Francium (87Fr) has no stable isotopes. A standard atomic weight cannot be given. Its most stable isotope is 223Fr with a half-life of 22 minutes, occurring in trace quantities in nature as an intermediate decay product of 235U.
Of elements whose most stable isotopes have been identified with certainty, francium is the most unstable. All elements with atomic number of 106 (seaborgium) or greater have most-stable-known isotopes shorter than that of francium, but as those elements have only a relatively small number of isotopes discovered, the possibility remains that undiscovered isotopes of these elements may have longer half-lives.
|-| 197Fr|| style="text-align:right" | 87| style="text-align:right" | 110| 197.01101(6)| 2.3(19) ms| α| 193At| (7/2−)||-| 198Fr|| style="text-align:right" | 87| style="text-align:right" | 111| 198.01028(3)| 15(3) ms| α| 194At| 3+#||-| 199Fr|| style="text-align:right" | 87| style="text-align:right" | 112| 199.00726(4)| 16(7) ms| α| 195At| 1/2+#||-| 200Fr|| style="text-align:right" | 87| style="text-align:right" | 113| 200.00657(8)| 24(10) ms| α| 196At| 3+#||-| style="text-indent:1em" | 200mFr| | colspan="3" style="text-indent:2em" | 60(110) keV| 190(120) ms| α| 196At| 10−#||-| rowspan=2|201Fr| rowspan=2|| rowspan=2 style="text-align:right" | 87| rowspan=2 style="text-align:right" | 114| rowspan=2|201.00386(8)| rowspan=2|67(3) ms| α (99%)| 197At| rowspan=2|(9/2−)| rowspan=2||-| β+ (1%)| 201Rn|-| rowspan=2|202Fr| rowspan=2|| rowspan=2 style="text-align:right" | 87| rowspan=2 style="text-align:right" | 115| rowspan=2|202.00337(5)| rowspan=2|290(30) ms| α (97%)| 198At| rowspan=2|(3+)| rowspan=2||-| β+ (3%)| 202Rn|-| rowspan=2 style="text-indent:1em" | 202mFr| rowspan=2|| rowspan=2 colspan="3" style="text-indent:2em" | 330(90)# keV| rowspan=2|340(40) ms| α (97%)| 198At| rowspan=2|(10−)| rowspan=2||-| β+ (3%)| 202Rn|-| rowspan=2|203Fr| rowspan=2|| rowspan=2 style="text-align:right" | 87| rowspan=2 style="text-align:right" | 116| rowspan=2|203.000925(17)| rowspan=2|0.55(2) s| α (95%)| 199At| rowspan=2|(9/2−)#| rowspan=2||-| β+ (5%)| 203Rn|-| rowspan=2|204Fr| rowspan=2|| rowspan=2 style="text-align:right" | 87| rowspan=2 style="text-align:right" | 117| rowspan=2|204.000653(26)| rowspan=2|1.7(3) s| α (96%)| 200At| rowspan=2|(3+)| rowspan=2||-| β+ (4%)| 204Rn|-| rowspan=2 style="text-indent:1em" | 204m1Fr| rowspan=2|| rowspan=2 colspan="3" style="text-indent:2em" | 50(4) keV| rowspan=2|2.6(3) s| α (90%)| 200At| rowspan=2|(7+)| rowspan=2||-| β+ (10%)| 204Rn|-| style="text-indent:1em" | 204m2Fr| | colspan="3" style="text-indent:2em" | 326(4) keV| 1.7(6) s||| (10−)| |-| rowspan=2|205Fr| rowspan=2|| rowspan=2 style="text-align:right" | 87| rowspan=2 style="text-align:right" | 