JP-10 (fuel) explained

JP-10 fuel - (Jet Propellant 10), is a jet fuel, specified and used mainly as a gas turbine fuel in missiles. Despite being designed for military purposes, it is not a kerosene based fuel. It is a gas turbine fuel for missiles.[1] It contains mainly exo-tetrahydrodicyclopentadiene (a synthetic fuel), and adamantane. However, it is usually classed as a single component fuel, as well as a hydrocarbon.[2] It is produced by catalytic hydrogenation of dicyclopentadiene and then isomerization. It superseded JP-9 because of a lower temperature service limit.[1] Its main use is in the Tomahawk missiles.[3]

The Russian equivalent is called detsilin.

Chemical properties of JP-10 fuel

Uses

JP-10 absorbs heat energy, so is endothermic with a relatively high density of 940 kg/m3. It has a low freezing point of less than and the flash point is . The high energy density of 39.6 MJ/L makes it ideal for military aerospace applications - its primary use. The ignition and burn chemistry has been extensively studied.[6] [7] [8] The exo isomer also has a low freezing point.[9] [10] Its other properties have also been studied extensively.[11] [12] [13] [14] [15]

Even though its uses are mainly for the military, the relatively high cost has meant research has been undertaken to find lower costs routes including the use of cellulosic materials.[16]

Further research

Current and past areas of research focus on:

