Metal-phenolic network explained

A metal-phenolic network (MPN) is a supramolecular coordination compound that is derived from metal ions and polyphenols that can be deposited onto nearly any surface.[1] [2] MPNs adsorb to a wide variety of surfaces due to noncovalent forces.[3] Possible applications of MPN-based materials include drug delivery, bioimaging, biotechnology, and electrocatalysis.[4] [5] For example, they have been commercialized as antimicrobial and anti-odor coatings under the trade name "SWIFF"[6]

Notes and References

  1. One-Step Assembly of Coordination Complexes for Versatile Film and Particle Engineering. Science. 12. 154–7. 10.1126/science.1237265. 2013. 341. 23846899. Hirotaka Ejima . Joseph J. Richardson . Kang Liang . James P. Best . Martin P. van Koeverden . Georgina K. Such . Jiwei Cui . Frank Caruso . 2013Sci...341..154E. 11343/197428. 26054362. free.
  2. Guo. Junling. Ping. Yuan. Ejima. Hirotaka. Alt. Karen. Meissner. Mirko. Richardson. Joseph J.. Yan. Yan. Peter. Karlheinz. von Elverfeldt. Dominik. Hagemeyer. Christoph E.. Caruso. Frank. Engineering Multifunctional Capsules through the Assembly of Metal-Phenolic Networks. Angewandte Chemie International Edition. 26 May 2014. 53. 22. 5546–5551. 10.1002/anie.201311136. 24700671. 11343/115252. free.
  3. Ejima. Hirotaka. Richardson. Joseph J.. Caruso. Frank. 2017-02-01. Metal-phenolic networks as a versatile platform to engineer nanomaterials and biointerfaces. Nano Today. 12. 136–148. 10.1016/j.nantod.2016.12.012. 11343/127237. free.
  4. Kim . Nayeong . Lee . Inhui . Choi . Yuri . Ryu . Jungki . 2021 . Molecular design of heterogeneous electrocatalysts using tannic acid-derived metal–phenolic networks . Nanoscale . en . 13 . 48 . 20374–20386 . 10.1039/D1NR05901G . 34731231 . 239977371 . 2040-3364.
  5. Guo. Junling. Tardy. Blaise L.. Christofferson. Andrew J.. Dai. Yunlu. Richardson. Joseph J.. Zhu. Wei. Hu. Ming. Ju. Yi. Cui. Jiwei. Dagastine. Raymond R.. Yarovsky. Irene. Caruso. Frank. Modular assembly of superstructures from polyphenol-functionalized building blocks. Nature Nanotechnology. 11. 12. 1105–1111. 10 October 2016. 10.1038/nnano.2016.172. 27723730. 2016NatNa..11.1105G. 11343/120178. free.
  6. www.swiffspray.com

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