Ammonium phosphomolybdate explained

Ammonium phosphomolybdate is the inorganic salt of phosphomolybdic acid with the chemical formula (NH4)3PMo12O40. The salt contains the phosphomolybdate anion, a well known heteropolymetalate of the Keggin structural class.

Synthesis

Ammonium phosphomolybdate can be made by heating ammonium orthomolybdate combined with phosphoric acid and nitric acid, yielding ammonium nitrate, water, and a yellow precipitate of ammonium phosphomolybdate is obtained.[1]

Normally, it often exists as a hexahydrate, a dark yellow fine crystal which is poorly soluble in water.[1]

It is also obtained as a test result for phosphate ions.

Notes and References

  1. Book: 10.1002/9781118744994.ch39. Keggin Structure Polyoxometalates . 36 . 2014 . Dias . José Alves . Dias . Sílvia Cláudia Loureiro . Caliman . Ednéia . Inorganic Syntheses: Volume 36 . 210–217. 9781118744994 .