    • Elected Head of the Chemistry Division of the European Academy of Sciences, 2015
    • Visiting Professor at Qingdao University of Science and Technology, China, 2016 - 2019
    • Qiushi Chair Professor of the University of Zhejiang, China, 2017- 2019
    • Professor Chair at Suzhou University (China), 2017-2020
    • Appointed Academic "Master" of the "111Project" Rubber-Plastics Materials and Engineering Overseas Expertise Introduction Center for Discipline Innovation, Qingdao University of Science en Technology, China, 2017-2022
    • Distinguish Honorary Professor at Yangzhou University (China), 2018-2022.
    • Distinguished Visiting Scholar, University of Hong-Kong, 2018
    • “Tongji Master Lecture”, Tongji University (China), 2019
    • Distinguished professor, Zhejiang University (China), 2019-2024

    Learned Societies - Academies

    • Fellow of the Royal Society of Chemistry (CChem FRSC), 1996
    • Membre correspondant of the French Academy of Sciences, 1993
    • Corresponding member of the Academy of Sciences of Zaragoza (Spain), 2002
    • Member of the Academia Europaea, 2002
    • Member of the European Academy of Sciences, 2002
    • Member of the German National Academy of Sciences Leopoldina, 2005
    • Member of the French Academy of Sciences, 2005
    • Distinguished member of the French Chemical Society (1st promotion), 2013
    • Foreign corresponding member of the Lisbon Academy of Sciences (Portugal), 2015

    Decorations

    References

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