Afropectinariella doratophylla is a species of orchid in the genus Afropectinariella that is endemic to São Tomé and Príncipe. On São Tomé, it can be found from elevations of, growing with Syzygium guineense or with Bulbophyllum lizae. On Príncipe, it is found in shrubby vegetation at around elevation. It is threatened by deforestation for agriculture and timber.