Arsenic tetroxide explained

Arsenic tetroxide is an inorganic compound with the chemical formula As2O4, containing As(III) and As(V), AsIIIAsVO4.

Synthesis

It can be synthesized in an autoclave via the following reaction:

2 + → 2

Structure

It adopts a layer structure, and the coordination geometry of As(III) is triangular pyramid while As(V) is tetrahedral.[1]

Notes and References

  1. Jones. P. G.. Beesk, W.. Sheldrick, G. M.. Sharman, E.. Arsenic dioxide. Acta Crystallographica Section B. 14 February 1980. 36. 2. 439–440. 10.1107/S0567740880003433.