See main article: 2014 São Paulo Challenger de Tênis.
Marcelo Demoliner and João Souza were the defending champions, but they decided not to play together. Demoliner played alongside Elias and Souza played alongside Sá.
Guido Pella and Diego Sebastián Schwartzman won the title, defeating Máximo González and Andrés Molteni in the final, 1-6, 6–3, [10-4].
Horacio Zeballos (quarterfinals)
André Sá / João Souza (quarterfinals) Máximo González / Andrés Molteni (final)
Roberto Maytín / Fernando Romboli (quarterfinals)