| Appointment | Name | Notes (GCH denotes Grand Cross of the order) |
|---|
| 1815 | Colonel Hugh Halkett | Promoted GCH 1851 |
| 1815 | Major-General Sir James Frederick Lyon | Promoted GCH 1817 |
| 1815 | Major-General Sir Colin Halkett | Promoted GCH 1820 |
| 1815 | Major-General Sir Benjamin Bloomfield | Promoted GCH 1819, later Baron Bloomfield |
| 1816 | Major-General Sir Colquhoun Grant | Promoted GCH 1831 |
| 1816 | Major-General Sir Richard Hussey Vivian, Bart. | Promoted GCH 1831, later Baron Vivian |
| 1816 | Colonel Sir George Adam Wood | |
| 1816 | Sir William Congreve, Bart. | |
| 1817 | Colonel Sir William Robe | |
| 1817 | Major-General Francis de Rottenburg | |
| 1817 | Major-General Sir Alexander Dickson | |
| 1818 | Rear Admiral Sir Home Riggs Popham | |
| 1818 | Colonel Sir Benjamin D'Urban | |
| 1819 | Lieutenant-General Sir Tomkyns Hilgrove Turner | Promoted GCH 1827 |
| 1819 | Major-General Sir John Elley | |
| 1819 | Major-General Sir Herbert Taylor | Promoted GCH 1825 |
| 1819 | Captain The Honourable Charles Paget | Promoted GCH 1832 |
| 1819 | Major-General Sir Andrew Francis Barnard | Promoted GCH 1833 |
| 1820 | Major-General George Airey | |
| 1820 | Lieutenant-Colonel Sir Robert William Gardiner | |
| 1820 | Major-General James Murray, 1st Baron Glenlyon | |
| 1821 | Major-General Sir Charles William Doyle | Promoted GCH 1837 |
| 1821 | Lieutenant Lord Francis Conyngham | Promoted GCH 1823, later 2nd Marquess Conyngham |
| 1821 | Sir William Knighton, Bart. | Physician to the King, promoted GCH 1823 |
| 1821 | Major-General Sir Edward Kerrison, Bart. | Promoted GCH 1831 |
| 1821 | Lieutenant-General Sir Samuel Ford Whittingham | |
| 1821 | Major-General Sir George Augustus Quentin | |
| 1821 | Major-General Sir William Keir Grant | Promoted GCH 1835 |
| 1821 | Colonel Henry Frederick Cooke | |
| 1822 | Lieutenant-General Sir Richard Church | Promoted GCH 1837 |
| 1822 | The Honourable Francis Nathaniel Burton | Promoted GCH 1824 |
| 1824 | Colonel Sir James Henry Reynett | |
| 1824 | Lieutenant-Colonel Sir John Harvey | |
| 1825 | Sir Henry Halford, Bart., | (civil division) Promoted GCH 1830 |
| 1827 | Sir Frederick Beilby Watson | (civil division) |
| 1827 | Sir Jonathan Wathen-Waller, Bart. | (civil division) Promoted GCH 1830 |
| 1827 | Sir John Conroy, Bart. | (civil division) Comptroller and Private Secretary to the Duchess of Kent |
| 1828 | Frederick Augusta Barnard | Librarian to the King |
| 1828 | Captain The Honourable Robert Cavendish Spencer | Private Secretary to the Duke of Clarence |
| 1829 | Major-General Sir James Carmichael Smyth, Bart | |
| 1829 | Lord Albert Conyngham | (civil division) Secretary of Legation at Berlin, later Baron Londesborough |
| 1829 | Colonel Sir Augustus Frederick d'Este | (civil division) |
| 1830 | Colonel Sir Willoughby Cotton | |
| 1830 | Sir Philip Charles Sidney | (civil division) Promoted GCH 1831, later Baron De L'Isle and Dudley |
| 1830 | Major-General Sir Alexander Bryce | |
| 1831 | Major-General The Honourable Sir Frederick Cavendish Ponsonby | |
| 1831 | Major-General Sir James Charles Dalbiac | |
| 1831 | Colonel Sir Charles Wade Thornton | Promoted GCH 1837 |
