Lithium tellurite explained

Lithium tellurite is an inorganic compound, with the chemical formula Li2TeO3. It crystallises in the monoclinic crystal system, with space group C2/c.[1] It can be prepared by reacting lithium oxide,[2] lithium hydroxide[3] or lithium carbonate[4] with tellurium dioxide. It reacts with lithium fluoride at high temperatures in a 3:1 stoichiometric ratio to obtain Li7(TeO3)3F.

Notes and References

  1. Folger, F. Crystal structure of lithium tellurate(IV). Zeitschrift fuer Anorganische und Allgemeine Chemie, 1975. 411 (2): 103-110. ISSN: 0044-2313.
  2. Moret, Jacques; Cachau-Herreillat, Danielle; Norbert, Alain; Maurin, Maurice. Lithium oxide-tellurium dioxide system. Comptes Rendus des Seances de l'Academie des Sciences, Serie C: Sciences Chimiques, 1971. 272 (23): 1870-1873. ISSN: 0567-6541.
  3. Breusov, O.N.; Revzina, T. V.; Druz, N. A. Synthesis and some properties of lithium tellurite. Zhurnal Neorganicheskoi Khimii, 1965. 10 (9): 1990-1992. ISSN: 0044-457X.
  4. Inorganic Chemistry. 56. 23. en. 0020-1669. 2017-12-04. 14697–14705. 10.1021/acs.inorgchem.7b02670. Li 7 (TeO 3) 3 F: A Lithium Fluoride Tellurite with Large Second Harmonic Generation Responses and a Short Ultraviolet Cutoff Edge. 2021-03-19. Jiang-He Feng, Chun-Li Hu, Hou-Ping Xia, Fang Kong, Jiang-Gao Mao. 29131609 . 2020-07-09. https://web.archive.org/web/20200709103251/https://pubs.acs.org/doi/10.1021/acs.inorgchem.7b02670. live.

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