Andradite Explained

Andradite [Adr]
Category:Garnet group
Formula:Ca3Fe2(SiO4)3
Imasymbol:Adr[1]
Strunz:9.AD.25
System:Cubic
Class:Hexoctahedral (mm)
H-M symbol: (4/m 2/m)
Symmetry:Iad
Unit Cell:a = 12.056 Å; Z = 8
Color:Yellow, greenish yellow to emerald-green, dark green; brown, brownish red, brownish yellow; grayish black, black; may be sectored
Habit:Commonly well-crystallized dodecahedra, trapezohedra, or combinations, also granular to massive
Cleavage:none
Fracture:conchoidal to uneven
Tenacity:Brittle
Mohs:6.5 to 7
Luster:Adamantine to resinous, dull
Diaphaneity:Transparent to translucent
Refractive:n = 1.887
Opticalprop:Isotropic, typically weakly anisotropic
Absorption:demantoid – 440nm band or complete absorption at 440nm and below, may also have lines at 618, 634, 685, 690nm
Streak:White
Gravity:3.859 calculated; 3.8–3.9 measured
References:[2] [3] [4] [5]
Var1text:transparent light to dark green to yellow-green
Var2:Melanite
Var2text:opaque black
Var3:Topazolite
Var3text:transparent to translucent yellow, may show chatoyancy

Andradite is a mineral species of the garnet group. It is a nesosilicate, with formula Ca3Fe2Si3O12.

Andradite includes three varieties:

It was first described in 1868 for an occurrence in Drammen, Buskerud, Norway.[3] [4] [7] Andradite was named after the Brazilian statesman, naturalist, professor and poet José Bonifácio de Andrada e Silva (1763–1838).[3] [7]

Occurrence

It occurs in skarns developed in contact metamorphosed impure limestones or calcic igneous rocks; in chlorite schists and serpentinites and in alkalic igneous rocks (typically titaniferous). Associated minerals include vesuvianite, chlorite, epidote, spinel, calcite, dolomite and magnetite.[3] It is found in Iran, Italy, the Ural Mountains of Russia, Arizona and California and in Dnipropetrovsk Oblast in Ukraine.

Like the other garnets, andradite crystallizes in the cubic space group 3}}d, with unit-cell parameter of 12.051 Å at 100 K.[9]

The spin structure of andradite contains two mutually canted equivalent antiferromagnetic sublattices[10] below the Néel temperature (TN=11 K[11]).

See also

Notes and References

  1. Warr. L.N.. 2021. IMA–CNMNC approved mineral symbols. Mineralogical Magazine. 85. 3 . 291–320. 10.1180/mgm.2021.43 . 2021MinM...85..291W . 235729616 . free.
  2. Gemological Institute of America, GIA Gem Reference Guide 1995,
  3. Handbook of Mineralogy
  4. http://www.mindat.org/min-223.html Andradite
  5. http://www.webmineral.com/data/Andradite.shtml Webmineral data
  6. Olga Bortnik. All about precious stones. ― Moscow: Harvest, 2011.
  7. Book: Grande . Lance . Augustyn . Allison . Gems and Gemstones: Timeless Natural Beauty of the Mineral World . University of Chicago Press . 2009 . 188–91 . 978-0-226-30511-0.
  8. http://www.mindat.org/min-7443.html Melanite
  9. Thomas Armbruster and Charles A. Geiger (1993): "Andradite crystal chemistry, dynamic X-site disorder and structural strain in silicate garnets." European Journal of Mineralogy v. 5, no. 1, p. 59-71.
  10. Danylo Zherebetskyy (2010). Quantum mechanical first principles calculations of the electronic and magnetic structure of Fe-bearing rock-forming silicates, PhD Thesis, Universal Publishers/Dissertation.com, Boca Raton, Florida, USA, p. 136. .
  11. Enver Murad (1984): "Magnetic ordering in andradite." American Mineralogist 69, no. 7-8; pp. 722–24.