Arsenide chloride explained
Arsenide chlorides or chloride arsenides are compounds containing anions composed of chloride (Cl−) and arsenide (As3−). They can be considered as mixed anion compounds. They are in the category of pnictidehalides. Related compounds include the arsenide bromides, arsenide iodides, phosphide chlorides, and antimonide chlorides.
List
| formula | system | space group | unit cell Å | volume | density | comment | ref |
|---|
| Ca3AsCl3 | | Pm3m | a= 5.760 | | | | [1] |
| Sr2AsCl | | | | | | dark violet | [2] |
| Cd8As7Cl | cubic | P23 | a=7.266, Z=1 | | | | [3] |
| Hg7.4As4Cl6 | cubic | Pa3 | a= 12.178, Z= 4 | | | | [4] |
| (Hg6As4)(HgCl6)Hg0.5 | cubic | Pa | a=12.189 Z=4 | 1810.7 | 7.398 | yellow; air stable; band gap 2.01 | |
| (Hg6As4)[TiCl<sub>6</sub>]Cl | cubic | Pa3 | a = 1209.4 | | | | [5] |
| [Hg<sub>4</sub>As<sub>2</sub>][ZrCl<sub>6</sub>] | orthorhombic | Pbca | a=13.277 b=13.420 c=16.814 Z=8 | 2769.1 | 5.570 | dark yellow | [6] |
| [Hg<sub>4</sub>As<sub>2</sub>][HfCl<sub>6</sub>] | orthorhombic | Pbca | a=13.273 b=13.413 c=16.809 Z=8 | 2992 | 5.964 | orange | |
| (Hg3AsS)(GaCl4) | hexagonal | P63/mc | a =7.245, c =11.960, Z = 2 | 543.6 | 5.622 | light yellow | [7] |
| Hg3AsS4Cl | hexagonal | P63mc | a = 7.431, c = 9.003 Z=2 | | | yellow; air stable | [8] |
| [Hg<sub>6</sub>As<sub>4</sub>](CuCl3)2 | monoclinic | I2/a | a = 14.690, b = 9.1851, c = 20.285, β=92.170, Z=6 | | | | [9] |
| (Hg9.75As5.5)(GaCl4)3 | orthorhombic | Pmn21 | a=22.567 b=12.146 c=12.983 Z=4 | 3559 | 5.604 | | [10] |
| (Hg6As4)[MoCl<sub>6</sub>]Cl | cubic | Pa3 | a = 12.078 | | | | |
| [Hg<sub>6</sub>As<sub>4</sub>](AgCl3)2 | monoclinic | I2/a | a = 14.690, b = 9.1851, c = 20.285, β = 93.17°, Z = 4 | | | | [11] |
| (Hg6As4)(CdCl6)Hg0.5 | cubic | Pa | a=12.172 Z=4 | 1803.2 | 7.104 | yellow; air stable; band gap 2.05 | [12] |
| [Hg<sub>6</sub>As<sub>4</sub>](InCl6)Cl | cubic | Pa3 | a = 12.109, Z = 4 | | | dark red | [13] |
| [Hg<sub>6</sub>As<sub>4</sub>Cl<sub>3</sub>](SnCl3)Hg0.13 | cubic | P213 | a=12.233 Z=4 | | | | [14] |
| Hg3As2TlCl3 | orthorhombic | Pbcm | a = 6.292, b = 12.341 c = 12.248 Z=4 | | | red | [15] |
| Hg6As4BiCl7 | cubic | Pa3 | a=12.178 Z=4 | | | | [16] |
| [Hg<sub>4</sub>As<sub>2</sub>][UCl<sub>6</sub>] | orthorhombic | Pbca | a=13.316 b=13.636 c=16.853 Z=8 | 3060.0 | 6.090 | red | [17] | |
Notes and References
- Hadenfeldt . C. . Vollert . H. O. . August 1982 . Darstellung, thermisches Verhalten und Kristallstruktur des Calciumarsenidchlorids Ca3AsCl3 . Zeitschrift für anorganische und allgemeine Chemie . de . 491 . 1 . 113–118 . 10.1002/zaac.19824910115 . 0044-2313.
