Aza Paternò−Büchi reaction explained

Aza Paternò−Büchi reaction involves an ππ* excited state of alkene reacting with a ground state imine. This strategy was developed by the laboratory Sivaguru and co-workers[1] to overcome the shortcomings involving direct excitation of imines. Traditionally addition of excited imines to carbon-carbon double bonds involves making the imines as part of a carbocycle.[2]

Notes and References

  1. Kumarasamy. Elango. Kandappa. Sunil Kumar. Raghunathan. Ramya. Jockusch. Steffen. Sivaguru. Jayaraman. 2017-06-12. Realizing an Aza Paternò-Büchi Reaction. Angewandte Chemie International Edition. en. 56. 25. 7056–7061. 10.1002/anie.201702273. 28452104. free.
  2. Padwa. Albert.. February 1977. Photochemistry of the carbon-nitrogen double bond. Chemical Reviews. en. 77. 1. 37–68. 10.1021/cr60305a004. 0009-2665.

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