118| rowspan=2|204.998594(8)| rowspan=2|3.80(3) s| α (99%)| 201At| rowspan=2|(9/2−)| rowspan=2||-| β+ (1%)| 205Rn|-| rowspan=2|206Fr| rowspan=2|| rowspan=2 style="text-align:right" | 87| rowspan=2 style="text-align:right" | 119| rowspan=2|205.99867(3)| rowspan=2|~16 s| β+ (58%)| 206Rn| rowspan=2|(2+, 3+)| rowspan=2||-| α (42%)| 202At|-| style="text-indent:1em" | 206m1Fr| | colspan="3" style="text-indent:2em" | 190(40) keV| 15.9(1) s||| (7+)||-| style="text-indent:1em" | 206m2Fr|| colspan="3" style="text-indent:2em" | 730(40) keV| 700(100) ms||| (10−)||-| rowspan=2|207Fr| rowspan=2|| rowspan=2 style="text-align:right" | 87| rowspan=2 style="text-align:right" | 120| rowspan=2|206.99695(5)| rowspan=2|14.8(1) s| α (95%)| 203At| rowspan=2|9/2−| rowspan=2||-| β+ (5%)| 207Rn|-| rowspan=2|208Fr| rowspan=2|| rowspan=2 style="text-align:right" | 87| rowspan=2 style="text-align:right" | 121| rowspan=2|207.99714(5)| rowspan=2|59.1(3) s| α (90%)| 204At| rowspan=2|7+| rowspan=2||-| β+ (10%)| 208Rn|-| rowspan=2|209Fr| rowspan=2|| rowspan=2 style="text-align:right" | 87| rowspan=2 style="text-align:right" | 122| rowspan=2|208.995954(16)| rowspan=2|50.0(3) s| α (89%)| 205At| rowspan=2|9/2−| rowspan=2||-| β+ (11%)| 209Rn|-| rowspan=2|210Fr| rowspan=2|| rowspan=2 style="text-align:right" | 87| rowspan=2 style="text-align:right" | 123| rowspan=2|209.996408(24)| rowspan=2|3.18(6) min| α (60%)| 206At| rowspan=2|6+| rowspan=2||-| β+ (40%)| 210Rn|-| rowspan=2|211Fr| rowspan=2|| rowspan=2 style="text-align:right" | 87| rowspan=2 style="text-align:right" | 124| rowspan=2|210.995537(23)| rowspan=2|3.10(2) min| α (80%)| 207At| rowspan=2|9/2−| rowspan=2||-| β+ (20%)| 211Rn|-| rowspan=2|212Fr| rowspan=2|| rowspan=2 style="text-align:right" | 87| rowspan=2 style="text-align:right" | 125| rowspan=2|211.996202(28)| rowspan=2|20.0(6) min| β+ (57%)| 212Rn| rowspan=2|5+| rowspan=2||-| α (43%)| 208At|-| rowspan=2|213Fr| rowspan=2|| rowspan=2 style="text-align:right" | 87| rowspan=2 style="text-align:right" | 126| rowspan=2|212.996189(8)| rowspan=2|34.14(6) s[1] | α (99.45%)| 209At| rowspan=2|9/2−| rowspan=2||-| β+ (.55%)| 213Rn|-| 214Fr|| style="text-align:right" | 87| style="text-align:right" | 127| 213.998971(9)| 5.0(2) ms| α| 210At| (1−)||-| style="text-indent:1em" | 214m1Fr|| colspan="3" style="text-indent:2em" | 123(6) keV| 3.35(5) ms| α| 210At| (8−)||-| style="text-indent:1em" | 214m2Fr|| colspan="3" style="text-indent:2em" | 638(6) keV| 103(4) ns||| (11+)||-| style="text-indent:1em" | 214m3Fr|| colspan="3" style="text-indent:2em" | 6477+Y keV| 108(7) ns||| (33+)||-| 215Fr|| style="text-align:right" | 87| style="text-align:right" | 128| 215.000341(8)| 86(5) ns| α| 211At| 9/2−||-|216Fr|| style="text-align:right" | 87| style="text-align:right" | 