Johannes Nicolaus Brønsted Explained

Johannes Nicolaus Brønsted
Birth Date:22 February 1879
Birth Place:Varde, Denmark
Death Place:Copenhagen, Denmark
Nationality:Danish
Fields:Physical chemistry
Workplaces:University of Copenhagen
Known For:Brønsted–Lowry acid–base theory
Brønsted catalysis equation
Specific ion interaction theory
Awards:H. C. Ørsted Medal

Johannes Nicolaus Brønsted (in Danish joˈhænˀəs ne̝koˈlɛːus ˈpʁɶnsteð/; 22 February 1879 – 17 December 1947) was a Danish physical chemist who is best known for developing the Brønsted–Lowry acid–base theory; he developed the theory at the same time as (but independently of) Martin Lowry.[1]

Biography

Brønsted was born in Varde, Denmark on 22 February 1879. His mother died shortly after his birth, and his father died when Brønsted was 14 years old; he then moved to Copenhagen with his older sister and his stepmother.[2] In 1897, Brønsted began his studies as a chemical engineer at the Polytechnic Institute inCopenhagen. After his first degree, Brønsted changed fields and received his magister degree in chemistry in 1902 from the University of Copenhagen. In 1905, he became an assistant at the Chemical Institute and obtained his doctoral degree in 1908. In the same year, Brønsted became a professor of physical and inorganic chemistry at the University of Copenhagen.

In 1929, Brønsted was a visiting professor at Yale University.[3] His research gained worldwide recognition, resulting in four Nobel prize nominations, a gold H. C. Ørsted Medal and being appointed as a fellow of the Royal Society and a member of the National Academy of Sciences.[1] [4]

Brønsted married Charlotte Warberg, whom he met during his first degree. The couple had four children.[5] In World War II, Brønsted's opposition to the Nazis led to his election to the Danish parliament in 1947, but he was too ill to take his seat and died shortly after the election.[1]

Research

Early in his career, Brønsted studied chemical thermodynamics and later studied electrolyte solutions and carried out an extensive series of solubility measurements. These measurements led him to establish general laws which were later confirmed when the Debye–Hückel theory was proposed.[6] [7]

Brønsted is best known for his work on reaction kinetics, in particular acid–base reactions. In 1923, he recognized that acid–base reactions involved the transfer of a proton, from the acid (proton donor) to the base (proton acceptor).[8] Almost simultaneously and independently, the British chemist Martin Lowry arrived at the same conclusion, thus the name Brønsted–Lowry acid–base theory.[9] Also in 1923, Gilbert N. Lewis proposed an electronic theory of acid–base reactions, but both theories remain commonly used.[10]

Later in his career, Brønsted kept studying reaction kinetics, with a special focus on reactions taking place in non-aqueous solutions. He also developed some work about the effect of molecular size on the thermodynamical properties of hydrocarbons, polymers and colloids.[6] He also worked with the Nobel prize winner George de Hevesy on isotope separation by fractional distillation.[11]

Notes and References

  1. Encyclopedia: Johannes Nicolaus Brønsted . . March 28, 2012.
  2. Web site: Biography of Johannes Nicolaus Brönsted (1879-1947) . The Biography.
  3. Ralph E. Oesper. Oesper . Ralph E. . Johannes Nicolaus Bronsted (1879-) . Journal of Chemical Education . April 1938 . 15 . 4 . 151 . 10.1021/ed015p151. 1938JChEd..15..151. .
  4. Web site: Nomination Archive - Johannes N Brönsted . NobelPrize.org . 27 January 2021 . 1 April 2020.
  5. Web site: Johannes Nicolaus Brønsted . Kilder til Dansk Kunsthistorie . 26 January 2021.
  6. Ronnie Bell . Bell . R. P. . Prof. J. N. BrØnsted . Nature . February 1948 . 161 . 4086. 269 . 10.1038/161269a0. 1948Natur.161..269B . free .
  7. Ronnie Bell . Bell . R. P. . The Brönsted memorial lecture . J. Chem. Soc. . 1950 . 409–419 . 10.1039/JR9500000409.
  8. Johannes Nicolaus Brønsted. Brönsted . J. N. . Einige Bemerkungen über den Begriff der Säuren und Basen (Some observations about the concept of acids and bases) . Recueil des Travaux Chimiques des Pays-Bas . 1923 . 42 . 8 . 718–728 . 10.1002/recl.19230420815.
  9. Martin Lowry . Lowry . T. M. . The uniqueness of hydrogen . Journal of the Society of Chemical Industry . 19 January 1923 . 42 . 3 . 43–47 . 10.1002/jctb.5000420302 .
  10. Encyclopedia: Johannes Nicolaus Brønsted . . March 28, 2012.
  11. Johannes Nicolaus Brønsted . Brønsted . J. N. . George de Hevesy . Hevesy . G. . The Separation of the Isotopes of Mercury . Nature . September 1920 . 106 . 2657 . 144 . 10.1038/106144c0. 1920Natur.106Q.144B . free .