Neodymium-doped yttrium orthovanadate explained

Neodymium-doped yttrium orthovanadate (Nd:YVO₄) is a crystalline material formed by adding neodymium ions to yttrium orthovanadate. It is commonly used as an active laser medium for diode-pumped solid-state lasers. It comes as a transparent blue-tinted material. It is birefringent, therefore rods made of it are usually rectangular.

As in all neodymium-doped laser crystals, the lasing action of Nd:YVO₄ is due to its content of neodymium ions, which may be excited by visible or infrared light, and undergo an electronic transition resulting in emission of coherent infrared light at a lower frequency, usually at 1064 nm (other transitions in Nd are available, and can be selected for by external optics).

Basic properties

• Atomic density

~1.37×10²⁰ atoms/cm³

• Crystal structure

• • zircon tetragonal (tetragonal bipyramidal)
  • space group D_4h
  • a=b=7.12, c=6.29
• Density

4.22 g/cm³

• Mohs hardness

Glass-like, ~5

• Thermal expansion coefficient

• • α_a=4.43×10⁻⁶/K
  • α_c=11.37×10⁻⁶/K
• Thermal conductivity

• • parallel to C-axis: 5.23 W·m⁻¹·K⁻¹
  • perpendicular to C-axis: 5.10 W·m⁻¹·K⁻¹

Optical properties

• Lasing wavelengths: 914 nm, 1064 nm, 1342 nm
• Crystal class: positive uniaxial, n_o=n_a=n_b, n_e=n_c,
  • n_o=1.9573, n_e=2.1652, at 1064 nm
  • n_o=1.9721, n_e=2.1858, at 808 nm
  • n_o=2.0210, n_e=2.2560, at 532 nm
• Fluorescence lifetime (spontaneous emission lifetime) as a function of Nd ions concentration:

Nd concentration (atom %)	Fluorescence lifetime (μs)@ 1064 nm	Reference
0.4	110	J. Appl. Phys. 49, 5517-5522 (1978).
1.0	100	Castech web site
1.1	90	Casix web site
2.0	50	Casix web site

• Absorption cross-section at 808 nm: 5.5×10⁻²⁰ cm²
• Emission cross-section at 1064 nm: 30×10⁻¹⁹ cm² (Reference: JOSA 66, 1405-1414 (1976).)
• Polarized laser emission: π-polarization; parallel to optic axis (c-axis) (for a-cut crystal)
• Gain-bandwidth

0.96 nm (257 GHz) at 1064 nm (for 1.1 atm% Nd doped)

• Absorption coefficients at 808 nm for different doping concentrations:

See also

• Yttrium aluminium garnet (YAG)

References

• Infrared Spectral Emittance and Optical Properties of Yttrium Vanadate . H. E. Rast . H. H. Caspers . S. A. Miller . amp . Phys. Rev. . 169 . 3 . 705–709 . 1968 . 10.1103/PhysRev.169.705 . abstract . 1968PhRv..169..705R .
• Correlation between rare-earth oscillator strengths and rare-earth–valence-band interactions in neodymium-doped YMO4 (M=V, P, As), Y3Al5O12, and LiYF4 matrices . O. Guillot-Noel . B. Bellamy . B. Viana . D. Gourier . Phys. Rev. B . 60 . 3 . 1668–1677 . 1999 . 10.1103/PhysRevB.60.1668 . abstract . 1999PhRvB..60.1668G .