Holmium(III) nitrate explained

Holmium (III) nitrate is an inorganic compound, a salt of holmium and nitric acid with the chemical formula Ho(NO3)3.[1] The compound forms yellowish crystals, dissolves in water, also forms crystalline hydrates.[2]

Synthesis

Anhydrous salt is obtained by the action of nitrogen dioxide on holmium(III) oxide:

2Ho2O3+9N2O4 \xrightarrow{150oC 4Ho(NO
3)

3+6NO}

Effect of nitrogen dioxide on metallic holmium:

Ho+3N2O4 \xrightarrow{200oCHo(NO
3)

3+3NO}

Reaction of holmium hydroxide and nitric acid:

Ho(OH)3+3NHO3 \xrightarrow{150oCHo(NO
3)

3+3H2O}

Physical properties

Holmium(III) nitrate forms yellowish crystals.

Forms a crystalline hydrate of the composition Ho(NO3)3•5H2O.[3]

Soluble in water and ethanol.

Chemical properties

Hydrated holmitic nitrate thermally decomposes to form and decomposes to holmium oxide upon subsequent heating.

Application

The compound is used for the production of ceramics and glass.

Also used to produce metallic holmium and as a chemical reagent.

Notes and References

  1. Book: Лидин . Ростислав . Молочко . Вадим . Андреева . Лариса . Константы неорганических веществ. Справочник . 2 February 2019 . Litres . 978-5-04-077039-7 . 40 . 18 August 2021 . ru.
  2. Web site: 14483-18-2 - Holmium(III) nitrate pentahydrate, REacton®, 99.9% (REO) - 14588 - Alfa Aesar . . 18 August 2021.
  3. Web site: Holmium(III) nitrate pentahydrate . . 18 August 2021.