Dionisios Vlachos Explained

Dionisios G. Vlachos
Honorific Prefix:	Allan & Myra Ferguson Chair
Birth Place:	Greece
Nationality:	American
Field:	Chemical Engineer
Work Institution:	University of Delaware
Alma Mater:	University of Minnesota National Technical University of Athens
Doctoral Advisor:	Lanny D. Schmidt Rutherford Aris
Known For:	Catalysis, Reaction Engineering, Microreactors, Biomass
Prizes:	AIChE Wilhelm Award (2011), AAAS Fellow (2009)

Dionisios G. Vlachos is an American chemical engineer, the Allan & Myra Ferguson Endowed Chair Professor of Chemical Engineering at the University of Delaware and director of the Catalysis Center for Energy Innovation, a U.S. Department of Energy - Energy Frontiers Research Center. Throughout his career at University of Delaware and the University of Minnesota, he has advanced the study of catalysts and reaction engineering including catalytic applications in biomass utilization, alkane conversion and zeolites. He is a fellow of the American Association for the Advancement of Science (AAAS, 2009) and recipient of the Wilhelm Award of the American Institute of Chemical Engineers (2011).^[1]

Early life and education

Dionisios was born in Greece and grew up on the island of Cephalonia, Greece in the Ionian Sea. In 1987, he earned a diploma in chemical engineering from the National Technical University of Athens. He completed a master's degree in 1990 with thesis, "Step Dynamics for Modeling of Crystal Surfaces". He completed his Ph.D. in chemical engineering at the University of Minnesota in 1992 with advisors Lanny D. Schmidt and Rutherford Aris on the topic of dynamic crystal surfaces as it pertains to catalysis. His thesis was published in 1992 with the title, "Structure and Dynamics of Adsorbed Phases and Crystal Surfaces".^[2] During his time in graduate school, Dionisios prepared thirteen journal publications with his advisor including:

• D. G. Vlachos, L. D. Schmidt, and R. Aris, The Effect of Phase Transitions, Surface Diffusion, and Defects on Surface Reactions: Fluctuations and Oscillations, J. Chem. Phys. 93, 8306-8313 (1990).^[3]
• D.G. Vlachos, L.D. Schmidt, R. Aris Structures of Small Metal Clusters: Isomerization and Phase Transitions, Journal of Chemical Physics 96, 6891 (1992).^[4]
• D.G. Vlachos, F. Schuth, R. Aris, L.D. Schmidt "Spatial and Temporal Patterns in Catalytic Oscillations", Physics A: Statistical Mechanics and its Applications 188(1-3), 302-321 (1992).^[5]

Professor of chemical engineering

Dr. Vlachos joined the University of Massachusetts Amherst Department of Chemical Engineering in Amherst, MA in 1993 as an assistant professor. He was promoted to associate professor in 1998, after which he took a position as associate professor of chemical engineering at the University of Delaware in 2000. In 2003, he was promoted to the rank of professor of chemical engineering. In 2009, he became the Elizabeth Inez Kelley Professor of Chemical Engineering, a position which he held until 2016. In 2015, he became a professor (joint) of physics and astronomy at the University of Delaware.

Leadership roles

Vlachos has served in leadership roles with national and international oversight of chemical engineering research. In 2008, he became the director of the University of Delaware Center for Catalytic Science and Technology (CCST), which he held until 2011.^[6] In 2009, he led the formation of the Catalysis Center for Energy Innovation (CCEI), a national Department of Energy research center with over 70 people from around the United States.^[7] In 2016, he was appointed the director of the Delaware Energy Institute (UDEI).^[8] He is also the fundamentals division leader within the Dept. of Energy RAPID Manufacturing Institute starting in 2017.^[9]

Research

Vlachos' research has focused on four areas of chemical engineering and materials science:

Surface chemistry and catalysis

His contributions to catalysis and surface chemistry have addressed the challenges associated with combining experiment, calculation and modeling for complex catalysis. For example, he has published numerous papers on the reforming of hydrocarbons, including microkinetic descriptions of hundreds of reactions on supported metals.^[10] Other research has addressed liquid phase dehydration and/or hydrodeoxygenation of biomass-derived molecules such as furfural, dimethylfuran, or benzoic acid.^[11] He has expanded on general approaches to catalytic design by using descriptors in parallel with efforts to develop reaction models with the accuracy of first principles approaches.^[12]

