Masataka Ogawa Explained

Masataka Ogawa
Native Name:小川 正孝
Native Name Lang:ja
Birth Date:1865 2, df=yes
Birth Place:Edo, Tokugawa shogunate
Death Place:Sendai, Empire of Japan
Fields:Chemistry
Workplaces:Tohoku Imperial University
Alma Mater:Imperial University
Known For:Discovery of rhenium
Awards:Sakurai Prize
Order of the Sacred Treasure, 2nd class (1925)
Member of the Imperial Court, Senior Third Rank (1928)

was a Japanese chemist mainly known for the claimed discovery of element 43 (later known as technetium), which he named nipponium. In fact, he had discovered, but misidentified, element 75 (later called rhenium).[1] [2]

After graduating from the University of Tokyo, he studied under William Ramsay in London, where he worked on the analysis of the rare mineral thorianite. He extracted and isolated a small amount of an apparently unknown substance from the mineral, which he announced as the discovery of element 43, naming the newly discovered element nipponium. He published his results in 1909 and a notice was also published in the Journal of the American Chemical Society.[3] For this work, he was awarded a doctorate and the highest prize of the Tokyo Chemical Society. However, no other researchers were able to replicate his discovery, and the announcement was forgotten.[4]

Ogawa served as president of Tohoku University between 1919 and 1928.[5] While the name nipponium could not be reused for another element, element 113 was also discovered by a team of Japanese scientists and is now named nihonium, also after Japan. The name was chosen in respectful homage to Ogawa's work.[6]

Notes and References

  1. Yoshihara . H. K. . 2004 . Discovery of a new element 'nipponium': re-evaluation of pioneering works of Masataka Ogawa and his son Eijiro Ogawa . . 59 . 8 . 1305–1310 . 2004AcSpe..59.1305Y . 10.1016/j.sab.2003.12.027.
  2. Hisamatsu . Yoji . Egashira . Kazuhiro . Yoshiteru . Maeno . 2022 . Ogawa’s nipponium and its re-assignment to rhenium . Foundations of Chemistry . 24 . 15–57 . 10.1007/s10698-021-09410-x . 16 November 2023. free .
  3. Howe . J. S. . 1909 . Recent Work in Inorganic Chemistry . . 31 . 12 . 1284–1305 . 10.1021/ja01942a006.
  4. Web site: Kaji . M. . A discovery which served as a foothold . St. Petersburg: Through Centuries . 2016-03-11.
  5. http://www.sci.tohoku.ac.jp/sci-aniv100/index.html Tohoku University Faculty of Science 100th Anniversary page
  6. Öhrström . Lars . Reedijk . Jan . 28 November 2016 . Names and symbols of the elements with atomic numbers 113, 115, 117 and 118 (IUPAC Recommendations 2016) . Pure Appl. Chem. . 88 . 12 . 1225–1229 . 10.1515/pac-2016-0501 . 22 April 2017. 1887/47427 . 99429711 . free .