This is a List of ambassadors of Venezuela to Spain.[1]
| Name | From | To | Notes |
|---|---|---|---|
| 1846 | 1846 | ||
| Francisco Michelena y Rojas | 1852 | 1854 | |
| Mauricio Berrizbeitia | 1858 | 1860 | |
| 1860 | 1861 | ||
| 1863 | 1866 | President of Venezuela for three separate terms, from 1870–1877, from 1879–1884, and from 1886–1887. | |
| Laureano Zavarce | 1868 | 1868 | |
| 1869 | 1872 | interim President of Venezuela in 1868, 1870 and 1892; Foreign Minister twice. | |
| 1873 | 1876 | ||
| Eduardo Calcaño y Panizza | 1882 | 1886 | |
| 1890 | 1891 | ||
| Marco Antonio Saluzzo | 1891 | 1892 | |
| Tomás Michelena | 1893 | 1893 | |
| Fernando Arvelo | 1893 | 1896 | |
| Juan Pietri | 1895 | 1896 | |
| José Andrade | 1896 | 1899 | |
| Bernabé Planas | 1900 | 1901 | |
| 1910 | 1911 | ||
| 1914 | 1925 | ||
| 1910 | 1918 | Minister of Foreign Affairs 1919-21 and 1936-41. | |
| José Antonio Martínez Méndez | 1920 | 1921 | |
| 1916 | 1924 | ||
| Gumersindo Torres | 1927 | 1929 | |
| Alberto Urbaneja | 1929 | 1932 | |
| 1931 | 1933 | President, 1929-31 | |
| Emilio Ochoa | 1933 | 1936 | |
| Juan Tinoco | 1936 | 1939 | |
| 1939 | 1941 | ||
| Alberto Zérega Fombona | 1941 | 1942 | |
| Cristóbal Benítez | 1942 | 1945 | |
| 1950 | 1953 | ||
| 1953 | 1958 | ||
| José Saúl Guerrero Rosales | 1958 | 1962 | |
| Régulo Pacheco Vivas | 1962 | 1964 | |
| 1964 | 1967 | ||
| Eligio Anzola Anzola | 1967 | 1968 | |
| 1969 | 1972 | Journalist and historian | |
| 1972 | 1974 | Historian | |
| Santiago Ochoa Briceño | 1974 | 1977 | |
| Rubén Carpio Castillo | 1977 | 1978 | |
| Ernesto Santander | 1978 | 1979 | |
| Eduardo Tamayo Gascué | 1979 | 1981 | |
| Rafael León Morales | 1979 | 1979 | |
| Rigoberto Henriquez Vera | 1984 | 1984 | |
| Arturo Hernández Grisanti | 1990 | 1992 | |
| 1992 | 1994 | Minister of Foreign Affairs 1991-2 | |
| José Miguel Uzcátegui | 1994 | 1996 | |
| Francisco Paparoni | 1996 | 1998 | |
| 1998 | 1999 | ||
| 2000 | 2002 | ||
| 2002 | 2005 | ||
| Arévalo Méndez Rivero | 2005 | 2006 | |
| 2007 | 2009 |