See main article: 2014 San Benedetto Tennis Cup.
Pierre-Hugues Herbert and Maxime Teixeira were the defending champion but they did not participate that year.
Daniele Giorgini and Potito Starace won the title, defeating Hugo Dellien and Sergio Galdós in the final, 6–3, 6–7(3–7), [10–5].
Guillermo Durán / Eduardo Schwank (quarterfinals)
Alessandro Giannessi / Máximo González (first round)
Roberto Maytín / Andrés Molteni (first round)
Andrej Martin / 
Jaroslav Pospíšil (quarterfinals)