Nanoparticles and synthesis

His interest in nanoparticles includes his master's thesis entitled, "Step Dynamics for Modeling of Crystal Surfaces." A focus on crystal structures and growth behavior continued with a focus on the nucleation, growth and design of nanoporous materials including zeolites and MOFs.^[13] His research on nanoparticle synthesis was frequently combined in the impact on applications including catalysis, adsorption, and separation via membranes.^[14]

Modeling and simulation

Vlachos' approach to modeling is identified by its breadth of scale from molecular, to particle, and macroscale for applications across reaction chemistry, separations, and biology.^[15] His interests also include advanced approaches to couple molecular dynamics with quantum mechanical simulations as well as accelerate stochastic simulations.^[16]

Energy, fuels and reactors

Vlachos' research in engineering and science applications in to fuel and energy address broad areas including microreactor design, catalyst design, chemical reaction network development for fuel chemistry, and optimization of energy systems.^[17] For example, his research on hydrocarbon microflame stability provides insight into the design principles of microburners.^[18] He has also developed molecular-level descriptions of the pyrolysis of cellulose and biomass with applications in renewable biofuels.^[19]

Broader impact

His research has had broader impact on the educational and industrial sectors by translation of his interests beyond the university.

His research in collaboration with his colleagues has directly led to the following technologies:

• Advanced electrodes for fuel cells: As a replacement for platinum, Vlachos and co-workers have developed a tungsten carbide material composed of nanoparticles with improved performance.^[20]
• Renewable rubber for automobile tires: Chemical conversion of sugar to isoprene provides a renewable pathway to manufacture poly-(cis)-isoprene, the key rubber material in automobile tires. Vlachos and co-workers have developed a catalyst and process to synthesize isoprene at high yield.^[21]
• Advanced soap and surfactants: The preparation of advanced soaps/detergents (i.e., surfactants), includes unique chemical properties and a chemical process for manufacture. As part of the Catalysis Center for Energy Innovation, Vlachos and co-workers have developed a class of "oleo-furan sulfonate" (OFS) surfactants with unique properties beyond conventional molecules.^[22]
• Renewable PET polyester: Vlachos and co-workers have developed a catalyst and process to make para-xylene, the key monomer in the plastic PET (poly-ethylene-terephthalate).^[23]

Teaching and advising

Vlachos has supervised and mentored over 50 graduate Ph.D. students and 40 post-doctoral scholars.^[24] His advising has produced numerous industrial leaders and faculty in the academia, with several former students at leading institutions of research and education including Jeff Rimer (Univ. of Houston), Mark Snyder (Lehigh University), Ayman Karim (Virginia Tech), George Tsilomelekis (Rutgers University), and Giannis Mpourmpakis (Univ. of Pittsburgh).^{[25] [26] [27]}

Journal publications

Dionisios Vlachos has authored more than 350 journal articles describing significant advances in catalysis, microreactors, and energy applications which include:

• V. Nikolakis, E. Kokkoli, M. Tirrell, M. Tsapatsis, D.G. Vlachos "Zeolite growth by addition of subcolloidal particles: Modeling and experimental validation", Chemistry of Materials, 12(3), 845-853 (2000).^[28]
• Z. Lai, Griselda Bonilla, I. Diaz, J.G. Nery, K. Sujaoti, M.A. Amat, E. Kokkoli, O. Terasaki, R.W. Thompson, M. Tsapatsis, D.G. Vlachos "Microstructural optimization of a zeolite membrane for organic vapor separation", Science, 300(5618), 456-460 (2003).^[29]
• Y. Chen, D.G. Vlachos "Hydrogenation of ethylene and dehydrogenation and hydrogenolysis of ethane on Pt (111) and Pt (211): a density functional theory study", Journal of Physical Chemistry C, 114(11), 4973-4982 (2010).^[30]
• Vassili Vorotnikov, Giannis Mpourmpakis, Dionisios G Vlachos "DFT study of furfural conversion to furan, furfuryl alcohol, and 2-methylfuran on Pd (111)", ACS Catalysis, 2(12), 2496-2504 (2012).^[31]
• V. Choudhary, S.H. Mushrif, C. Ho, A. Anderko, V. Nikolakis, N.S. Marinkovic, A.I. Frenkel, S.I. Sandler, D.G. Vlachos"Insights into the interplay of Lewis and Brønsted acid catalysts in glucose and fructose conversion to 5-(hydroxymethyl) furfural and levulinic acid in aqueous media", Journal of the American Chemical Society, 135(10), 3997-4006 (2013).^[32]

