N-Vinylpyrrolidone Explained

N-Vinylpyrrolidone (NVP) is an organic compound consisting of a 5-membered lactam ring linked to a (2 carbon) vinyl group. It is a colorless liquid although commercial samples can appear yellowish.

It is produced industrially by vinylation of 2-pyrrolidone, i.e. the base-catalyzed reaction with acetylene. It is the precursor to polyvinylpyrrolidone (PVP), an important synthetic material. The NVP monomer is commonly used as a reactive diluent in ultraviolet and electron-beam curable polymers applied as inks, coatings or adhesives.

Synthesis

Starting from γ-Butyrolactone, 2-pyrrolidone is synthesized by treatment with ammonia.[1] Subsequently, acetylene is used to introduce the vinyl group.[2]

See also

References

  1. Teodorescu . Mirela . Bercea . Maria . Poly(vinylpyrrolidone) – A Versatile Polymer for Biomedical and Beyond Medical Applications . Polymer-Plastics Technology and Engineering . 23 June 2015 . 54 . 9 . 923–943 . 10.1080/03602559.2014.979506.
  2. Encyclopedia: 10.1002/14356007.a01_097.pub3. Ullmann's Encyclopedia of Industrial Chemistry. 2008. Pässler. Peter. Hefner. Acetylene Chemistry. Werner. Buckl. Klaus. Meinass. Helmut. Meiswinkel. Andreas. Wernicke. Hans-Jürgen. Ebersberg. Günter. Müller. Richard. Bässler. Jürgen. Behringer. Hartmut. Mayer. Dieter. 3527306730.

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