| Nikolay Semyonov | |
| Native Name Lang: | ru |
| Birth Name: | Nikolay Nikolayevich Semyonov |
| Birth Place: | Saratov, Saratov Governorate, Russian Empire |
| Death Place: | Moscow, Russian SFSR, Soviet Union |
| Nationality: | Russian |
| Field: | Physics, chemistry |
| Doctoral Advisor: | Abram Ioffe |
| Doctoral Students: | David A. Frank-Kamenetskii |
| Known For: | chemical transformation |
Nikolay Nikolayevich Semyonov , sometimes Semenov, Semionov or Semenoff[1] (Russian: Никола́й Никола́евич Семёнов; – 25 September 1986) was a Soviet physicist and chemist. Semyonov was awarded the 1956 Nobel Prize in Chemistry for his work on the mechanism of chemical transformation.
Semyonov was born in Saratov, the son of Elena Dmitrieva and Nikolai Alex Semyonov.[2] He graduated from the department of physics of Petrograd University (1913–1917), where he was a student of Abram Fyodorovich Ioffe. In 1918, he moved to Samara, where he was enlisted into Kolchak's White Army during Russian Civil War.
Semyonov published his first research paper in 1916 and became a lecturer at the University of Tomsk in western Siberia.
After graduating from Saint Petersburg State University, he worked as an assistant and lecturer at the Tomsk and Tomsk University Institute of Technology, where he published his first research paper in 1916. He returned to western Siberia, Petrograd and took charge of the electron phenomena laboratory of the Petrograd Physico-Technical Institute in 1920. He also became the vice-director of the institute. In 1921, he married philologist Maria Boreishe-Liverovsky (student of Zhirmunsky). She died two years later. On September 15-1924, Nikolay married Maria's niece, Natalia Nikolaevna Burtseva. They had two children, one son Yurii Nikolaevich and one daughter Ludmilla Nikolaevna.
During that difficult time, Semyonov, together with Pyotr Kapitsa, discovered a way to measure the magnetic field of an atomic nucleus (1922). Later the experimental setup was improved by Otto Stern and Walther Gerlach and became known as Stern–Gerlach experiment.
In 1925, Semyonov, together with Yakov Frenkel, studied kinetics of condensation and adsorption of vapors. In 1927, he studied ionisation in gases and published an important book, Chemistry of the Electron. In 1928, he, together with Vladimir Fock, created a theory of thermal disruptive discharge of dielectrics.
In 1927, Semyonov studied the ionization of gases, the chemistry of the electron. In 1928, he created the theory of the broken discharge of dielectrics with Vladimir Fock.
He lectured at the Petrograd Polytechnical Institute and was appointed Professor in 1928. In 1931, he organized the Institute of Physical Chemistry of the USSR Academy of Sciences (which moved to Chernogolovka in 1943) and became its first director. In 1932, he became a full member of the Soviet Academy of Sciences.
The ideas of Semyonov have been applied in the science of reaction and production of polymerization reactions. His ideas are also applied in catalysis studies in biological systems.
Semyonov married Natalya Nikolaevna Semyonov and together they both have a son and a daughter.Semyonov died on September 25, 1986, in Moscow, and was buried at the Novodevichy Cemetery.
Semyonov's outstanding work on the mechanism of chemical transformation includes an exhaustive analysis of the application of the chain theory to varied reactions (1934–1954) and, more significantly, to combustion processes. He proposed a theory of degenerate branching, which led to a better understanding of the phenomena associated with the induction periods of oxidation processes. He spent most of his career focusing and developing the field of chemical chain reactions.
Semyonov wrote two important books outlining his work. Chemical Kinetics and Chain Reactions was published in 1934, with an English edition in 1935. It was the first book in the U.S.S.R. to develop a detailed theory of unbranched and branched chain reactions in chemistry. Some Problems of Chemical Kinetics and Reactivity, first published in 1954, was revised in 1958; there are also English, American, German, and Chinese editions. He is the only Soviet/Russian Chemistry Nobel Laureate, who received the Nobel Prize in Chemistry (together with Sir Cyril Norman Hinshelwood) for his work in 1956.
Semyonov had long been a supporter of the Communist Party and the Soviet Union. After the Bulletin of the Atomic Scientists accused the Soviet Union of heavy scientific censorship in 1953, he coauthored the Soviet response which denied all accusations. He is also noted as being the most famous signatory to a 1971 public letter from Soviet scientists to United States president Richard Nixon, on displeasure in the murder trial of Angela Davis.
Semyonov trained Russian organometallic chemist Alexandr Shilov, who discovered platinum catalyzed C-H activation.
Semyonov was also an Honorary Doctor of several universities: Oxford (1960), Brussels (1962), London (1965), Budapest Technical University (1965), Polytechnic Institute of Milan (1964) and others.