Awards and honors

Vlachos' contributions to research, education and service have received numerous awards, many of which demonstrate his interests in catalysis, mathematics and the problems associated with energy and sustainability. In 2016, he was appointed director of the University of Delaware Energy Institute. His appointment was highlighted as:

Other awards and honors include:^[33]

• (2016) Philadelphia Catalysis Club Award^[34]
• (2015) ICI Distinguished Lecture, University of Alberta ^[35]
• (2014) J.D. Lindsay Lecture Series, Texas A&M University
• (2011) R.H. Wilhelm Award in Chemical Reaction Engineering^[36]
• (2009) AAAS Fellow ^[37]
• (2007) George Piercy Distinguished Visiting Professorship - Univ. of Minnesota
• (2003) Provost's Merit Award - Univ. of Delaware
• (1997) NSF Career Award

External links

• Chemical & Biomolecular Engineering - Univ. of Delaware, Prof. Vlachos
• Vlachos Research Group
• Google Scholar - Dionisios Vlachos

Notes and References

1. Web site: AAAS Fellows - 2009 . AAAS . April 7, 2017.
2. Thesis - Raymond J. Gorte. .
3. The Effect of Phase Transitions, Surface Diffusion, and Defects on Surface Reactions: Fluctuations and Oscillations. The Journal of Chemical Physics. 93. 11. 8306. 10.1063/1.459313. 1990. Vlachos. D. G. Schmidt. L. D. Aris. R. free.
4. Structures of small metal clusters. II. Phase transitions and isomerization . The Journal of Chemical Physics . 96 . 9 . 6891 . 10.1063/1.462583 . 1992 . Vlachos . D. G . Schmidt . L. D . Aris . R . 1992JChPh..96.6891V .
5. Spatial and Temporal Patterns in Catalytic Oscillations. Physica A: Statistical Mechanics and Its Applications. 188. 1–3. 302–321. 10.1016/0378-4371(92)90275-U. 1992. Vlachos. D.G.. Schüth. F.. Aris. R.. Schmidt. L.D.. 1992PhyA..188..302V.
6. Delaware Center for Catalytic Science & Technology. 2 March 2018.
7. Membership - Catalysis Center for Energy Innovation. 2 March 2018.
8. Leadership - Delaware Energy Institute. 2 March 2018.
9. RAPID - Intensified Process Fundamentals. 2 March 2018. 2017-10-03.
10. Hierarchical multiscale mechanism development for methane partial oxidation and reforming, and for thermal decomposition of oxygenates on Rh. The Journal of Physical Chemistry B. 109. 35. 16819–35. 10.1021/jp052479t. 16853141. 2005. Mhadeshwar. A. B. Vlachos. D. G.
11. Hydrodeoxygenation of HMF Over Pt/C in a Continuous Flow Reactor. AIChE Journal. 61. 2. 590. 10.1002/aic.14660. 2015. Luo. Jing. Arroyo-Ramírez. Lisandra. Gorte. Raymond J. Tzoulaki. Despina. Vlachos. Dionisios G.
12. Building large microkinetic models with first-principles' accuracy at reduced computational cost. Chemical Engineering Science. 121. 190–199. 10.1016/j.ces.2014.09.011. 2015. Sutton. Jonathan E.. Vlachos. Dionisios G.. free.
13. Zeolite growth by addition of subcolloidal particles: Modeling and experimental validation. Chemistry of Materials. 12. 3. 845. 10.1021/cm990653i. 2000. Nikolakis. Vladimiros. Kokkoli. Efrosini. Tirrell. Matthew. Tsapatsis. Michael. Vlachos. Dionisios G.
14. Microstructural optimization of a zeolite membrane for organic vapor separation. Science. 191. 4226. 485–487. 10.1126/science.1082169. 12624179. 2003. Salama. G.. Morad. M.. Diaz. I.. Nery. J. G.. Sujaoti. K.. Amat. M. A.. Kokkoli. E.. Terasaki. O.. Thompson. R. W.. Tsapatsis. M.. Vlachos. D. G.. 2003Sci...300..456L. 25364470. free.
