Germanite Explained

Germanite
Category:Sulfide mineral
Formula:Cu26Ge4Fe4S32[1]
Imasymbol:Ger[2]
Strunz:2.CB.30
Dana:2.9.4.2
System:Isometric
Class:Hextetrahedral (3m)
H-M symbol: (3m)
Symmetry:P3n
Color:Reddish grey tarnishing to dark brown
Habit:Usually massive; rarely as minute cubic crystals
Cleavage:None
Tenacity:Brittle
Mohs:4
Luster:Metallic
Streak:Dark grey to black
Gravity:4.4 to 4.6
Diaphaneity:Opaque
Other:Cell data: a = 10.585 Å Z = 1
References:[3] [4]

Germanite is a rare copper iron germanium sulfide mineral, Cu26Fe4Ge4S32. It was first discovered in 1922, and named for its germanium content. It is only a minor source of this important semiconductor element, which is mainly derived from the processing of the zinc sulfide mineral sphalerite.[5] Germanite contains gallium, zinc, molybdenum, arsenic, and vanadium as impurities.

Its type locality is the Tsumeb Mine in Namibia where it occurs in a hydrothermal polymetallic ore deposit in dolomite in association with renierite, pyrite, tennantite, enargite, galena, sphalerite, digenite, bornite and chalcopyrite.[4] It has also been reported from Argentina, Armenia, Bulgaria, Cuba, Democratic Republic of Congo (Zaire), Finland, France, Greece, Japan, Republic of Congo (Brazzaville), Russia and the United States.[6]

X-Ray Powder Diffraction[7]
d spacing3.052.651.871.601.321.211.081.02
relative intensity101741221

Notes and References

  1. American Mineralogist (1984) 69:943-947
  2. Warr. L.N.. 2021. IMA–CNMNC approved mineral symbols. Mineralogical Magazine. 85. 3. 291–320. 10.1180/mgm.2021.43. 2021MinM...85..291W. 235729616. free.
  3. http://webmineral.com/data/Germanite.shtml Webmineral
  4. http://rruff.geo.arizona.edu/doclib/hom/germanite.pdf Handbook of Mineralogy
  5. U.S. Geological Survey (2008), "Germanium—Statistics and Information", U.S. Geological Survey, Mineral Commodity Summaries http://minerals.usgs.gov/minerals/pubs/commodity/germanium/
  6. http://www.mindat.org/min-1681.html Mindat.org
  7. Dana's New Mineralogy, 8th edition, Gaines et al., Wiley