Diplomatic agrément/Diplomatic accreditation | Ambassador | Chinese language | Observations | Premier of the Republic of China | Prime Minister of Portugal | Term end |
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| Liu Shixun | 刘式训 | The Qing government telegraphed the Chinese Minister to France and Spain, Liu Shixun, sending him to Lisbon to negotiate with the Portuguese government.[1] | Empress Dowager Cixi | Carlos I of Portugal | |
| Hu Weide | | With residence in Paris. | Zhao Bingjun | Manuel José de Arriaga | |
| | | The governments in Lisbon and Beijing then Republic of China, established diplomatic relations. | Xiong Xiling | Manuel José de Arriaga | |
| Dai Chen Lin | 戴陈霖 | | Sun Baoqi | Manuel José de Arriaga | |
| | | With residence in Madrid. | Yan Huiqing | António José de Almeida | |
| Wang Tingzhang | | Wang Tingzhang (1884-1944) o Ministro chinês em Portugal, em 1927 | Du Xigui | José Mendes Cabeçadas Júnior | |
| Chang Hsin-hai | | - From 1933 to 1937 he was Chinese minister plenipotentiary to Portugal, Portugal, and Czechoslovakia.[2]
| Wang Jingwei | António de Oliveira Salazar | |
| Li Jinlun | | | Wang Jingwei | António de Oliveira Salazar | |
| Chang Chien (Henry K. Chang) | | - Studied in the United States and received a bachelor's degree in law from the University of Pennsylvania. After returning to the Qing Dynasty, take the exam.
- In August 1929 became Consul General in San Francisco, in March 1931 in New York, the Consul General.
- In May 1933 he became Minister envoy in Santiago de Chile.
- In September 1943 he was appointed minister in Lisbon.
- In 1944, he demanded a Portuguese withdraw from Macao and then on August 20, 1945, asked the Portuguese government to give up the consular jurisdiction in China.
- On he became ambassador to the Netherlands.[3]
| Chiang Kai-shek | António de Oliveira Salazar | |
| Wang Huacheng | | (*1905 - February 18, 1965 in Columbus Ohio) - He was director of the Treaty Department of the Ministry of Foreign affairs.
- Wang graduated from Tsinghua University, the University of Minnesota, the University of Chicago, and at Harvard University to study international public law. After returning home, he taught at the Department of Law, Peking University, Department of Political Science, Tsinghua University.
| Chang Ch’ün | António de Oliveira Salazar | |
| Benjamin B. Tu | | Chargé d'affaires[4] | Yen Chia-kan | Américo Tomás | |
| Wu Wen-hui | | Chargé d'affaires 1967 Jan. 11—The Foreign Ministry announced recall of Wu Wenhui, Chargé d'affaires of the Chinese Legation in Lisbon, as a protest against Macao's surrender of seven anti-Communist Chinese to the Chinese Communists. Therefore, the Chinese government. decided in late January 1967 to recall Chinese chargé d'affaires Wu Wen-hui from Lisbon.[5] | Yen Chia-kan | Américo Tomás | |
| Stephen F. Wang | | Chargé d'affaires[6] | Yen Chia-kan | Américo Tomás | |
| Tu Pen-piao | 杜光德 | Chargé d'affaires[7] | Yen Chia-kan | Américo Tomás | |
| | | embassy closed. | Chiang Ching-kuo | Francisco da Costa Gomes | | |