15. Vlachos Research Group - Research Areas. 2 March 2018.
16. Vlachos Research. 2 March 2018.
17. Combustion characteristics and flame stability at the microscale: a CFD study of premixed methane/air mixtures. Chemical Engineering Science. 58. 21. 4871–4882. 10.1016/j.ces.2002.12.005. 2003. Norton. D.G.. Vlachos. D.G..
18. A CFD study of propane/air microflame stability. Combustion and Flame. 138. 1–2. 97–107. 10.1016/j.combustflame.2004.04.004. 2004. Norton. D.G.. Vlachos. D.G..
19. Revealing pyrolysis chemistry for biofuels production: Conversion of cellulose to furans and small oxygenates. Energy Environ. Sci.. 5. 5414–5424. 2 March 2018. 10.1039/C1EE02743C. 2012. Mettler. Matthew S.. Mushrif. Samir H.. Paulsen. Alex D.. Javadekar. Ashay D.. Vlachos. Dionisios G.. Dauenhauer. Paul J..
20. New Material Could be the Catalyst to an Eco-Friendly Fuel Cell. 2 March 2018. 2017-10-09.
21. University of Delaware researchers look to make tires made from plants and wood. 2 March 2018.
22. 'Perfect' Soap Molecule. 2 March 2018.
23. Plants into Plastics. 2 March 2018.
24. Vlachos Alumni. 2 March 2018.
25. Giannis Bourmpakis - Univ. of Pittsburgh. 2 March 2018.
26. Mark Snyder - Lehigh University. 2 March 2018.
27. Jeff Rimer - University of Houston. 2 March 2018. 2016-05-25.
28. Zeolite growth by addition of subcolloidal particles: Modeling and experimental validation. Chemistry of Materials. 12. 3. 845. 10.1021/cm990653i. 2000. Nikolakis. Vladimiros. Kokkoli. Efrosini. Tirrell. Matthew. Tsapatsis. Michael. Vlachos. Dionisios G.
29. Microstructural optimization of a zeolite membrane for organic vapor separation. Science. 191. 4226. 485–487. 10.1126/science.1082169. 12624179. 2003. Salama. G.. Morad. M.. Diaz. I.. Nery. J. G.. Sujaoti. K.. Amat. M. A.. Kokkoli. E.. Terasaki. O.. Thompson. R. W.. Tsapatsis. M.. Vlachos. D. G.. 2003Sci...300..456L. 25364470. free.
30. Hydrogenation of ethylene and dehydrogenation and hydrogenolysis of ethane on Pt (111) and Pt (211): a density functional theory study. The Journal of Physical Chemistry C. 114. 11. 4973. 10.1021/jp909163z. 2010. Chen. Ying. Vlachos. Dionisios G.
31. DFT study of furfural conversion to furan, furfuryl alcohol, and 2-methylfuran on Pd (111). ACS Catalysis. 2. 12. 2496. 10.1021/cs300395a. 2012. Vorotnikov. Vassili. Mpourmpakis. Giannis. Vlachos. Dionisios G.
32. Insights into the interplay of Lewis and Brønsted acid catalysts in glucose and fructose conversion to 5-(hydroxymethyl) furfural and levulinic acid in aqueous media. Journal of the American Chemical Society. 135. 10. 3997–4006. 10.1021/ja3122763. 23432136. 2013. Choudhary. Vinit. Mushrif. Samir H. Ho. Christopher. Anderko. Andrzej. Nikolakis. Vladimiros. Marinkovic. Nebojsa S. Frenkel. Anatoly I. Sandler. Stanley I. Vlachos. Dionisios G.
33. Dionisios Vlachos. 2 March 2018.
34. Philadelphia Catalysis Club Award. 2 March 2018.
35. Previous iCI Distinguished Lecturers. 2 March 2018.
36. AIChE Wilhelm Award. 2 March 2018. 2012-03-28.
37. AAAS Fellow - Dionisios Vlachos. 2 March 2018.