Cr23C6 crystal structure explained

Cr₂₃C₆ is the prototypical compound of a common crystal structure, discovered in 1933^[1] as part of the chromium-carbon binary phase diagram. Over 85 known compounds adopt this structure type,^[2] which can be described as a NaCl-like packing of chromium cubes and cuboctahedra.^[3]

Structure

The space group of this structure is called Fmm (in Hermann–Mauguin notation) or "225" (in the International Tables for Crystallography). It belongs to a cubic crystal system, with Pearson symbol cF116.

The shortest interatomic distances are between carbon and chromium atoms, which is expected on the basis of atomic size. The carbon atoms are in positions that cap each face of the chromium cubes and their coordination environment can be thought of as distorted square antiprisms formed from chromium atoms of both the cubes and the cuboctahedra.

The closest Cr-Cr contacts are between members of a cuboctahedron, and the third closest are between members of a cube. The members of the cube, however, are closer to the 8 chromium atoms in the unit cell that are not part of either polyhedron. The coordination environment of these other atoms can be thought of as distorted Friauf polyhedra composed of chromium atoms, if next-nearest neighbors are included.

Materials

Examples of compounds that form in this structure type include Cr₂₃C₆, Mn₂₃C₆, and many ternary intermetallic carbides and borides.^[4] A few phases of ternary silicides, germanides, and phosphides are also known to exist.^{[5] [6]} In going from the binary to ternary systems, some of the transition metal atoms are substituted by a third element, which can be an alkali metal, alkaline earth metal, rare-earth element, main group element, or another transition metal. This leads to an empirical formula of the form A_23−xB_xC₆. Materials of this kind continue to be studied for potentially interesting magnetic and physical properties.^{[7] [8]}

References

1. Westgren, A. Crystal structure and composition of cubic chromium carbide. Jernkontorets Ann. 1933, 117, 501.
2. Villars, P. Pearson's Handbook of Crystallographic Data for Intermetallic Phases, vol. 1; ASM International: Materials Park, 1997.
3. Bowman . A. L. . Arnold . G. P. . Storms . E. K. . Nereson . N. G. . The crystal structure of Cr₂₃C₆ . Acta Crystallographica Section B: Structural Crystallography and Crystal Chemistry . International Union of Crystallography (IUCr) . 28 . 10 . 1972-10-15 . 0567-7408 . 10.1107/s0567740872007526 . 3102–3103.
4. Stadelmaier, H. H. Developments in the Structural Chemistry of Alloy Phases; Plenum Press: New York, 1969; p 141.
5. Gribanov . A.V. . Seropegin . Yu.D. . Bodak . O.I. . Crystal structure of the compounds Ce₃Pd₂₀Ge₆ and Ce₃Pd₂₀Si₆ . Journal of Alloys and Compounds . Elsevier BV . 204 . 1-2 . 1994 . 0925-8388 . 10.1016/0925-8388(94)90057-4 . L9–L11.
6. Keimes . V. . Mewis . A. . Mg₃Ni₂₀P₆ und Mn₃Ni₂₀P₆ - Zwei neue Phosphide mit Cr₂₃C₆-Struktur. Mg₃Ni₂₀P₆ and Mn₃Ni₂₀P₆ - Two new phosphides with the Cr₂₃C₆ structure . Zeitschrift für anorganische und allgemeine Chemie . Wiley . 618 . 12 . 1992 . 0044-2313 . 10.1002/zaac.19926180107 . 35–38 . de.
7. Eriksson . T. . Vennström . M. . Ronneteg . S. . Andersson . Y. . Nordblad . P. . Complex magnetic properties of Mn₃Ni₂₀P₆ and ferromagnetic structure of the new isostructural compound Mn₃Pd₂₀P₆ . Journal of Magnetism and Magnetic Materials . Elsevier BV . 308 . 2 . 2007 . 0304-8853 . 10.1016/j.jmmm.2006.05.016 . 203–209.
8. Veremchuk . I. . Gumeniuk . R. . Prots . Yu. . Schnelle . W. . Burkhardt . U. . Rosner . H. . Kuz'ma . Yu. . Leithe-Jasper . A. . Crystallographic and physical properties of RE_2−xNi₂₁B₆ (RE=Er, Yb and Lu) . Solid State Sciences . Elsevier BV . 11 . 2 . 2009 . 1293-2558 . 10.1016/j.solidstatesciences.2008.09.004 . 507–512.

External links

• International Crystal Structure Database