Epsomite Explained

Epsomite
Category:Sulfate mineral
Imasymbol:Esm[1]
Strunz:7.CB.40
Dana:29.6.11.1
System:Orthorhombic
Class:Disphenoidal (222)
H-M symbol: (2 2 2)
Symmetry:P2₁2₁2₁
Unit Cell: = 11.86, = 11.99
= 6.858 [Å];
Color:White, grey, colorless, or pink, greenish
Habit:Acicular to fibrous encrustations
Twinning:Rarely observed on
Cleavage: perfect distinct
Fracture:Conchoidal
Mohs:2
Luster:Vitreous, silky when fibrous
Diaphaneity:Transparent to translucent
Gravity:1.67–1.68 g/ml
Opticalprop:Biaxial (−)
Refractive: = 1.433 = 1.455 = 1.461
Birefringence: = 0.028
2V:Measured: 52°
Solubility:In water
Alteration:Dehydrates in dry air
References:[2] [3] [4]

Epsomite, Epsom salt, or magnesium sulfate heptahydrate, is a hydrous magnesium sulfate mineral with formula .

Physical properties

Epsomite crystallizes in the orthorhombic system. The normal form is as massive encrustations, while acicular or fibrous crystals are rarely found. It is colorless to white with tints of yellow, green and pink. It is a soft mineral with variable Mohs hardness around 2.0~2.5, and it has a low specific gravity [5]

It is readily soluble in water, and absorbs water from the air. It converts to hexahydrate with the loss of one water molecule and a switch to monoclinic structure.

The epsomite group includes solid solution series with morenosite (·) and goslarite (·).

Etymology

It was first systematically described in 1806 for an occurrence near Epsom, Surrey, England, after which it was named. It has been also referred to as "cave cotton" when in its fibrous form.

Occurrence

Epsomite forms as encrustations or efflorescences on limestone cavern walls and mine timbers and walls, rarely as volcanic fumarole deposits, and as rare beds in evaporite layers such as those found in certain bodies of salt water.[6] It occurs in association with melanterite, gypsum, halotrichite, pickeringite, alunogen, rozenite, and mirabilite.[4]

Naturally occurring epsomite in caverns can potentially produce particulates of inhalable size, and may contain significant amounts of toxic impurities.[7]

Uses

Epsom salt is commonly sold as the main ingredient in bath salt, with additives such as glycerin (used as a humectant) and fragrances. The purpose of bath salts is mostly to make the bathing experience more enjoyable and serve as a vehicle for cosmetics, though they are said to improve cleaning and aid in exfoliation.[8]

Research on topical magnesium (for example Epsom salt baths) is very limited.[9] The trade organization 'Epsom Salt Council' recommends bathing 2 or 3 times/week, using Epsom salts each time.[10]

Gallery

See also

Notes and References

  1. Warr . L.N. . 2021 . IMA–CNMNC approved mineral symbols . Mineralogical Magazine . 85 . 3 . 291–320 . 10.1180/mgm.2021.43 . free . 2021MinM...85..291W . 235729616 .
  2. Web site: Epsomite . Web Mineral (webmineral.com) .
  3. Web site: Epsomite . Mindat.org .
  4. Epsomite . Handbook of Mineralogy . .
  5. Web site: Epsomite . dead . https://web.archive.org/web/20060317160728/http://mineral.galleries.com/minerals/sulfates/epsomite/epsomite.htm . 2006-03-17 . Mineral galleries (mineral.galleries.com) . Sulfates . dmy-all.
  6. Book: McGraw-Hill Encyclopedia of Science & Technology . 10th . 2007 . New York, NY . McGraw-Hill . 9780071441438 . 84152915.
  7. Giordani . Matteo . Meli . Maria Assunta . Roselli . Carla . Betti . Michele . Peruzzi . Fabio . Taussi . Marco . Valentini . Laura . Fagiolino . Ivan . Mattioli . Michele . April 2022 . Could soluble minerals be hazardous to human health? Evidence from fibrous epsomite . Environmental Research . en . 206 . 112579 . 10.1016/j.envres.2021.112579. 34968437 . 2022ER....20612579G .
  8. Book: Browning, Marie . 1999 . Natural Soapmaking . . New York, NY . Sterling . 0-8069-6289-5 . 42598586 .
  9. Web site: Rath . Linda . Why take an epsom salts bath? . A-to-Z guides . WebMD (webmd.com) . en-US .
  10. Report on absorption of magnesium sulfate . Epsom Salt Council . October 2015 . commercial / promotional . epsomsaltcouncil.org .