- Hadenfeldt . Claus . 1976-04-01 . Darstellung und Eigenschaften von Ca 2 AsBr, Sr 2 AsCl und Ca 3 AsBr 3 .: Preparation and Properties of Ca 2 AsBr, Sr 2 AsCl, and Ca 3 AsBr 3 . Zeitschrift für Naturforschung B . en . 31 . 4 . 408–410 . 10.1515/znb-1976-0403 . 1865-7117 . 95122668. free .
- Shevelkov . Andrei V. . Reshetova . Ludmila N. . Popovkin . Boris A. . December 1997 . Cd8As7Cl: A Novel Pnictidohalide with a New Structure Type . Journal of Solid State Chemistry . en . 134 . 2 . 282–285 . 10.1006/jssc.1997.7555. 1997JSSCh.134..282S .
- Shevelkov . Andrei V. . Dikarev . Evgeny V. . Popovkin . Boris A. . November 1996 . Two New Cubic Structures of Mercury Arsenidehalides . Journal of Solid State Chemistry . en . 126 . 2 . 324–327 . 10.1006/jssc.1996.0344. 1996JSSCh.126..324S .
- Synthese, Kristallstrukturen und Magnetismus von (Hg6As4)[MoCl6]Cl, (Hg6As4)[TiCl6]Cl und (Hg6As4)[TiBr6]Br. Zeitschrift für Anorganische und Allgemeine Chemie. 2000. 10.1002/1521-3749(200007)626:7<1620::AID-ZAAC1620>3.0.CO;2-R. Beck. Johannes. Neisel. Udo. 626. 7. 1620–1626.
- Li . Xiao-Guo . Jiang . Xiao-Ming . Zhang . Ming-Jian . Liu . Bin-Wen . Fan . Yu-Hang . Guo . Guo-Cong . Huang . Jin-Shun . 2013-12-02 . Three-Dimensional Mercury Pnictide [Hg 4 Z 2 ] 2+ Cationic Frameworks Stabilized by Tetravalent Metal Halide Anions in Supramolecular Complexes: [Hg 4 Z 2 ][MCl 6 ] (Z = P, As; M = Zr, Hf) . European Journal of Inorganic Chemistry . en . 2013 . 35 . 5980–5986 . 10.1002/ejic.201300888 . 1434-1948. free .
- Jiang . Xiao-Ming . Li . Xiao-Guo . Fan . Yu-Hang . Liu . Bin-Wen . Zeng . Hui-Yi . Guo . Guo-Cong . 2013 . New mercury-contained cationic frameworks stabilized by (GaCl4)− unit via weak electrostatic forces in supramolecular compounds (Hg11P4)(GaCl4)4 and (Hg3AsS)(GaCl4) . Dalton Transactions . en . 42 . 43 . 15475–15481 . 10.1039/c3dt51451j . 24022795 . 1477-9226.
- Beck . Johannes . Hedderich . Sylvia . Köllisch . Klaus . 2000-12-01 . Hg 3 AsE 4 X (E = S, Se; X = Cl, Br, I), a Family of Isotypic Compounds with an Acentric, Layered Structure . Inorganic Chemistry . en . 39 . 25 . 5847–5850 . 10.1021/ic0003527 . 11151388 . 0020-1669.
- Oleneva . Olga S. . Olenev . Andrei V. . Dikarev . Evgeny V. . Shevelkov . Andrei V. . June 2005 . Solid State Supramolecular Complexes [Hg6As4](CuX3)2 (X = Cl, Br): One-Dimensional Helical Guest in a Three-Dimensional Host Framework ]. Journal of Cluster Science . en . 16 . 2 . 273–285 . 10.1007/s10876-005-4548-y . 95453360 . 1040-7278.
