| Picture | Name | Notes | Period |
|---|
| | | 1823–1825 |
| | | 1825–1850 |
| Manuel Montt Torres | | 1850–1851 |
| | | 1851–1855 |
| | | 1855–1861 |
| | | 1861–1880 |
| | | 1880–1881 |
| | | 1882 |
| | | 1883 |
| | | 1884 |
| | | 1885 |
| | | 1886 |
| | | 1887 |
| | | 1888 |
| | | 1889–1890 |
| | | 1891 |
| | | 1891–1892 |
| | | 1893 |
| | | 1894 |
| | | 1895 |
| | | 1896 |
| | | 1897 |
| | | 1898 |
| | | 1899 |
| | | 1900 |
| | | 1901 |
| | | 1902 |
| | | 1903 |
| | | 1904 |
| | | 1905 |
| | | 1906 |
| | | 1907 |
| | | 1908 |
| | | 1909 |
| | | 1910 |
| | | 1911 |
| | | 1912 |
| | | 1913 |
| | | 1914 |
| | | 1915 |
| | | 1916 |
| | | 1917 |
| | | 1918 |
| | | 1919–1922 |
| | | 1922–1925 |
| | | 1925–1927 |
| | | 1927 |
| | | 1927–1929 |
| | | 1929–1931 |
| | | 1931–1932 |
| | | 1932–1934 |
| | | 1934–1937 |
| | | 1938–1940 |
| | | 1940–1943 |
| | | 1944–1950 |
| | | 1951–1954 |
| | | 1954–1957 |
| | | 1957–1960 |
| | | 1960–1963 |
| | | 1963–1966 |
| | | 1966–1969 |
| | | 1962–1972 |
| | | 1972–1975 |
| | | 1975–1978 |
| | | 1978–1983 |
| | | 1983–1988 |
| | | 1988–1991 |
| | | 1991–1993 |
| Marcos Aburto Ochoa | | 1993–1995 |
| | | 1996–1997 |
| | | 1998–1999 |
| | | 2000–2001 |
| | | 2002–2003 |
| | | 2004–2005 |
| | | 2006 – January 6, 2008 |
| | | January 6, 2008 – December 18, 2009 |
| | | December 18, 2009 – January 6, 2012 |
| | | January 6, 2012 – January 5, 2014 |
| Sergio Muñoz Gajardo | | January 6, 2014 – January 5, 2016 |
| Hugo Dolmestch Urra[1] | | January 5, 2016 – January 8, 2018 |
| [2] | | January 8, 2018 – 2019 |
| | | January 6, 2020 – 2022 |
| Juan Eduardo Fuentes Belmar | | 2022 – present | |
