Levenspiel plot explained

A Levenspiel plot is a plot used in chemical reaction engineering to determine the required volume of a chemical reactor given experimental data on the chemical reaction taking place in it. It is named after the late chemical engineering professor Octave Levenspiel.

Derivation

For a continuous stirred-tank reactor (CSTR), the following relationship applies:[1] [2]

V=FAo\left(

1
-rA

\right)X

where:

V

is the reactor volume

FAo

is the molar flow rate per unit time of the entering reactant A

X

is the conversion of reactant A

-rA

is the rate of disappearance of reactant A per unit volume per unit time

For a plug flow reactor (PFR), the following relationship applies:

V=FAo

X
\int
0
1
-rA

dX

If

FAo\over-rA

is plotted as a function of

X

, the required volume to achieve a specific conversion can be determined given an entering molar flow rate.

The volume of a CSTR necessary to achieve a certain conversion at a given flow rate is equal to the area of the rectangle with height equal to

FAo\over-rA

and width equal to

X

.

The volume of a PFR necessary to achieve a certain conversion at a given flow rate is equal to the area under the curve of

FAo\over-rA

plotted against

X

.

References

  1. Book: Fogler, H. Scott. 2006 . Elements of Chemical Reaction Engineering . Prentice Hall . 4th . 45–65 . 0130473944 .
  2. Book: Skogestad, Sigurd . 2008 . Chemical and Energy Process Engineering . CRC Press . 265 . 9781420087567.