Hilkka I. Kenttämaa Explained
Hilkka Kenttämaa |
Alma Mater: | University of Helsinki(BS MS Phil.Lic. PhD) |
Thesis Title: | Unimolecular Gas Phase Reactions of Some Organophosphorus Ester Ions and Effects of Stepwise Collisional Excitation |
Thesis Year: | 1986 |
Awards: | Frank H. Field and Joe L. Franklin ACS Award for Outstanding Achievement in Mass Spectrometry |
Field: | Chemistry |
Work Institutions: | Purdue University |
Hilkka Inkeri Kenttämaa is a researcher in organic and bioorganic mass spectrometry, and the Frank Brown Endowed Distinguished Professor of Chemistry at Purdue University. She is a pioneer in distonic radical cation research and laser-induced acoustic desorption.
Early life and education
Kenttämaa had initially planned to study mathematics, instead of chemistry, despite both her parents being chemists. She studied at Helsinki University, earning a BS in 1977, a MS in 1978, a Phil. Lic.in 1981, and a PhD in Organic Chemistry in 1986. She did post-doctoral research with R. Graham Cooks at Purdue University in 1986.[1]
Career
She began her career as a research scientist at Helsinki University, the Academy of Finland, and as a visiting research scientist at Purdue University. She joined the faculty at Purdue University in 1989, and was promoted to Full Professor in 1999.[2] Her projects include using tandem mass spectrometry to study reaction mechanisms[3] [4] and fast pyrolysis process.[5] She is a pioneer in distonic radical cation research[6] and laser-induced acoustic desorption.[7] [8]
She was elected as a member of the Finish Academy of Science in 2004.[9] She serves as a subject editor in basic mass spectrometry for Mass Spectrometry Reviews.[10]
Honors and awards
Selected publications
Below is a list of articles co-authored by Kenttämaa, with over 100 citations:
- Vicki H. Wysocki; Hilkka I. Kenttämaa; R. Graham Cooks (1987) "Internal energy distributions of isolated ions after activation by various methods". International Journal of Mass Spectrometry and Ion Processes 75 (2): 181–208.[23]
- Krista M. Stirk; L. K. Marjatta Kiminkinen; Hilkka I. Kenttamaa (1992) "Ion-molecule reactions of distonic radical cations". Chemical Reviews 92 (7):1649–1665.[24]
- David S. Pinkston; Penggao Duan; Vanessa A. Gallardo; Steven C. Habicht; Xiaoli Tan; Kuangnan Qian; Murray Gray; Klaus Müllen; Hilkka I. Kenttämaa (2009) "Analysis of asphaltenes and asphaltene model compounds by laser-induced acoustic desorption/Fourier transform ion cyclotron resonance mass spectrometry". Energy Fuels 23 (11): 5564–5570.[25]
- David Borton, II; David S. Pinkston; Matthew R. Hurt; Xiaoli Tan; Khalid Azyat; Alexander Scherer; Rik Tykwinski; Murray Gray; Kuangnan Qian; Hilkka I. Kenttämaa (2010) "Molecular structures of asphaltenes based on the dissociation reactions of their ions in mass spectrometry". Energy Fuels 24 (10): 5548–5559.[26]
- Trenton H. Parsell; Benjamin C. Owen; Ian Klein; Tiffany M. Jarrell; Christopher L. Marcum; Laura J. Haupert; Lucas M. Amundson; Hilkka I. Kenttämaa; Fabio Ribeiro; Jeffrey T. Miller; Mahdi M. Abu-Omar (2013) "Cleavage and hydrodeoxygenation (HDO) of C–O bonds relevant to lignin conversion using Pd/Zn synergistic catalysis". Chemical Science 4 (2): 806–813.[27]
- Trenton Parsell; Sara Yohe; John Degenstein; Tiffany Jarrell; Ian Klein; Emre Gencer; Barron Hewetson; Matt Hurt; Jeong Im Kim; Harshavardhan Choudhari; Basudeb Saha; Richard Meilan; Nathan Mosier; Fabio Ribeiro; W. Nicholas Delgass; Clint Chapple; Hilkka I. Kenttämaa; Rakesh Agrawal; Mahdi M. Abu-Omar (2015) "A synergistic biorefinery based on catalytic conversion of lignin prior to cellulose starting from lignocellulosic biomass". Green Chemistry 17 (3): 1492–1499.[28]
- Hao Luo; Ian M. Klein; Yuan Jiang; Hanyu Zhu; Baoyuan Liu; Hilkka I. Kenttämaa; Mahdi M. Abu-Omar (2016) "Total utilization of miscanthus biomass, lignin and carbohydrates, using earth abundant nickel catalyst". ACS Sustainable Chemistry & Engineering 4 (4): 2316–2322.[29]
Book chapter
- Kawthar Z. Alzarieni; Hilkka I. Kenttämaa. "The distillation precipitation fractionation mass spectrometry (DPF-MS) method for molecular profiling of crude oil" in The Chemistry of Oil and Petroleum Products. Merv Fingas (Ed.). De Gruyter 2022.[30]
Patent applications
- High power laser induced acoustic desorption probe (2007) US 7619217 B2
- Laser-induced acoustic desorption/atmospheric pressure chemical ionization of compounds(2011) US 8344319 B2
- Sample deposition chamber for laser-induced acoustic desorption (liad) foils (2012) WO 2013103417 A3
- Differentially pumped dual linear quadrupole ion trap mass spectrometer (2015) US 9496127 B2
- Multichannel Pulsed Valve Inlet System (2019) US[31]
Notes and References
- Web site: Purdue Chemistry: Kenttämaa Labs: Hilkka I. Kenttämaa . 2022-06-07 . www.chem.purdue.edu.
