Ethyltoluene Explained

Ethyltolune describes organic compounds with the formula . Three isomers exist: 1,2- 1,3-, and 1,4-. All are colorless liquids, immiscible in water, with similar boiling points. They are classified are aromatic hydrocarbons. The ring bears two substituents: a methyl group and an ethyl group.

Cymenes
Name2-ethyltoluene 3-ethyltoluene 4-Ethyltoluene
Structural formula
CAS number611-14-3 620-14-4 622-96-8
melting point-80.8 -95.5 -62.3
boiling point (°C)165 161.3 162

Production and reactions

Ethyltoluenes are prepared by alkylation of toluene with ethylene:

These alkylations are catalyzed by various Lewis acids, such as aluminium trichloride.

3- and 4-Ethyltoluenes are mainly of interest as precursors to methylstyrenes:

This dehydrogenation is conducted in the presence of zinc oxide catalysts.[1]

Notes and References

  1. Book: 10.1002/14356007.a13_227.pub3 . Hydrocarbons . Ullmann's Encyclopedia of Industrial Chemistry . 2014 . Schmidt . Roland . Griesbaum . Karl . Behr . Arno . Biedenkapp . Dieter . Voges . Heinz-Werner . Garbe . Dorothea . Paetz . Christian . Collin . Gerd . Mayer . Dieter . Höke . Hartmut . 1–74 . 9783527306732 .