Ixiolite Explained

Ixiolite
Category:Oxide minerals
Formula: or
Imasymbol:Ix[1]
Strunz:4.DB.25
System:Orthorhombic, some varieties might be monoclinic
Class:Dipyramidal (mmm)
H-M symbol: (2/m 2/m 2/m)
Symmetry:Pbcn
Unit Cell:a = 4.785, b = 5.758
c = 5.16 [Å]; Z = 4
Color:Steel-grey, black
Habit:Irregular granular or inclusions, also as prismatic crystals; some varieties might be pseudoorthorhombic
Twinning:Uncommon on
Fracture:Irregular/ uneven, sub-conchoidal
Tenacity:Brittle
Mohs:6 -
Luster:Sub-metallic
Diaphaneity:Opaque
Gravity:7.03 - 7.23
References:[2] [3] [4] [5]

Ixiolite is an accessory oxide mineral found in granitic pegmatites. It is an oxide with the general chemical formula or .

Structure

Ixiolite was originally reported as crystallizing in the monoclinic crystal system.[3] Detailed studies of the scandium, tin and titanium rich varieties indicate that they form crystals in the orthorhombic system whereas tungsten ixiolite is monoclinic.

Discovery and occurrence

It was first described in 1857 for an occurrence at Skogsböle, Kimito Island, Finland. The name is for Ixion, the Greek mythological character related to Tantalus, as the mineral contains tantalum.[2]

Ixiolite is typically associated with feldspar, tapiolite, cassiterite, microlite, and rutile.[3]

Substitution and varieties

Trace elements include zirconium, hafnium, titanium and tungsten.[3]

As with other tantalum and niobium bearing minerals considerable substitution and a number of varieties exist. Substitutions in the formula are common and the varieties stannian ixiolite (tin), titanian ixiolite (titanium) and wolframian ixiolite (tungsten) have been reported.[6]

Scandium is present in many ixiolite sample with percentages up to 4.0 percent Sc2O3, but usually less than one percent scandium oxide. High scandium ixiolites, containing from 4 to 19% scandium oxide are typically also rich in tin and titanium.[6]

Economic importance

Ixiolite together with microlite, tantalite, tapiolite, wodginite are the most important minerals mined for the element tantalum. Ixiolite contains about 69 % tantalum oxide (Ta2O5) and is a common constituent of coltan ore.[7]

Further reading

Notes and References

  1. Warr. L.N.. 2021. IMA–CNMNC approved mineral symbols. Mineralogical Magazine. 85. 3. 291–320. 10.1180/mgm.2021.43. 2021MinM...85..291W. 235729616. free.
  2. http://www.mindat.org/min-2059.html Mindat.org - Ixiolite
  3. Web site: Ixiolite. Handbook of Mineralogy. Mineralogical Society of America. 20 February 2013. 10 October 2012. https://web.archive.org/web/20121010135550/http://www.handbookofmineralogy.com/pdfs/ixiolite.pdf.
  4. http://www.webmineral.com/data/Ixiolite.shtml Ixiolite data on Webmineral
  5. https://www.mineralienatlas.de/lexikon/index.php/MineralData?mineral=Ixiolite Mineralienatlas
  6. Wise, M.A. . Černý, P. . Falster, A.U. . 1998 . Scandium substitution in columbite-group minerals and ixiolite . Canadian Mineralogist . 36 . 673–680 .
  7. Web site: Niobium-Tantalum. bgs.ac.uk. 2 March 2013.