N-philes explained

N-philes are group of radical molecules which are specifically attracted to the C=N bonds, defying often the selectivity rules of electrophilic attack. N-philes can often masquerade as electrophiles, where acyl radicals are excellent examples which interact with pi electrons of aryl groups.

References

• 2338–9 . 10.1039/B207729A . 5-Azahexenoyl radicals cyclize via nucleophilic addition to the acyl carbon rather than 5-exo homolytic addition at the imine . 2002 . Falzon . Chantal T. . Ryu . Ilhyong . Schiesser . Carl H. . Chemical Communications . 20 . 12430429.