- Web site: Purdue University: College of Science: Chemistry professor receives distinguished honors . 2022-06-07 . www.purdue.edu.
- Feng . Erlu . Ma . Xin . Kenttämaa . Hilkka I. . 2021-06-08 . Characterization of Protonated Substituted Ureas by Using Diagnostic Gas-Phase Ion-Molecule Reactions Followed by Collision-Activated Dissociation in Tandem Mass Spectrometry Experiments . Analytical Chemistry . en . 93 . 22 . 7851–7859 . 10.1021/acs.analchem.1c00326 . 34028247 . 235168836 . 0003-2700.
- Kumar . Rashmi . Kenttämaa . Hilkka I. . 2020-10-07 . Effects of Analyte Concentration on the Protonation Sites of 4-Aminobenzoic Acid upon Atmospheric Pressure Chemical Ionization As Revealed by Gas-Phase Ion–Molecule Reactions . Journal of the American Society for Mass Spectrometry . en . 31 . 10 . 2210–2217 . 10.1021/jasms.0c00285 . 32852952 . 221359886 . 1044-0305.
- Yu . Zaikuan . Murria . Priya . Easton . Mckay W. . Degenstein . John C. . Zhu . Hanyu . Xu . Lan . Agrawal . Rakesh . Delgass . W. Nicholas . Ribeiro . Fabio H. . Kenttämaa . Hilkka I. . 2019-10-24 . Exploring the Reaction Mechanisms of Fast Pyrolysis of Xylan Model Compounds via Tandem Mass Spectrometry and Quantum Chemical Calculations . The Journal of Physical Chemistry A . en . 123 . 42 . 9149–9157 . 10.1021/acs.jpca.9b04438 . 31545607 . 2019JPCA..123.9149Y . 202748635 . 1089-5639.
- Kiminkinen . L. K. Marjatta . Stirk . Krista G. . Kenttamaa . Hilkka I. . 1992 . A remarkably stable organic radical cation: the distonic isomer of the unstable radical cation of dimethyl propyl phosphate . Journal of the American Chemical Society . en . 114 . 6 . 2027–2031 . 10.1021/ja00032a015 . 0002-7863.
- Jarrell . Tiffany M. . Owen . Benjamin C. . Riedeman . James S. . Prentice . Boone M. . Pulliam . Chris J. . Max . Joann . Kenttämaa . Hilkka I. . 2017-06-01 . Laser-Induced Acoustic Desorption/Electron Ionization of Amino Acids and Small Peptides . Journal of the American Society for Mass Spectrometry . en . 28 . 6 . 1091–1098 . 10.1007/s13361-017-1684-1 . 28500583 . 2017JASMS..28.1091J . 41709530 . 1044-0305.
- Ma . Xin . Zhang . Yuyang . Lei . Hao-Ran . Kenttämaa . Hilkka I. . 2019-05-01 . Laser-induced acoustic desorption . MRS Bulletin . en . 44 . 5 . 372–381 . 10.1557/mrs.2019.105 . 2019MRSBu..44..372M . 164846809 . 1938-1425.
- Web site: Ulkomaiset jäsenet . 2022-06-07 . Tiedeakatemia . fi.
- Web site: Mass Spectrometry Reviews Editorial Board . June 7, 2022 . Wiley Analytical Science Mass Spectrometry Reviews.
- 1991-08-01 . ASMS News . Journal of the American Society for Mass Spectrometry . en . 2 . 4 . 350–353 . 10.1016/1044-0305(91)80027-5 . 1044-0305. free .
- Web site: 2015 . News and Views . 2022-06-07 . American Society for Mass Spectrometry.
- Web site: Research Awards . 2022-06-07 . www.asms.org.
- Web site: NSF Award Search: Award # 9631701 - Oxidative Damage and Repair of Biological Macromolecules . 2022-06-07 . www.nsf.gov.
- Web site: Hikka Kenttamaa presented 2009 Provost's Award for Outstanding Graduate Faculty Mentor - Purdue University Department of Chemistry . 2022-06-07 . www.chem.purdue.edu.
