Kugel–Khomskii coupling explained

Kugel–Khomskii coupling describes a coupling between the spin and orbital degrees of freedom in a solid; it is named after the Russian physicists Kliment I. Kugel (Климент Ильич Кугель) and Daniel I. Khomskii (Daniil I. Khomskii, Даниил Ильич Хомский). The Hamiltonian used is:

H=t2
U

\sum\langle\left[4\left(\overrightarrow{Si}\overrightarrow{Sj}\right)\left(\tau

\alpha
-
i
1
2
\alpha
\right)\left(\tau-
j
1
2
\alpha
\right) +\left(\tau+
i
1
2
\alpha
\right)\left(\tau+
j
1
2

\right)-1\right].

References