References

  1. Book: Aviation Fuel Properties. 1983. Coordinating Research Council. CRC Report Nº 530. . dead. 3. 2023-12-06. 2012-07-22. https://web.archive.org/web/20120722080544/http://www.dtic.mil/dtic/tr/fulltext/u2/a132106.pdf.
  2. Ciccarelli . G. . Card . J. . February 2006 . Detonation in Mixtures of JP-10 Vapor and Air . AIAA Journal . en . 44 . 2 . 362–367 . 10.2514/1.18582 . 0001-1452.
  3. Web site: Coggeshall . Katharine . Revolutionizing Tomahawk fuel . Los Alamos National Laboratory . 20 May 2020 . 21 May 2020 . https://web.archive.org/web/20200521132110/https://www.lanl.gov/discover/publications/national-security-science/2020-spring/tomahawk.php . dead .
  4. Web site: JP10 specs . 2024-05-20 . web.stanford.edu . en.
  5. Web site: h/c ratio - Google Search . 2024-05-20 . www.google.com.
  6. Web site: Exo-tricyclo[5.2.1.0(2.6)]decane ]. 2023-10-03 . webbook.nist.gov . en.
  7. Li . S. C. . Varatharajan . B. . Williams . F. A. . December 2001 . Chemistry of JP-10 Ignition . AIAA Journal . en . 39 . 12 . 2351–2356 . 10.2514/2.1241 . 0001-1452.
  8. Davidson . D. F. . Horning . D. C. . Herbon . J. T. . Hanson . R. K. . 2000-01-01 . Shock tube measurements of JP-10 ignition . Proceedings of the Combustion Institute . 28 . 2 . 1687–1692 . 10.1016/S0082-0784(00)80568-8 . 1540-7489.
  9. Herbinet . Olivier . Sirjean . Baptiste . Bounaceur . Roda . Fournet . René . Battin-Leclerc . Frédérique . Scacchi . Gérard . Marquaire . Paul-Marie . 2006-10-01 . Primary Mechanism of the Thermal Decomposition of Tricyclodecane . The Journal of Physical Chemistry A . en . 110 . 39 . 11298–11314 . 10.1021/jp0623802 . 17004739 . 2006JPCA..11011298H . 1089-5639.
  10. Wu . Junjun . Gao . Lu Gem . Ning . Hongbo . Ren . Wei . Truhlar . Donald G. . 2020-06-01 . Direct dynamics of a large complex hydrocarbon reaction system: The reaction of OH with exo-tricyclodecane (the main component of Jet Propellant-10) . Combustion and Flame . 216 . 82–91 . 10.1016/j.combustflame.2020.02.019 . 216384271 . 0010-2180. free .
  11. Web site: Exo-tricyclo[5.2.1.0(2.6)]decane ]. 2023-10-03 . Cheméo . en.
  12. Seiser . R. . Niemann . U. . Seshadri . K. . 2011-01-01 . Experimental study of combustion of n-decane and JP-10 in non-premixed flows . Proceedings of the Combustion Institute . 33 . 1 . 1045–1052 . 10.1016/j.proci.2010.06.078 . 1540-7489.
  13. Tao . Yujie . Xu . Rui . Wang . Kun . Shao . Jiankun . Johnson . Sarah E. . Movaghar . Ashkan . Han . Xu . Park . Ji-Woong . Lu . Tianfeng . Brezinsky . Kenneth . Egolfopoulos . Fokion N. . Davidson . David F. . Hanson . Ronald K. . Bowman . Craig T. . Wang . Hai . 2018-12-01 . A Physics based approach to modeling real fuel combustion chemistry III Reaction kinetic model of JP10 . Combustion and Flame . 198 . 466–476 . 10.1016/j.combustflame.2018.08.022 . 104745782 . 0010-2180.
  14. Li . Heng . Liu . Guozhu . Jiang . Rongpei . Wang . Li . Zhang . Xiangwen . 2015-05-01 . Experimental and kinetic modeling study of exo-TCD pyrolysis under low pressure . Combustion and Flame . 162 . 5 . 2177–2190 . 10.1016/j.combustflame.2015.01.015 . 0010-2180.
  15. Goh . K. H. H. . Geipel . P. . Hampp . F. . Lindstedt . R. P. . 2013-01-01 . Regime transition from premixed to flameless oxidation in turbulent JP-10 flames . Proceedings of the Combustion Institute . 34 . 2 . 3311–3318 . 10.1016/j.proci.2012.06.173 . 1540-7489.
  16. Li . Guangyi . Hou . Baolin . Wang . Aiqin . Xin . Xuliang . Cong . Yu . Wang . Xiaodong . Li . Ning . Zhang . Tao . 2019-08-26 . Making JP‐10 Superfuel Affordable with a Lignocellulosic Platform Compound . . en . 58 . 35 . 12154–12158 . 10.1002/anie.201906744 . 1433-7851.
  17. Chenoweth . Kimberly . van Duin . Adri C. T. . Dasgupta . Siddharth . Goddard III . William A. . 2009-03-05 . Initiation Mechanisms and Kinetics of Pyrolysis and Combustion of JP-10 Hydrocarbon Jet Fuel . The Journal of Physical Chemistry A . en . 113 . 9 . 1740–1746 . 10.1021/jp8081479 . 1089-5639.
  18. Zhong . Bei-jing . Zeng . Zhao-mei . Zhang . Hou-zhen . 2022-03-15 . An experimental and kinetic modeling study of JP-10 combustion . Fuel . 312 . 122900 . 10.1016/j.fuel.2021.122900 . 0016-2361.
  19. Van Devener . Brian . Anderson . Scott L. . 2006-09-01 . Breakdown and Combustion of JP-10 Fuel Catalyzed by Nanoparticulate CeO 2 and Fe 2 O 3 . Energy & Fuels . en . 20 . 5 . 1886–1894 . 10.1021/ef060064g . 0887-0624.
  20. Huang . Ming-Yu . Wu . Jung-Chung . Shieu . Fuh-Sheng . Lin . Jiang-Jen . 2011-03-01 . Preparation of high energy fuel JP-10 by acidity-adjustable chloroaluminate ionic liquid catalyst . Fuel . 90 . 3 . 1012–1017 . 10.1016/j.fuel.2010.11.041 . 0016-2361.
  21. Xing . Enhui . Mi . Zhentao . Xin . Chengwei . Wang . Li . Zhang . Xiangwen . 2005-04-20 . Endo- to exo-isomerization of tetrahydrodicyclopentadiene catalyzed by commercially available zeolites . Journal of Molecular Catalysis A: Chemical . 231 . 1 . 161–167 . 10.1016/j.molcata.2005.01.015 . 1381-1169.
  22. E . Xiu-tian-feng . Pan . Lun . Zhang . Xiangwen . Zou . Ji-Jun . 2020-09-15 . Influence of quadricyclane additive on ignition and combustion properties of high-density JP-10 fuel . Fuel . 276 . 118047 . 10.1016/j.fuel.2020.118047 . 0016-2361.
  23. Chung . H. S. . Chen . C. S. H. . Kremer . R. A. . Boulton . J. R. . Burdette . G. W. . 1999-05-01 . Recent Developments in High-Energy Density Liquid Hydrocarbon Fuels . Energy & Fuels . en . 13 . 3 . 641–649 . 10.1021/ef980195k . 0887-0624.