| 1831 | Major-General Sir John Brown | |
| 1831 | Major-General Sir James Campbell | |
| 1831 | Major-General Sir Benjamin Charles Stephenson | Promoted GCH 1834 |
| 1831 | Major-General Sir Henry Wheatley | Promoted GCH 1834 |
| 1831 | Sir George Harrison | (civil division) |
| 1831 | Captain Sir George Francis Seymour | Promoted GCH 1834 |
| 1831 | Captain Sir Thomas Ussher | |
| 1831 | Colonel Stephen Remnant Chapman | |
| 1831 | Sir William Burnett | (civil division) |
| 1831 | Lieutenant-Colonel The Honourable Sir Edward Cust | |
| 1831 | Lieutenant-General Sir Phineas Riall | |
| 1831 | Lieutenant-General Sir William Hutchinson, d. 1845? | |
| 1831 | Major-General Sir Lewis Grant | |
| 1831 | Major-General Sir Amos Godsill Robert Norcott | |
| 1831 | Major-General Sir James Cockburn, Bart. | |
| 1831 | Colonel Sir Evan John Murray MacGregor, Bart. | |
| 1831 | Colonel Sir Neil Douglas | |
| 1831 | Captain Sir William Howe Mulcaster | |
| 1831 | Colonel William, baron von Tuyll | |
| 1831 | Sir William Pym | (civil division) |
| 1832 | Lieutenant-General Sir Warren Marmaduke Peacocke | |
| 1832 | Lieutenant-General Charles Bulkeley Egerton | |
| 1832 | Lieutenant-General Sir William Sheridan | |
| 1832 | Major-General Sir William Paterson | |
| 1832 | Major-General John Frederick Sigismund Smith | |
| 1832 | Major-General William Nicolay | |
| 1832 | Major-General Arthur Benjamin Clifton | |
| 1832 | Colonel George Whitmore | |
| 1832 | Colonel Leonard Greenwell | |
| 1832 | Colonel Robert Henry Dick | |
| 1832 | Colonel Frederick William Trench | |
| 1832 | Captain William Augustus Montagu | |
| 1832 | Sir William Franklin | (civil division) |
| 1832 | Sir Henry Seaton | (civil division) |
| 1832 | Major-General John Macleod | |
| 1832 | Major-General Frederick William Mulcaster | |
| 1832 | Major-General Claude François, vicomte de Rivarol | |
| 1832 | Major-General Sir William Parker Carrol | |
| 1832 | Major-General John Hanbury | |
| 1832 | Colonel David Ximenes | |
| 1832 | Captain Sir John Marshall | |
| 1832 | Sir John Webb | (civil division) |
| 1832 | Major-General Joseph Straton | |
| 1832 | Colonel John George Woodford | |
| 1832 | George Hamilton Seymour | (civil division) Promoted GCH 1834 |
| 1832 | Captain Sir Humphrey Fleming Senhouse | |
| 1832 | Lieutenant-General Sir Thomas Browne | |
| 1832 | Major-General William Douglas | |
| 1832 | Major-General William Cornwallis Eustace | |
| 1832 | Captain Nisbet Josiah Willoughby | |
| 1832 | Captain Andrew Pellatt Green | |
| 1832 | Captain Arthur Farquhar | |
| 1832 | Commissary-General Sir John Bisset | (civil division) |
| 1832 | John Deas Thomson | (civil division) |
| 1832 | Sir George Jackson | (civil division) |
| 1832 | Commodore Charles Marsh Schomberg | |
| 1832 | Rear Admiral Sir Charles Cunningham | |
| 1832 | Rear Admiral The Honourable Courtenay Boyle | |
| 1833 | Lieutenant-General David Latimer Tinling Widdrington | |
| 1833 | Major-General William George Harris, 2nd Baron Harris | |
| 1833 | Rear Admiral Edward Durnford King | |
| 1833 | Captain Sir Francis Augustus Collier | |
| 1833 | Captain Richard Spencer | |