- Web site: Thayer . Ann M. . 2015 . Frank H. Field & Joe L. Franklin Award For Outstanding Achievement In Mass Spectrometry . 2022-06-07 . ACS Chemical and Engineering News.
- Web site: 2014-08-11 . ACS 2015 National Award Winners . 2022-06-07 . ACS Chemical & Engineering News.
- Web site: 2015-16 Innovators Hall of Fame Inductees - Office of Technology Commercialization - Purdue University . 2022-06-07 . www.prf.org.
- Web site: 2016 Fellows American Association for the Advancement of Science . 2022-06-07 . www.aaas.org . en.
- Web site: Hilkka Kenttamaa . 2022-06-07 . The Analytical Scientist . en.
- Web site: Purdue researchers part of team honored by NASA . 2022-06-07 . School of Aeronautics and Astronautics - Purdue University . en.
- Web site: Hoffpauir . Daniel . 2020-11-25 . 2020 NASA Engineering and Safety Center Honor Awards . 2022-06-07 . NASA.
- Wysocki . Vicki H. . Kenttämaa . Hilkka I. . Cooks . R.Graham . 1987 . Internal energy distributions of isolated ions after activation by various methods . International Journal of Mass Spectrometry and Ion Processes . en . 75 . 2 . 181–208 . 10.1016/0168-1176(87)83054-9. 1987IJMSI..75..181W .
- Stirk . Krista M. . Kiminkinen . L. K. Marjatta . Kenttamaa . Hilkka I. . 1992 . Ion-molecule reactions of distonic radical cations . Chemical Reviews . en . 92 . 7 . 1649–1665 . 10.1021/cr00015a008 . 0009-2665.
- Pinkston . David S. . Duan . Penggao . Gallardo . Vanessa A. . Habicht . Steven C. . Tan . Xiaoli . Qian . Kuangnan . Gray . Murray . Müllen . Klaus . Kenttämaa . Hilkka I. . 2009-11-19 . Analysis of Asphaltenes and Asphaltene Model Compounds by Laser-Induced Acoustic Desorption/Fourier Transform Ion Cyclotron Resonance Mass Spectrometry . Energy & Fuels . en . 23 . 11 . 5564–5570 . 10.1021/ef9006005 . 0887-0624.
- Borton . David . Pinkston . David S. . Hurt . Matthew R. . Tan . Xiaoli . Azyat . Khalid . Scherer . Alexander . Tykwinski . Rik . Gray . Murray . Qian . Kuangnan . Kenttämaa . Hilkka I. . 2010-10-21 . Molecular Structures of Asphaltenes Based on the Dissociation Reactions of Their Ions in Mass Spectrometry . Energy & Fuels . en . 24 . 10 . 5548–5559 . 10.1021/ef1007819 . 0887-0624.
- Parsell . Trenton H. . Owen . Benjamin C. . Klein . Ian . Jarrell . Tiffany M. . Marcum . Christopher L. . Haupert . Laura J. . Amundson . Lucas M. . Kenttämaa . Hilkka I. . Ribeiro . Fabio . Miller . Jeffrey T. . Abu-Omar . Mahdi M. . 2013 . Cleavage and hydrodeoxygenation (HDO) of C–O bonds relevant to lignin conversion using Pd/Zn synergistic catalysis . Chem. Sci. . en . 4 . 2 . 806–813 . 10.1039/C2SC21657D . 2041-6520.
- Parsell . Trenton . Yohe . Sara . Degenstein . John . Jarrell . Tiffany . Klein . Ian . Gencer . Emre . Hewetson . Barron . Hurt . Matt . Kim . Jeong Im . Choudhari . Harshavardhan . Saha . Basudeb . 2015 . A synergistic biorefinery based on catalytic conversion of lignin prior to cellulose starting from lignocellulosic biomass . Green Chemistry . en . 17 . 3 . 1492–1499 . 10.1039/C4GC01911C . 1210426 . 1463-9262.
- Luo . Hao . Klein . Ian M. . Jiang . Yuan . Zhu . Hanyu . Liu . Baoyuan . Kenttämaa . Hilkka I. . Abu-Omar . Mahdi M. . 2016-04-04 . Total Utilization of Miscanthus Biomass, Lignin and Carbohydrates, Using Earth Abundant Nickel Catalyst . ACS Sustainable Chemistry & Engineering . en . 4 . 4 . 2316–2322 . 10.1021/acssuschemeng.5b01776 . 2168-0485. free .
- Book: The Chemistry of Oil and Petroleum Products . 2022-05-23 . De Gruyter . 978-3-11-069452-9 . Fingas . Merv . 10.1515/9783110694529. 249083493 .
- Web site: Multichannel Pulsed Valve Inlet System Purdue OTC . 2022-06-07 . inventions.prf.org.