denotes the first female secretary of that particular department.
| Secretary | Position | Year appointed | Administration | |
|---|---|---|---|---|
| Government | ||||
| 1986 | Herself | |||
| 2001 | Herself | |||
| 1998 | Joseph Estrada | |||
| 2016 | Rodrigo Duterte | |||
| 2022 | ||||
| Secretary of Agrarian Reform | ||||
| 1989 | Corazon Aquino | |||
| 2017 | Rodrigo Duterte | |||
| Secretary of Budget and Management | ||||
| 1998 | Fidel Ramos | |||
| Emilia Boncodin | 2001 | Gloria Macapagal Arroyo | ||
| 2019 | Rodrigo Duterte | |||
| Tina Rose Marie Canda | 2021 | Rodrigo Duterte | ||
| 2022 | Bongbong Marcos | |||
| Secretary of Education | ||||
| 1986 | Corazon Aquino | |||
| 1998 | Fidel Ramos | |||
| 2005 | Gloria Macapagal Arroyo | |||
| 2010 | Gloria Macapagal Arroyo | |||
| 2016 | Rodrigo Duterte | |||
| Sara Duterte | 2022 | |||
| Secretary of Energy | ||||
| 2015 | Benigno Aquino III | |||
| Secretary of Environment and Natural Resources | ||||
| 2002 | Gloria Macapagal Arroyo | |||
| 2016 | Rodrigo Duterte | |||
| 2022 | Bongbong Marcos | |||
| Secretary of Finance | ||||
| 2003 | Gloria Macapagal Arroyo | |||
| Secretary of Foreign Affairs | ||||
| 2002 | Herself | |||
| Gloria Macapagal Arroyo | 2003 | Herself | ||
| 2003 | Gloria Macapagal Arroyo | |||
| Secretary of Health | ||||
| 1996 | Fidel Ramos | |||
| 2009 | Gloria Macapagal Arroyo | |||
| 2014 | Benigno Aquino III | |||
| 2016 | Rodrigo Duterte | |||
| 2022 | Bongbong Marcos | |||
| Secretary of Human Settlements and Urban Development | ||||
| Melissa Aradanas | 2022 | Bongbong Marcos | ||
| Secretary of Justice | ||||
| 2002 | Gloria Macapagal Arroyo | |||
| 2007 | Gloria Macapagal Arroyo | |||
| 2010 | Benigno Aquino III | |||
| Secretary of Labor and Employment | ||||
| 1992 | ||||
| 2001 | Gloria Macapagal Arroyo | |||
| 2010 | Benigno Aquino III | |||
| Secretary of Migrant Workers | ||||
| 2022 | ||||
| Secretary of National Defense | ||||
| 2003 | Herself | |||
| Gloria Macapagal Arroyo | 2006 | Herself | ||
| Secretary of Science and Technology | ||||
| 2001 | Gloria Macapagal Arroyo | |||
| Secretary of Social Welfare and Development | ||||
| 1946 | Manuel Roxas | |||
| 1954 | Ramon Magsaysay | |||
| 1960 | Carlos P. Garcia | |||
| 1962 | Diosdado Macapagal | |||
| 1971 | Ferdinand Marcos | |||
| 1978 | Ferdinand Marcos | |||
| 1986 | Corazon Aquino | |||
| 1992 | Fidel Ramos | |||
| 1995 | Fidel Ramos | |||
| 1998 | ||||
| 2000 | Joseph Estrada | |||
| 2001 | ||||
| 2005 | ||||
| 2005 | Gloria Macapagal Arroyo | |||
| 2009 | Gloria Macapagal Arroyo | |||
| 2010 | ||||
| 2016 | ||||
| 2018 | ||||
| Secretary of Tourism | ||||
| 1989 | Corazon Aquino | |||
| 1996 | Fidel Ramos | |||
| 1996 | Fidel Ramos | |||
| 1998 | Joseph Estrada | |||
| 2016 | Rodrigo Duterte | |||
| 2018 | Rodrigo Duterte | |||
| 2022 | ||||
| Secretary of Trade and Industry | ||||
| 1992 | Corazon Aquino | |||
| Ma. Cristina Aldeguer-Roque | 2024 | |||
| Secretary of Transportation and Communications | ||||
| 1998 | Fidel Ramos | |||
| 2010 | Gloria Macapagal Arroyo | |||
| Presidential Spokesperson | ||||
| 1992 | Fidel Ramos | |||
| Executive Secretary | ||||
| 1987 | Corazon Aquino | |||
| Chairman of the Commission on Higher Education | ||||
| 2010 | Benigno Aquino III | |||
| Presidential Management Staff | ||||
| 1992 | Fidel Ramos | |||
| 1998 | Joseph Estrada | |||
| 2010 | Benigno Aquino III | |||
| 2022 | ||||
| Cabinet Secretary | ||||
| 1992 | Fidel Ramos | |||
| 1998 | Joseph Estrada | |||
| Secretary of the Presidential Communications Operations Office | ||||
| 2022 | ||||
| 2022 | ||||
| Housing and Urban Development Coordinating Council | ||||
| 1978 | Ferdinand Marcos | |||
| 2000 | Joseph Estrada | |||
| 2016 | Rodrigo Duterte | |||
| Secretary of Socio-economic Planning/Director General of National Economic and Development Authority | ||||
| 1986 | Corazon Aquino | |||
| National Security Adviser | ||||
| 2022 | ||||