129|216.003198(15)|0.70(2) μs| α| 212At|(1−)||-| style="text-indent:1em" | 216mFr|| colspan="3" style="text-indent:2em" | 219(6) keV| 850(30) ns| α| 212At| (9−)||-| 217Fr|| style="text-align:right" | 87| style="text-align:right" | 130| 217.004632(7)| 16.8(19) μs| α| 213At| 9/2−||-| 218Fr|| style="text-align:right" | 87| style="text-align:right" | 131| 218.007578(5)| 1.0(6) ms| α| 214At| 1−||-|style="text-indent:1em" | 218m1Fr|| colspan="3" style="text-indent:2em" | 86(4) keV| 22.0(5) ms| α| 214At| (8−)||-| style="text-indent:1em" | 218m2Fr|| colspan="3" style="text-indent:2em" | 200(150)# keV|||| high||-| 219Fr|| style="text-align:right" | 87| style="text-align:right" | 132| 219.009252(8)| 20(2) ms| α| 215At| 9/2−||-| rowspan=2|220Fr| rowspan=2|| rowspan=2 style="text-align:right" | 87| rowspan=2 style="text-align:right" | 133| rowspan=2|220.012327(4)| rowspan=2|27.4(3) s| α (99.65%)| 216At| rowspan=2|1+| rowspan=2||-| β− (.35%)| 220Ra|-| rowspan=3|221Fr| rowspan=3|| rowspan=3 style="text-align:right" | 87| rowspan=3 style="text-align:right" | 134| rowspan=3|221.014255(5)| rowspan=3|4.9(2) min| α (99.9%)| 217At| rowspan=3|5/2−| rowspan=3|Trace[2] |-| β− (.1%)| 221Ra|-| CD (8.79×10−11%)[3] | 207Tl
14C|-| 222Fr|| style="text-align:right" | 87| style="text-align:right" | 135| 222.017552(23)| 14.2(3) min| β−| 222Ra| 2−||-| rowspan=2|223Fr| rowspan=2|Actinium K| rowspan=2 style="text-align:right" | 87| rowspan=2 style="text-align:right" | 136| rowspan=2|223.0197359(26)| rowspan=2|22.00(7) min| β− (99.99%)| 223Ra| rowspan=2|3/2(−)| rowspan=2|Trace[4] |-| α (.006%)| 219At|-| 224Fr|| style="text-align:right" | 87| style="text-align:right" | 137| 224.02325(5)| 3.33(10) min| β−| 224Ra| 1−||-| 225Fr|| style="text-align:right" | 87| style="text-align:right" | 138| 225.02557(3)| 4.0(2) min| β−| 225Ra| 3/2−||-| 226Fr|| style="text-align:right" | 87| style="text-align:right" | 139| 226.02939(11)| 49(1) s| β−| 226Ra| 1−||-| 227Fr|| style="text-align:right" | 87| style="text-align:right" | 140| 227.03184(11)| 2.47(3) min| β−| 227Ra| 1/2+||-| 228Fr|| style="text-align:right" | 87| style="text-align:right" | 141| 228.03573(22)#| 38(1) s| β−| 228Ra| 2−||-| 229Fr|| style="text-align:right" | 87| style="text-align:right" | 142| 229.03845(4)| 50.2(4) s| β−| 229Ra| (1/2+)#||-| 230Fr|| style="text-align:right" | 87| style="text-align:right" | 143| 230.04251(48)#| 19.1(5) s| β−| 230Ra|||-| 231Fr|| style="text-align:right" | 87| style="text-align:right" | 144| 231.04544(50)#| 17.6(6) s| β−| 231Ra| (1/2+)#||-| 232Fr|| style="text-align:right" | 87| style="text-align:right" | 145| 232.04977(69)#| 5(1) s| β−| 232Ra|||-| 233Fr|| style="text-align:right" | 87| style="text-align:right" | 146| 233.052518(21)| 900(100) ms| β−| 233Ra| 1/2+ #|