Lichenin Explained

Lichenin, also known as lichenan or moss starch, is a complex glucan occurring in certain species of lichens. It can be extracted from Cetraria islandica (Iceland moss).[1] It has been studied since about 1957.[2]

Structure

Chemically, lichenin is a mixed-linkage glucan, consisting of repeating glucose units linked by β-1,3 and β-1,4 glycosidic bonds.

Uses

It is an important carbohydrate for reindeers and northern flying squirrels, which eat the lichen Bryoria fremontii.

It can be extracted by digesting Iceland moss in a cold, weak solution of carbonate of soda for some time, and then boiling. By this process the lichenin is dissolved and on cooling separates as a colorless jelly. Iodine imparts no color to it.

Other uses of the name

In his 1960 novel Trouble with Lichen, John Wyndham gives the name Lichenin to a biochemical extract of lichen used to extend life expectancy beyond 300 years.

Notes and References

  1. Perlin . A. S. . Suzuki . S. . 1962 . The Structure of Lichenin: Selective Enzymolysis Studies . . 40 . 1 . 50–56 . . Canada . 10.1139/v62-009. free .
  2. Cunningham . WL . Manners . DJ . March 1964 . Studies on carbohydrate-metabolizing enzymes. 11. The hydrolysis of lichenin by enzyme preparations from malted barley and Rhizopus arrhizus . The Biochemical Journal . 90 . 3 . 596–602 . Portland Press on behalf of the Biochemical Society . England . 0264-6021 . 5833367 . 1202740 . 10.1042/bj0900596.