Etifelmine Explained

Etifelmine (INN; also known as gilutensin) is a stimulant drug. It was used for the treatment of hypotension (low blood pressure).[1]

Synthesis

The base-catalyzed reaction between benzophenone (1) and butyronitrile (2) gives 2-[hydroxy(diphenyl)methyl]butanenitrile (3).[2] [3] Catalytic hydrogenation reduces the nitrile group to a primary amine giving 1,1-diphenyl-2-ethyl-3-aminopropanol (4). The tertiary hydroxyl group is dehydrated by treatment with anhydrous hydrogen chloride gas, completing the synthesis of etifelmine (5).

See also

References

  1. Poepelmann H . The treatment of hypotensive circulatory disorders with gilutensin. . Therapie der Gegenwart . German . August 1964 . 103 . 1007–12 . 14254672 .
  2. https://pharmaceutical-substances.thieme.com/ps/search-results?docUri=KD-05-0097 Etifelmine
  3. Dr Werner Heinrich & Dr Walter Heigel, (1962 to Giulini Gmbh Geb).