The Union Territory of Daman and Diu had shared its administrator with Dadra and Nagar Haveli since its inception on 30 May 1987. The union territory of Daman and Diu was merged with the nearby territory of Dadra and Nagar Haveli to create the new union territory of Dadra and Nagar Haveli and Daman and Diu on 26 January 2020 and the office of Administrator of Daman and Diu was abolished on that date.
! Name | Took office ! Left office | |||
|---|---|---|---|---|
| 1 | Gopal Singh | 30 May 1987 | 18 July 1989 | |
| 2 | 18 July 1989 | 25 March 1991 | ||
| 3 | Bhanu Prakash Singh | 25 March 1991 | 16 March 1992 | |
| 4 | K.S. Baidwan | 16 March 1992 | 28 March 1994 | |
| 5 | Ramesh Chandra | 28 March 1994 | 15 July 1995 | |
| 6 | S.P. Aggarwal | 15 July 1995 | 26 June 1998 | |
| 7 | Ramesh Negi (acting) | 26 June 1998 | 23 February 1999 | |
| 8 | Sanat Kaul | 23 February 1999 | 23 April 1999 | |
| 9 | Ramesh Negi (acting) | 23 April 1999 | 19 July 1999 | |
| 10 | O.P. Kelkar | 19 July 1999 | 2003 | |
| 11 | Arun Mathur | 2003 | 2006 | |
| 12 | R.K. Verma | 2006 | 2009 | |
| 13 | Shri Satya Gopal, | 2009 | 2011 | |
| 14 | Shri. Narendra cham, | 2011 | 2012 | |
| 15 | B. S. Bhalla | 28 September 2012 | 18 August 2014 | |
| 16 | Ashish Kundra | 18 August 2014 | 13 March 2016 | |
| 17 | 14 March 2016 | 29 August 2016 | ||
| 18 | Praful Khoda Patel | 29 August 2016 | 26 January 2020 |