- Jiang . Xiao-Ming . Yan . Zhi-Bo . Liu . Dan . Wang . Ke-Feng . Guo . Guo-Cong . Li . Shao-Zhen . Liu . Jun-Ming . October 2014 . Large and Fast Single-Crystal Resistive Humidity Sensitivity of Metal Pnictide Halides Containing van der Waals Host-Guest Interactions . Chemistry: An Asian Journal . en . 9 . 10 . 2872–2879 . 10.1002/asia.201402572. 25110860 . free .
- Oleneva . Olga S. . Olenev . Andrei V. . Dikarev . Evgeny V. . Shevelkov . Andrei V. . October 2004 . From Discrete to Extended Guests: A Novel Supramolecular [Hg 6 As 4 ](AgCl 3) 2 Assembly Featuring One-Dimensional (AgCl 3) 2− Anions ]. European Journal of Inorganic Chemistry . en . 2004 . 20 . 4006–4010 . 10.1002/ejic.200400205 . 1434-1948.
- Zou . Jian-Ping . Li . Yan . Fu . Ming-Lai . Guo . Guo-Cong . Xu . Gang . Liu . Xue-Hui . Zhou . Wei-Wei . Huang . Jin-Shun . March 2007 . The Synthesis, Crystal and Band Structures, and Properties of the Quaternary Supramolecular Complexes [Hg 6 Z 4 ](MX 6)Hg y (Z = As, Sb; M = Hg, Cd; X = Cl, Br, I; y = 0, 0.5, 0.6) ]. European Journal of Inorganic Chemistry . en . 2007 . 7 . 977–984 . 10.1002/ejic.200600894 . 1434-1948.
- Olenev . A. V. . Baranov . A. I. . Shatruk . M. M. . Tyablikov . A. S. . Shevelkov . A. V. . 2002 . Synthesis and the crystal structure of [Hg<sub>6</sub>As<sub>4](InCl6)Cl: influence of covalent and electrostatic factors on the supramolecular structure ]. Russian Chemical Bulletin . 51 . 3 . 444–448 . 10.1023/A:1015500116907. 92070325 .
- A New Family of Supramolecular Complexes with 3D Cationic Hg/Z Frameworks, SnX3− Guest Anions (Z = P, as, Sb; X = Cl, Br, I): Crystal Structures and Host−Guest Interactions. European Journal of Inorganic Chemistry. 2002. 10.1002/1099-0682(200203)2002:3<547::AID-EJIC547>3.0.CO;2-N. Olenev. Andrei V.. Baranov. Alexei I.. Shevelkov. Andrei V.. Popovkin. Boris A.. 2002. 3. 547–553.
- Polykationische Hg-Pnictid-Gerüste mit einer neuen Füllungsvariante in den Strukturen von Hg3As2TlCl3 und Hg3Sb2TlBr3. Zeitschrift für Anorganische und Allgemeine Chemie. 2001. 10.1002/1521-3749(200108)627:8<2016::AID-ZAAC2016>3.0.CO;2-N. Beck. Johannes. Neisel. Udo. 627. 8. 2016–2022.
- Beck . Johannes . Hedderich . Sylvia . Neisel . Udo . November 2000 . Synthesis and Crystal Structures of Hg6Sb5Br7, Hg6As4BiCl7, and Hg6Sb4BiBr7, Built of a Polycationic Mercury-Pnictide Framework with Trapped Anions . Journal of Solid State Chemistry . en . 154 . 2 . 350–355 . 10.1006/jssc.2000.8794. 2000JSSCh.154..350B .
- Bugaris . Daniel E. . Ibers . James A. . December 2008 . Syntheses, structures, and magnetic and optical properties of the compounds [Hg3Te2][UCl6] and [Hg4As2][UCl6] ]. Journal of Solid State Chemistry . en . 181 . 12 . 3189–3193 . 10.1016/j.jssc.2008.08.019. 2008JSSCh.181.3189B .
