Hauerite Explained

Hauerite
Category:Sulfide mineral, pyrite group
Formula:MnS2
Imasymbol:Hr[1]
Molweight:119.07 g/mol
Strunz:2.EB.05a
System:Cubic
Class:Diploidal (m)
H–M symbol: (2/m)
Symmetry:Pa
Unit Cell:a = 6.107 Å; Z = 4
Color:Reddish brown or brownish black
Habit:Octahedral crystals and globular aggregates
Cleavage: Perfect, Perfect, Perfect on
Fracture:Uneven to subconchoidal
Tenacity:Brittle
Mohs:4
Luster:Metallic-adamantine
Streak:Reddish brown
Diaphaneity:Opaque to subtranslucent
Gravity:3.463
Opticalprop:Isotropic
Refractive:n = 2.69
References:[2] [3]

Hauerite is a manganese sulfide mineral with the chemical formula MnS2. It forms reddish brown or black octahedral crystals with the pyrite structure and it is usually found associated with the sulfides of other transition metals such as rambergite. It occurs in low temperature, sulfur rich environments associated with solfataras and salt deposits in association with native sulfur, realgar, gypsum and calcite.[2]

It was discovered in Austro-Hungarian Monarchy in Kalinka (now Vígľašská Huta-Kalinka village) sulfur deposit near Detva in what is now Slovakia in 1846 and named after the Austrian geologists, Joseph Ritter von Hauer (1778–1863) and Franz Ritter von Hauer (1822–1899).[2]

It is found in Texas, US; the Ural Mountains of Russia, and Sicily, Italy.[4]

Under high pressure conditions (P>11 GPa), Hauerite undergoes a large collapse in unit cell volume (22%) driven by a spin-state transition.[5]

Notes and References

  1. Warr. L.N.. 2021. IMA–CNMNC approved mineral symbols. Mineralogical Magazine. 85. 3. 291–320. 10.1180/mgm.2021.43. 2021MinM...85..291W. 235729616. free.
  2. Web site: Anthony . John W. . Bideaux . Richard A. . Bladh . Kenneth W. . Nichols . Monte C. . Hauerite . Handbook of Mineralogy . Mineral Data Publishing . 1 August 2022 . 2005.
  3. Web site: Barthelmy. David. 2014. Hauerite Mineral Data. 1 August 2022. Webmineral.com.
  4. Book: Rocks and Minerals . . 2012 . 978-1-4093-8659-9 . Star . Fleur.
  5. http://www.pnas.org/content/111/14/5106.abstract Kimber, S.A.J., et al., Giant pressure-induced volume collapse in the pyrite mineral MnS2, PNAS, April 8, 2014, vol. 111, no. 14, pp. 5106–5110