Holger Braunschweig Explained

Holger Braunschweig
Birth Date:1961
Birth Place:Germany
Nationality:German
Field:Chemistry, Inorganic Chemistry, Organometallic Chemistry, Main-Group Chemistry, Organoboron chemistry
Work Institution:University of Würzburg
Alma Mater:RWTH Aachen University
Known For:Organoboron chemistry, Borylene Chemistry, Diborynes, Diborenes
Website:https://www.braunschweiggroup.de/
Prizes:2009 DFG Gottfried Wilhelm Leibniz Prize, 2014 RSC Main Group Award,http://www.rsc.org/ScienceAndTechnology/Awards/MainGroupChemistryAward/2014-Winner.asp 2016 GDCh Alfred Stock Memorial Prize.http://www.chemistryviews.org/details/ezine/9870971/Alfred_Stock_Memorial_Award_2016.html

Holger Braunschweig is Head and Chair of Inorganic Chemistry at the Julius-Maximilians-University of Würzburg in Würzburg, Germany. He is best known for founding the field of transition metal-boron multiple bonding (transition metal borylenes),[1] [2] [3] [4] the synthesis of the first stable compounds containing boron-boron[5] and boron-oxygen[6] triple bonds, the isolation of the first non-carbon/nitrogen main-group dicarbonyl,[7] and the first fixation of dinitrogen at an element of the p-block of the periodic table.[8] By modifying a strategy pioneered by Prof. Gregory Robinson of the University of Georgia, Braunschweig also discovered the first rational and high-yield synthesis of neutral compounds containing boron-boron double bonds (diborenes).[9] [10] In 2016 Braunschweig isolated the first compounds of beryllium in the oxidation state of zero.[11]

Education and research career

Braunschweig obtained his Ph.D. and Habilitation from RWTH Aachen with P. Paetzold and worked as a postdoctoral researcher with Michael F. Lappert, FRS, at the University of Sussex, Brighton. After two years at Imperial College London as Senior Lecturer and Reader he took up a Chair of Inorganic Chemistry at the Julius-Maximilians-University of Würzburg in 2002, and is now also the founding director of the Institute for Sustainable Chemistry & Catalysis with Boron (ICB) .

Professional achievements

In 2009 Braunschweig was awarded the Gottfried Wilhelm Leibniz Prize of the German Research Foundation (DFG) – the highest German-based research prize. He was also awarded the 2014 RSC Main Group Awardhttp://www.rsc.org/ScienceAndTechnology/Awards/MainGroupChemistryAward/2014-Winner.asp and the 2016 Alfred Stock Memorial Prize of the German Society of Chemists.http://www.chemistryviews.org/details/ezine/9870971/Alfred_Stock_Memorial_Award_2016.html He is a Fellow of the Royal Society of Chemistry, a member of the German National Academy of Science (Leopoldina),https://www.leopoldina.org/en/members/list-of-members/member/1506/ the Bavarian Academy of Sciences and Humanities,http://www.badw.de/en/community-of-scholars/members.html?tx_badwdb_badwperson%5Bper_id%5D=338&tx_badwdb_badwperson%5BpartialType%5D=BADWPersonDetailsPartial&tx_badwdb_badwperson%5BmemberType%5D=&tx_badwdb_badwperson%5Baction%5D=show&tx_badwdb_badwperson%5 and the North Rhine-Westphalian Academy of Sciences, Humanities and the Arts.http://www.awk.nrw.de/akademie/mitglieder/korrespondierende-mitglieder.html

External links

Notes and References

  1. Braunschweig. Holger. Wagner. Trixie. 1995-04-13. Synthesis and Structure of the First Transition Metal Borylene Complexes. Angewandte Chemie International Edition in English. en. 34. 7. 825–826. 10.1002/anie.199508251. 1521-3773.
  2. Braunschweig. Holger. Kollann. Carsten. Englert. Ulli. 1998-12-04. Synthesis and Structure of the First Terminal Borylene Complexes. Angewandte Chemie International Edition. en. 37. 22. 3179–3180. 10.1002/(sici)1521-3773(19981204)37:22<3179::aid-anie3179>3.0.co;2-z. 29711330. 1521-3773.
  3. Braunschweig. Holger. Dewhurst. Rian D.. Schneider. Achim. 2010-07-14. Electron-Precise Coordination Modes of Boron-Centered Ligands. Chemical Reviews. 110. 7. 3924–3957. 10.1021/cr900333n. 20235583. 0009-2665.
  4. Braunschweig. Holger. Dewhurst. Rian D.. Gessner. Viktoria H.. 2013-03-25. Transition metal borylene complexes. Chemical Society Reviews. en. 42. 8. 3197–208. 10.1039/c3cs35510a. 23403460. 1460-4744.
  5. Braunschweig. Holger. Dewhurst. Rian D.. Hammond. Kai. Mies. Jan. Radacki. Krzysztof. Vargas. Alfredo. 2012-06-15. Ambient-Temperature Isolation of a Compound with a Boron-Boron Triple Bond. Science. en. 336. 6087. 1420–1422. 10.1126/science.1221138. 0036-8075. 22700924. 2012Sci...336.1420B. 206540959.
  6. Braunschweig. Holger. Radacki. Krzysztof. Schneider. Achim. 2010-04-16. Oxoboryl Complexes: Boron−Oxygen Triple Bonds Stabilized in the Coordination Sphere of Platinum. Science. en. 328. 5976. 345–347. 10.1126/science.1186028. 0036-8075. 20395506. 2010Sci...328..345B. 206525030.
  7. Braunschweig. Holger. Dewhurst. Rian D.. Hupp. Florian. Nutz. Marco. Radacki. Krzysztof. Tate. Christopher W.. Vargas. Alfredo. Ye. Qing. Multiple complexation of CO and related ligands to a main-group element. Nature. 522. 7556. 327–330. 10.1038/nature14489. 26085273. 2015Natur.522..327B. 2015. 4454142.
  8. Légaré. Marc-André. Bélanger-Chabot. Guillaume. Dewhurst. Rian D.. Welz. Eileen. Krummenacher. Ivo. Engels. Bernd. Braunschweig. Holger. 2018-02-23. Nitrogen fixation and reduction at boron. Science. en. 359. 6378. 896–900. 10.1126/science.aaq1684. 0036-8075. 29472479. 2018Sci...359..896L. free.
  9. Braunschweig. Holger. Dewhurst. Rian D.. 2013-03-25. Single, Double, Triple Bonds and Chains: The Formation of Electron-Precise B-B Bonds. Angewandte Chemie International Edition. en. 52. 13. 3574–3583. 10.1002/anie.201208189. 23362015. 1521-3773.
  10. Arrowsmith. Merle. Braunschweig. Holger. Stennett. Tom E.. 2017-01-02. Formation and Reactivity of Electron-Precise B−B Single and Multiple Bonds. Angewandte Chemie International Edition. en. 56. 1. 96–115. 10.1002/anie.201610072. 27860056. 1521-3773.
  11. Arrowsmith. Merle. Braunschweig. Holger. Celik. Mehmet Ali. Dellermann. Theresa. Dewhurst. Rian D.. Ewing. William C.. Hammond. Kai. Kramer. Thomas. Krummenacher. Ivo. Neutral zero-valent s-block complexes with strong multiple bonding. Nature Chemistry. en. 8. 9. 890–894. 10.1038/nchem.2542. 27334631. 2016NatCh...8..890A. 2016.