Gold(III) phosphate explained

Gold(III) phosphate is a chemical compound with the formula AuPO4. It is a pale yellow solid that is insoluble in water and acetone. It decomposes at 450 °C into gold metal, phosphorus pentoxide, and oxygen.[1]

Production

Gold(III) phosphate is produced by the reaction of gold(III) hydroxide and phosphoric acid at 130 °C:

AuO(OH) + H3PO4 → AuPO4 + 2H2OIt can also be produced by the replacement of phosphoric acid with a mixture of nitric acid and phosphorus pentoxide.

Notes and References

  1. Pd2P2O7 AND AuPO4 - NEW ANHYDROUS PHOSPHATES OF NOBLE METALS . Phosphorus Research Bulletin . 2005 . 19 . 77–82 . 10.3363/prb1992.19.0_77 . Japanese Association of Inorganic Phosphorus Chemistry . en. free .