Light dressed state explained
In the fields of atomic, molecular, and optical science, the term light dressed state refers to a quantum state of an atomic or molecular system interacting with a laser lightin terms of the Floquet picture, i.e. roughly like an atom or a molecule plus a photon. The Floquet picture is based on the Floquet theorem in differential equations with periodic coefficients.
Mathematical formulation
The Hamiltonian of a system of charged particles interacting with a laser light can be expressed aswhere
is the
vector potential of the electromagnetic field of the laser;
is periodic in time as
.The position and momentum of the
-th particle are denoted as
and
, respectively,while its mass and charge are symbolized as
and
, respectively.
is the speed of light.By virtue of this time-periodicity of the laser field, the total Hamiltonian is also periodic in time as
The Floquet theorem guarantees that any solution
of the
Schrödinger equation with this type of Hamiltonian,
i\hbar
\psi(\{ri\},t)=H(t)\psi(\{ri\},t)
can be expressed in the form
\psi(\{ri\},t)=\exp[-iEt/\hbar]\phi(\{ri\},t)
where
has the same time-periodicity as the Hamiltonian,
\phi(\{ri\},t+T)=\phi(\{ri\},t).
Therefore, this part can be expanded in a
Fourier series, obtainingwhere
is the frequency of the laser field. This expression (2) reveals that a quantum state of the system governed by the Hamiltonian (1) can be specified by a real number
and an integer
.
The integer
in eq. (2) can be regarded as the number of photons absorbed from (or emitted to) the laser field.In order to prove this statement, we clarify the correspondence between the solution (2),which is derived from the classical expression of the electromagnetic field where thereis no concept of photons, and one which is derived from a quantized electromagnetic field (see
quantum field theory). (It can be verified that
is equal to the expectation value of the absorbed photon numberat the limit of
, where
is the initial number of total photons.)
References
- Shirley. Jon H.. Solution of the Schrödinger Equation with a Hamiltonian Periodic in Time. Physical Review. 138. 4B. 1965. B979–B987. 0031-899X. 10.1103/PhysRev.138.B979. 1965PhRv..138..979S .
- Sambe. Hideo. Steady States and Quasienergies of a Quantum-Mechanical System in an Oscillating Field. Physical Review A. 7. 6. 1973. 2203–2213. 0556-2791. 10.1103/PhysRevA.7.2203. 1973PhRvA...7.2203S .
- Guérin. S. Monti. F. Dupont. J-M. Jauslin. H R. On the relation between cavity-dressed states, Floquet states, RWA and semiclassical models. Journal of Physics A: Mathematical and General. 30. 20. 1997. 7193–7215. 0305-4470. 10.1088/0305-4470/30/20/020. 1997JPhA...30.7193G.
- Cardoso. G.C.. Tabosa. J.W.R.. Four-wave mixing in dressed cold cesium atoms. Optics Communications. 185. 4–6. 2000. 353–358. 0030-4018. 10.1016/S0030-4018(00)01033-6. 2000OptCo.185..353C .
- Book: Guérin. S.. Jauslin. H. R.. Advances in Chemical Physics . Control of Quantum Dynamics by Laser Pulses: Adiabatic Floquet Theory. 2003. 147–267. 1934-4791. 10.1002/0471428027.ch3. 9780471214526 .
- F.H.M. Faisal, Theory of Multiphoton Processes, Plenum (New York) 1987 .
See also