Dichlorodifluoroethylene Explained

A dichlorodifluoroethylene (systematically named dichlorodifluoroethene) is one of three compounds with the chemical formula . Dichlorodifluoroethylenes are colourless gases, and are some of the simplest chlorodifluoroalkenes.

The structural isomers are used as intermediates or precursors in the production of other industrial chemicals.[1] [2]

1,1-Dichloro-2,2-difluoroethylene

1,1-Dichloro-2,2-difluoroethylene is a low-boiling liquid that is used a refrigerant.[3] It may also be used as a solvent, but has practical limitations as such, because of its low boiling point (commercial listings, 19 °C; lit. 17 °C).[4]

It is regarded as a hazardous chemical for being toxic by inhalation (see MSDS), and a low-boiling liquid, and it causes irritation when it comes into contact with the skin and mucous membranes. Its ASHRAE number is R-1112a, and its CAS number is 79-35-6. Concentrated 1,1-dichloro-2,2-difluoroethylene can be ignited with ease in the laboratory.

cis- And trans-1,2-dichloro-1,2-difluoroethylene

The diastereomers were co-isolated first in 1965, by using a combination of fractional melting and fractional distillation.[5] The cis isomer's ASHRAE number is R-1112c, and its CAS number is 311-81-9. Its melting point is . The trans isomer's ASHRAE number is R-1112t, and its CAS number is 381-71-5. Its melting point is . The diastereomers are commercially only available as a mixtures of varying proportions.

External links

Notes and References

  1. Web site: 1,1-Dichlorodifluoroethylene | 79-35-6 suppliers - BuyersGuideChem . www.buyersguidechem.com . 26 December 2013.
  2. Web site: Process for the preparation of 1,2-difluoro-ethylene and 1-chloro-1,2-difluoro-ethylene . www.google.nl . 26 December 2013.
  3. Web site: Refrigeration Technologies: Knowledge Center: Toxic Info: Refrigerant Safety Profile . 2013-12-05 . https://web.archive.org/web/20131224091223/http://refrigtech.com/Knowledge_Center/Toxic_Info/zsafety.html . 2013-12-24 . dead .
  4. Web site: Organic Syntheses Procedure.
  5. Craig. Norman C.. Evans, David A.. Infrared and Raman spectra of cis- and trans-1,2-dichloro-1,2-difluoroethylene. Journal of the American Chemical Society. 5 October 1965. 87. 19. 4223–4230. 10.1021/ja00947a001. ACS Publications.