| 1833 | Colonel John Boscawen Savage | |
| 1833 | Captain Sir Samuel John Brooke Pechell, Bart. | |
| 1833 | Lieutenant-General Henry John Cumming | |
| 1834 | Lieutenant-General Evan Lloyd | |
| 1834 | Lieutenant-General Thomas Gage Montresor | |
| 1834 | Major-General Samuel Trevor Dickens | |
| 1834 | Major-General James Kearney | |
| 1834 | Major-General Lorenzo Moore | |
| 1834 | Major-General James Viney | |
| 1834 | Major-General Henry Willoughby Rooke | |
| 1834 | Major-General Sir Patrick Ross | |
| 1834 | Colonel Henry King | |
| 1834 | Rear Admiral John Ferris Devonshire | |
| 1834 | Captain James Hillyar | |
| 1834 | Captain Salusbury Pryce Davenport | |
| 1834 | Commissary-General Sir Robert Hugh Kennedy | (civil division) |
| 1834 | Commissary-General Sir William Henry Robinson | (civil division) |
| 1834 | Sir John Woolmore | (civil division) |
| 1834 | Lieutenant-General Sir Joseph Maclean | |
| 1834 | Rear Admiral Sir Hugh Pigot | |
| 1834 | Commodore Robert Barrie | |
| 1834 | Colonel Patrick Lindesay | |
| 1834 | Lieutenant-Colonel Edmund Currey | |
| 1834 | Colonel Sir Samuel Gordon Higgins | |
| 1834 | Captain The Honourable Sir Henry Duncan | |
| 1835 | Captain Charles Bullen | |
| 1835 | Captain William Henry Dillon | |
| 1835 | Captain William Elliott | |
| 1835 | Captain Edmund Lyons | Later Baron Lyons |
| 1835 | Major-General Thomas Bligh St George | |
| 1835 | Major-General Thomas Pearson | |
| 1835 | Major-General Maurice Charles O'Connell | |
| 1835 | Colonel Patrick Doherty | |
| 1835 | Colonel Sir Octavius Carey | |
| 1835 | Captain Lord James Townshend | |
| 1835 | Lieutenant-Colonel Charles Holland Hastings | |
| 1835 | Commodore Sir Samuel Warren | |
| 1835 | Colonel The Honourable Sir Horatio George Powys Townshend | |
| 1835 | Rear Admiral Sir Robert Lewis Fitzgerald | |
| 1835 | Sir Francis Bond Head | (civil division) |
| 1836 | | |
| 1836 | Major-General Sir Charles William Maxwell | |
| 1836 | Major-General William Gabriel Davy | |
| 1836 | Captain The Honourable Fleetwood Broughton Reynolds Pellew | |
| 1836 | Captain The Honourable James Ashley Maude | |
| 1836 | Captain John Strutt Peyton | |
| 1836 | Captain Richard O'Conor | |
| 1836 | Captain Henry Hart | |
| 1836 | Captain James John Gordon Bremer | |
| 1836 | Sir Robert Ker Porter | (civil division) |
| 1836 | Captain Sir John Franklin | (civil division) |
| 1836 | Sir John Nicol Robert Campbell | (civil division) Later baronet |
| 1837 | Lieutenant-General Alexander Halkett | |
| 1837 | Major-General Robert Barton | |
| 1837 | | |
| 1837 | Major-General Thomas Hawker | |
| 1837 | Vice Admiral Sir Adam Drummond | |
| 1837 | Captain Sir David Dunn | |
| 1837 | Captain Edward Chetham | |
| 1837 | Captain Thomas Mansell | |
| 1837 | Woodbine Parish | (civil division) |
| 1837 | Major-General Sir Edward Bowater | |
| 1837 | Major-General James Macdonnell | |
| 1837 | Major-General Robert McCleverty | |
| 1837 | Rear Admiral John Wentworth Loring | |
| 1837 | Colonel George Arthur | Later baronet |
| 1837 | David Davies | (civil division) |
| 1837 | William Frederick Chambers | (civil division) |
| 1837 | Captain Thomas Barker Devon | | |
