Carbonyl selenide explained

Carbonyl selenide is a chemical compound with the chemical formula . It is a linear molecule that is primarily of interest for research purposes.

Properties

Carbonyl selenide is a colorless gas with an unpleasant odor. Although the compound is quite stable, its solutions gradually revert to elemental selenium and carbon monoxide.[1]

Synthesis and reactions

Carbonyl selenide can be produced by treating selenium with carbon monoxide in the presence of amines.

It is used in organoselenium chemistry as a means of incorporating selenium into organic compounds, e.g. for the preparation of selenocarbamates (O-selenocarbamates and Se-selenocarbamates,, where R is organyl and R' and R" are any group, typically H or organyl).[2]

Notes and References

  1. Sonoda . Noboru . Selenium assisted carbonylation with carbon monoxide . Pure and Applied Chemistry . 65 . 4 . 699–706 . Great Britain . 1993 . 10.1351/pac199365040699. 96262544.
  2. Book: Banert, Klaus . Science of Synthesis Knowledge Updates 2014 . Georg Thieme Verlag . 3 . 2014 . 9783131763112.