Mellite Explained

Mellite should not be confused with Melilite.

Mellite
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Category:Organic minerals
Formula:Al2[C<sub>6</sub>(COO)<sub>6</sub>]·16H2O
Imasymbol:Mel[1]
Strunz:10.AC.05
System:Tetragonal
Class:Ditetragonal dipyramidal (4/mmm)
H-M symbol: (4/m 2/m 2/m)
Symmetry:I41/acd
Unit Cell:a = 15.53 Å, c = 23.19 Å; Z = 8
Color:Honey-yellow, deep red, pale shades of red, brown, gray, white;
Habit:Elongated bipyramidal prismatic; as nodules and coatings, fine-grained massive
Cleavage:poor/indistinct on
Fracture:conchoidal
Tenacity:Slightly sectile
Mohs:2-
Luster:Vitreous, resinous, greasy
Streak:White
Diaphaneity:Transparent to translucent
Gravity:1.64
Opticalprop:Uniaxial (-) may be anomalously biaxial
Refractive:nω = 1.539 nε = 1.511
Birefringence:δ = 0.028
Pleochroism:Weak; O = yellowish brown; E = yellow
Fluorescence:Pale yellow to blue (LW & SW UV)
Other:Pyroelectric

Mellite, also called honeystone, is an unusual mineral being also an organic chemical. It is chemically identified as an aluminium salt of mellitic acid, and specifically as aluminium benzenehexacarboxylate hexadecahydrate, with the chemical formula Al2C6(COO)6·16H2O.[2]

It is a translucent honey-coloured crystal which can be polished and faceted to form striking gemstones. It crystallizes in the tetragonal system and occurs both in good crystals and as formless masses. It is soft with a Mohs hardness of 2 to 2.5 and has a low specific gravity of 1.6.[3] [2]

It was discovered originally in 1789 at Artern in Thuringia, Germany. It has subsequently also been found in Russia, Austria, the Czech Republic, and Hungary. It was named from the Greek Greek, Ancient (to 1453);: μέλι meli "honey",[4] in allusion to its color.[5]

It is found associated with lignite and is assumed to be formed from plant material with aluminium derived from clay.[3]

Structure

The crystal structure of mellite has been determined by neutron diffraction and consists of slightly distorted Al(H2O)63+ octahedra linked by hydrogen bonds to [C<sub>6</sub>(COO)<sub>6</sub>]6− mellitate anions and water of crystallization.[6]

See also

Notes and References

  1. Warr. L.N.. 2021. IMA–CNMNC approved mineral symbols. Mineralogical Magazine. 85. 3. 291–320. 10.1180/mgm.2021.43. 2021MinM...85..291W. 235729616. free.
  2. http://webmineral.com/data/Mellite.shtml Webmineral data
  3. http://rruff.geo.arizona.edu/doclib/hom/mellite.pdf Handbook of Mineralogy
  4. .
  5. Web site: Mellite.
  6. Christian . Robl . Werner F. . Kuhs . A neutron diffraction study on hydrogen bonding in the mineral mellite (Al2[C<sub>6</sub>(COO)<sub>6</sub>] · 16H2O) at 15 K . . 1991 . 92 . 1 . 101–109 . 10.1016/0022-4596(91)90246-E . 1991JSSCh..92..101R .