Earlandite Explained

Earlandite
Category:Organic minerals
Formula:[Ca<sub>3</sub>(C<sub>6</sub>H<sub>5</sub>O<sub>7</sub>)<sub>2</sub>(H<sub>2</sub>O)<sub>2</sub>]·2H2O
Imasymbol:Ear[1]
Strunz:10.AC.15
Symmetry:P (No. 2)
Unit Cell:a = 5.9466(4), b = 10.2247(8)
c = 16.6496(13) [Å]; Z = 2
Color:White, pale yellow
Habit:Nodular
Refractive:nα = 1.515
nβ = 1.530
nγ = 1.580
Opticalprop:Biaxial (+)
2V:60°
Birefringence:δ = 0.065
Streak:White
Gravity:1.80–1.95 (measured), 2.00 (calculated)
Diagnostic:Fine-grained and wart-like nodule crystal habit
Solubility:Insoluble
Diaphaneity:Transparent
References:[2] [3] [4] [5]

Earlandite, [Ca<sub>3</sub>(C<sub>6</sub>H<sub>5</sub>O<sub>7</sub>)<sub>2</sub>(H<sub>2</sub>O)<sub>2</sub>]·2H2O, is the mineral form of calcium citrate tetrahydrate. It was first reported in 1936 and named after the English microscopist and oceanographer Arthur Earland FRSE. Earlandite occurs as warty fine-grained nodules ca. 1 mm in size in bottom sediments of the Weddell Sea, off Antarctica.[4] Its crystal symmetry was first assigned as orthorhombic, then as monoclinic, and finally as triclinic.[2]

Bibliography

Notes and References

  1. Warr. L.N.. 2021. IMA–CNMNC approved mineral symbols. Mineralogical Magazine. 85. 3. 291–320. 10.1180/mgm.2021.43. 2021MinM...85..291W. 235729616. free.
  2. Eberhardt . Herdtweck. Tobias . Kornprobst. Roland . Sieber. Leo . Straver. Johann . Plank. Crystal Structure, Synthesis, and Properties of tri-Calcium di-Citrate tetra-Hydrate [Ca<sub>3</sub>(C<sub>6</sub>H<sub>5</sub>O<sub>7</sub>)<sub>2</sub>(H<sub>2</sub>O)<sub>2</sub>]·2H2O. Z. Anorg. Allg. Chem.. 2011. 637. 6. 655–659. 10.1002/zaac.201100088.
  3. http://www.mindat.org/min-1344.html Earlandite
  4. Book: Anthony, John W. . Bideaux, Richard A. . Bladh, Kenneth W. . Nichols, Monte C. . Handbook of Mineralogy. Mineralogical Society of America. Chantilly, VA, US. Earlandite. 0962209740 . V (Borates, Carbonates, Sulfates). 2003.
  5. http://webmineral.com/data/Earlandite.shtml Earlandite